Palladium-Catalyzed Asymmetric Allylic α-Alkylation of Acyclic Ketones
about
Mechanistic origin of the stereodivergence in decarboxylative allylationStereospecific decarboxylative allylation of sulfonesIridium-catalyzed enantioselective allylic substitution of unstabilized enolates derived from α,β-unsaturated ketones.PREPARATION OF (S)-2-Allyl-2-methylcyclohexanone (Cyclohexanone, 2-methyl-2-(2-propen-1-yl)-, (2S)-).Metal Catalyzed Allylic Alkylation: Its Development in the Trost LaboratoriesMigratory decarboxylative coupling of coumarins: synthetic and mechanistic aspects.Enantioselective synthesis of alpha-tertiary hydroxyaldehydes by palladium-catalyzed asymmetric allylic alkylation of enolatesEnantioselective Tsuji allylations.Molybdenum-catalyzed asymmetric allylic alkylation of 3-alkyloxindoles: reaction development and applicationsPalladium-catalyzed decarboxylative sp3-sp3 coupling of nitrobenzene acetic estersLigand controlled highly regio- and enantioselective synthesis of alpha-acyloxyketones by palladium-catalyzed allylic alkylation of 1,2-enediol carbonatesDirect Asymmetric Alkylation of Ketones: Still Unconquered.Direct Copper-Free Domino Conjugate Addition-Cycloallylation using Organozinc ReagentsEnantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams.Asymmetric Dearomatization/Cyclization Enables Access to Polycyclic Chemotypes.Enantioselective Iridium-Catalyzed Allylic Alkylation Reactions of Masked Acyl Cyanide Equivalents.The catalytic enantioselective total synthesis of (+)-liphagal.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.The reaction mechanism of the enantioselective Tsuji allylation: inner-sphere and outer-sphere pathways, internal rearrangements, and asymmetric C-C bond formation.Direct, iridium-catalyzed enantioselective and regioselective allylic etherification with aliphatic alcohols.Stereoselective β-C-glycosylation by a palladium-catalyzed decarboxylative allylation: formal synthesis of aspergillide A.Facile access to cis-2,6-disubstituted tetrahydropyrans by palladium-catalyzed decarboxylative allylation: total syntheses of (±)-centrolobine and (+)-decytospolides A and B.3-Aza π-allyl palladium derived from imino migration in palladium-carbene: MCRs toward multiple substituted indole skeleton.Stereospecific Decarboxylative Nazarov Cyclization Mediated by Carbon Dioxide for the Preparation of Highly Substituted 2-Cyclopentenones.Quaternary β2,2 -Amino Acids: Catalytic Asymmetric Synthesis and Incorporation into Peptides by Fmoc-Based Solid-Phase Peptide Synthesis.Enantioselective synthesis of sterically hindered α-allyl-α-aryl oxindoles via palladium-catalysed decarboxylative asymmetric allylic alkylation.The asymmetric alkylation of dimethylhydrazones; intermolecular chirality transfer using sparteine as chiral ligand.One-pot synthesis of β-N-glycosyl imidazole analogues via a palladium-catalysed decarboxylative allylation.β-Type glycosidic bond formation by palladium-catalyzed decarboxylative allylation.Asymmetric Total Syntheses of Kopsia Indole Alkaloids.Enantioselective and Diastereoselective Tsuji-Trost Allylic Alkylation of Lactones: An Experimental and Computational Study
P2860
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P2860
Palladium-Catalyzed Asymmetric Allylic α-Alkylation of Acyclic Ketones
description
2005 nî lūn-bûn
@nan
2005 թուականի Դեկտեմբերին հրատարակուած գիտական յօդուած
@hyw
2005 թվականի դեկտեմբերին հրատարակված գիտական հոդված
@hy
2005年の論文
@ja
2005年論文
@yue
2005年論文
@zh-hant
2005年論文
@zh-hk
2005年論文
@zh-mo
2005年論文
@zh-tw
2005年论文
@wuu
name
Palladium-Catalyzed Asymmetric Allylic α-Alkylation of Acyclic Ketones
@ast
Palladium-Catalyzed Asymmetric Allylic α-Alkylation of Acyclic Ketones
@en
type
label
Palladium-Catalyzed Asymmetric Allylic α-Alkylation of Acyclic Ketones
@ast
Palladium-Catalyzed Asymmetric Allylic α-Alkylation of Acyclic Ketones
@en
prefLabel
Palladium-Catalyzed Asymmetric Allylic α-Alkylation of Acyclic Ketones
@ast
Palladium-Catalyzed Asymmetric Allylic α-Alkylation of Acyclic Ketones
@en
P2860
P356
P1476
Palladium-Catalyzed Asymmetric Allylic α-Alkylation of Acyclic Ketones
@en
P2093
P2860
P304
17180-17181
P356
10.1021/JA055968F
P407
P50
P577
2005-12-01T00:00:00Z