Experimental evidence for heavy-atom tunneling in the ring-opening of cyclopropylcarbinyl radical from intramolecular 12C/13C kinetic isotope effects.
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Evidence for tunneling in base-catalyzed isomerization of glyceraldehyde to dihydroxyacetone by hydride shift under formose conditions.Competition H(D) kinetic isotope effects in the autoxidation of hydrocarbonsTransition state for the NSD2-catalyzed methylation of histone H3 lysine 36Atom Tunneling in Chemistry.Entropic intermediates and hidden rate-limiting steps in seemingly concerted cycloadditions. Observation, prediction, and origin of an isotope effect on recrossing.Isotope effects and heavy-atom tunneling in the Roush allylboration of aldehydesInvestigating inner-sphere reorganization via secondary kinetic isotope effects in the C-H cleavage reaction catalyzed by soybean lipoxygenase: tunneling in the substrate backbone as well as the transferred hydrogen.Controlling Selectivity by Controlling the Path of Trajectories.Controlling Selectivity by Controlling Energy Partitioning in a Thermal Reaction in Solution.Fast Heavy-Atom Tunneling in Trifluoroacetyl Nitrene.Labelling and determination of the energy in reactive intermediates in solution enabled by energy-dependent reaction selectivity.Heavy-Atom Tunneling Calculations in Thirteen Organic Reactions: Tunneling Contributions are Substantial, and Bell's Formula Closely Approximates Multidimensional Tunneling at ≥250 K.Theoretical analysis on the kinetic isotope effects of bimolecular nucleophilic substitution (S(N)2) reactions and their temperature dependence.The new face of isotopic NMR at natural abundance.Der Tunneleffekt von Atomen in der ChemieComputational organic chemistryOrganische Chemie 2010
P2860
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P2860
Experimental evidence for heavy-atom tunneling in the ring-opening of cyclopropylcarbinyl radical from intramolecular 12C/13C kinetic isotope effects.
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2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Experimental evidence for heav ...... C/13C kinetic isotope effects.
@en
Experimental evidence for heav ...... C/13C kinetic isotope effects.
@nl
type
label
Experimental evidence for heav ...... C/13C kinetic isotope effects.
@en
Experimental evidence for heav ...... C/13C kinetic isotope effects.
@nl
prefLabel
Experimental evidence for heav ...... C/13C kinetic isotope effects.
@en
Experimental evidence for heav ...... C/13C kinetic isotope effects.
@nl
P2093
P2860
P356
P1476
Experimental evidence for heav ...... 2C/13C kinetic isotope effects
@en
P2093
David A Hrovat
Ollie M Gonzalez-James
Weston Thatcher Borden
P2860
P304
12548-12549
P356
10.1021/JA1055593
P407
P577
2010-09-01T00:00:00Z