Entropic intermediates and hidden rate-limiting steps in seemingly concerted cycloadditions. Observation, prediction, and origin of an isotope effect on recrossing.
about
Diels-Alder reactions of allene with benzene and butadiene: concerted, stepwise, and ambimodal transition states.Theoretical and computational studies of non-equilibrium and non-statistical dynamics in the gas phase, in the condensed phase and at interfaces.Taking the plunge: chemical reaction dynamics in liquids.Racing carbon atoms. Atomic motion reaction coordinates and structural effects on Newtonian kinetic isotope effects.Isotope effects, dynamic matching, and solvent dynamics in a Wittig reaction. Betaines as bypassed intermediates.Dynamic origin of the stereoselectivity of a nucleophilic substitution reaction.Controlling Selectivity by Controlling the Path of Trajectories.A case study of the mechanism of alcohol-mediated Morita Baylis-Hillman reactions. The importance of experimental observationsAromatic interactions in asymmetric catalysis: control of enantioselectivity in Diels-Alder reactions catalysed by camphor-derived hydrazides.Dynamics and the Regiochemistry of Nitration of Toluene.Lithium Diisopropylamide: Nonequilibrium Kinetics and Lessons Learned about Rate Limitation.Substituent effects on stereoselectivity of dihalocarbene reactions with cyclohexadiene and on the reactivity of bis-dihalocyclopropanes in electrophilic nitrations en route to pyrimidine N-oxides.Challenges in computational organic chemistryComputational organic chemistry
P2860
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P2860
Entropic intermediates and hidden rate-limiting steps in seemingly concerted cycloadditions. Observation, prediction, and origin of an isotope effect on recrossing.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
2012年论文
@zh
2012年论文
@zh-cn
name
Entropic intermediates and hid ...... isotope effect on recrossing.
@en
type
label
Entropic intermediates and hid ...... isotope effect on recrossing.
@en
prefLabel
Entropic intermediates and hid ...... isotope effect on recrossing.
@en
P2860
P356
P1476
Entropic intermediates and hid ...... isotope effect on recrossing.
@en
P2093
Eugene E Kwan
Ollie M Gonzalez-James
P2860
P304
P356
10.1021/JA208779K
P407
P577
2012-01-18T00:00:00Z