Biotinylated Rh(III) complexes in engineered streptavidin for accelerated asymmetric C-H activation
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Undirected, Homogeneous C-H Bond Functionalization: Challenges and OpportunitiesCotranslational incorporation of non-standard amino acids using cell-free protein synthesisProtein design: toward functional metalloenzymesA designed supramolecular protein assembly with in vivo enzymatic activityImmobilization of two organometallic complexes into a single cage to construct protein-based microcompartmentsOlefin Cyclopropanation via Carbene Transfer Catalyzed by Engineered Cytochrome P450 EnzymesA hybrid ring-opening metathesis polymerization catalyst based on an engineered variant of the β-barrel protein FhuA.Palladium(II)-catalyzed enantioselective C(sp³)-H activation using a chiral hydroxamic acid ligand.Direct nitration and azidation of aliphatic carbons by an iron-dependent halogenaseAsymmetric synthesis of α-branched amines via Rh(III)-catalyzed C-H bond functionalization.Opportunities for merging chemical and biological synthesisIntermolecular carbene S-H insertion catalysed by engineered myoglobin-based catalysts†.Library design and screening protocol for artificial metalloenzymes based on the biotin-streptavidin technology.Computational strategies for the design of new enzymatic functionsLight-driven electron injection from a biotinylated triarylamine donor to [Ru(diimine)3](2+)-labeled streptavidin.Significant Improvement of Oxidase Activity through the Genetic Incorporation of a Redox-active Unnatural Amino Acid.Efficient conversion of primary azides to aldehydes catalyzed by active site variants of myoglobinUnstabilized azomethine ylides for the stereoselective synthesis of substituted piperidines, tropanes, and azabicyclo[3.1.0] systemsMyoglobin-Catalyzed Olefination of AldehydesRhodium(III)-catalyzed indazole synthesis by C-H bond functionalization and cyclative captureAnion-π EnzymesConvergent Synthesis of Diverse Nitrogen Heterocycles via Rh(III)-Catalyzed C-H Conjugate Addition/Cyclization Reactions.Facile synthesis of unsymmetrical acridines and phenazines by a Rh(III)-catalyzed amination/cyclization/aromatization cascadeLessons from Nature: A Bio-Inspired Approach to Molecular Design.P450-catalyzed intramolecular sp(3) C-H amination with arylsulfonyl azide substrates.Enantioselective intramolecular C-H amination catalyzed by engineered cytochrome P450 enzymes in vitro and in vivo.Artificial metalloenzymes constructed from hierarchically-assembled proteins.Streptavidin-biotin technology: improvements and innovations in chemical and biological applications.Supramolecular catalysis. Part 2: artificial enzyme mimics.Metalloenzyme design and engineering through strategic modifications of native protein scaffolds.Metalloprotein design using genetic code expansion.Recent advances in engineering proteins for biocatalysis.Transition metal catalysis in confined spaces.Transition metal-catalyzed C-H functionalization of N-oxyenamine internal oxidants.Synthetic biology for the directed evolution of protein biocatalysts: navigating sequence space intelligently.Cascade catalysis--strategies and challenges en route to preparative synthetic biology.Antivitamins for Medicinal Applications.Reversible Covalent and Supramolecular Functionalization of Water-Soluble Gold(I) Complexes.Genetic Optimization of Metalloenzymes: Enhancing Enzymes for Non-Natural Reactions.Tomographic docking suggests the mechanism of auxin receptor TIR1 selectivity.
P2860
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P2860
Biotinylated Rh(III) complexes in engineered streptavidin for accelerated asymmetric C-H activation
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on October 2012
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
Biotinylated Rh
@nl
Biotinylated Rh(III) complexes ...... ated asymmetric C-H activation
@en
type
label
Biotinylated Rh
@nl
Biotinylated Rh(III) complexes ...... ated asymmetric C-H activation
@en
prefLabel
Biotinylated Rh
@nl
Biotinylated Rh(III) complexes ...... ated asymmetric C-H activation
@en
P2093
P2860
P356
P1433
P1476
Biotinylated Rh(III) complexes ...... ated asymmetric C-H activation
@en
P2093
Livia Knörr
Thomas R Ward
Todd K Hyster
P2860
P304
P356
10.1126/SCIENCE.1226132
P407
P577
2012-10-01T00:00:00Z