Mechanistic analysis of gold(I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis(gold) vinyl species and reversible C-O bond formation.
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Asymmetric gold-catalyzed lactonizations in water at room temperatureAnatomy of gold catalysts: facts and mythsσ-π-Diauration as an alternative binding mode for digold intermediates in gold(i) catalysis.Stereo- and Regioselective Alkyne Hydrometallation with Gold(III) Hydrides.Chirality Transfer in Gold(I)-Catalysed Hydroalkoxylation of 1,3-Disubstituted Allenes.Intriguing mechanistic labyrinths in gold(I) catalysis.Allenes and computational chemistry: from bonding situations to reaction mechanisms.Recent advances in trifluoromethylation of organic compounds using Umemoto's reagents.Gold-Catalyzed Enantioselective Annulations.Synthesis of gem-diaurated species from alkynols.Gold- or Silver-Catalyzed Syntheses of Pyrones and Pyridine Derivatives: Mechanistic and Synthetic Aspects.Gold(I)-Catalyzed Enantioselective Desymmetrization of 1,3-Diols through Intramolecular Hydroalkoxylation of Allenes.Gold(I)-catalyzed enantioselective carboalkoxylation of alkynes.Catalytic asymmetric synthesis of cyclic ethers containing an α-tetrasubstituted stereocenter.Gold-catalyzed annulations of 2-alkynyl benzaldehydes with vinyl ethers: synthesis of dihydronaphthalene, isochromene, and bicyclo[2.2.2]octane derivatives.Intermolecular gold-catalyzed cycloaddition of alkynes with oxoalkenes.Quantitative kinetic investigation of triazole-gold(I) complex catalyzed [3,3]-rearrangement of propargyl ester.Synthesis and study of cationic, two-coordinate triphenylphosphine-gold-π complexes.Competitive gold-activation modes in terminal alkynes: an experimental and mechanistic study.Straightforward synthetic access to gem-diaurated and digold σ,π-acetylide species.Isolation and characterization of gem-diaurated species having two C-Au σ bonds in gold(i)-activated amidiniumation of alkynes.On the Mechanism of the Digold(I)-Hydroxide-Catalysed Hydrophenoxylation of Alkynes.The mechanism of gold(I)-catalyzed hydroalkoxylation of alkynes: an extensive experimental study.Cationic, two-coordinate gold π complexes.Stereoselective Gold(I)-Catalyzed Intermolecular Hydroalkoxlation of Alkynes.Highly Efficient Gold(I)-Catalyzed Regio- and Stereoselective Hydrocarboxylation of Internal Alkynes.Gold-Catalyzed Asymmetric Intramolecular Cyclization of N-Allenamides for the Synthesis of Chiral Tetrahydrocarbolines.Merging gold catalysis, organocatalytic oxidation, and Lewis acid catalysis for chemodivergent synthesis of functionalized oxazoles from N-propargylamides.Why can a gold salt react as a base?Gold Catalysis for Heterocyclic Chemistry: A Representative Case Study on Pyrone Natural Products.Enantioselective Tandem Cyclization of Alkyne-Tethered Indoles Using Cooperative Silver(I)/Chiral Phosphoric Acid Catalysis.Direct Evidence for the Origin of Bis-Gold Intermediates: Probing Gold Catalysis with Mass Spectrometry.Deactivation of gold(I) catalysts in the presence of thiols and amines--characterisation and catalysis.Self-assembled nanospheres with multiple endohedral binding sites pre-organize catalysts and substrates for highly efficient reactions.A Striking Case of Enantioinversion in Gold Catalysis and Its Probable Origins.Synthesis of spiroaminals by bimetallic Au/Sc relay catalysis: TMS as a traceless controlling group.Gold(i)-catalyzed addition of aldehydes to cyclopropylidene bearing 6-aryl-1,5-enynes.Dual-role of PtCl2 catalysis in the intramolecular cyclization of (hetero)aryl-allenes for the facile construction of substituted 2,3-dihydropyrroles and polyheterocyclic skeletons.Role of σ,π-Digold(I) Alkyne Complexes in Reactions of Enynes.Gold-Catalyzed Cascade Cyclization of 2-Alkynyl-N-Propargylanilines by Rearrangement of a Propargyl Group
P2860
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P2860
Mechanistic analysis of gold(I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis(gold) vinyl species and reversible C-O bond formation.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
2012年论文
@zh
2012年论文
@zh-cn
name
Mechanistic analysis of gold(I ...... reversible C-O bond formation.
@ast
Mechanistic analysis of gold(I ...... reversible C-O bond formation.
@en
type
label
Mechanistic analysis of gold(I ...... reversible C-O bond formation.
@ast
Mechanistic analysis of gold(I ...... reversible C-O bond formation.
@en
prefLabel
Mechanistic analysis of gold(I ...... reversible C-O bond formation.
@ast
Mechanistic analysis of gold(I ...... reversible C-O bond formation.
@en
P2093
P2860
P356
P1476
Mechanistic analysis of gold(I ...... reversible C-O bond formation
@en
P2093
Dieter Weber
Ross A Widenhoefer
Timothy J Brown
P2860
P304
P356
10.1021/JA303844H
P407
P577
2012-05-29T00:00:00Z