Regio- and enantioselective Pd-catalyzed allylic alkylation of ketones through allyl enol carbonates.
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Palladium-Catalyzed Asymmetric Allylic α-Alkylation of Acyclic KetonesPalladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total SynthesisDirect and enantioselective {alpha}-allylation of ketones via singly occupied molecular orbital (SOMO) catalysisA Cooperative N-Heterocyclic Carbene/Palladium Catalysis System.PREPARATION OF (S)-2-Allyl-2-methylcyclohexanone (Cyclohexanone, 2-methyl-2-(2-propen-1-yl)-, (2S)-).Transition metal-catalyzed decarboxylative allylation and benzylation reactionsMetal Catalyzed Allylic Alkylation: Its Development in the Trost LaboratoriesPd and Mo Catalyzed Asymmetric Allylic Alkylation.Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones.Catalytic double stereoinduction in asymmetric allylic alkylation of oxindoles.Catalytic enantioselective synthesis of quaternary carbon stereocentresPalladium-catalyzed allylic alkylation of carboxylic acid derivatives: N-acyloxazolinones as ester enolate equivalents.Enantioselective synthesis of alpha-tertiary hydroxyaldehydes by palladium-catalyzed asymmetric allylic alkylation of enolatesEnantioselective Tsuji allylations.Ligand controlled highly regio- and enantioselective synthesis of alpha-acyloxyketones by palladium-catalyzed allylic alkylation of 1,2-enediol carbonatesDevelopment of asymmetric deacylative allylation.Direct Asymmetric Alkylation of Ketones: Still Unconquered.Opening of aryl-substituted epoxides to form quaternary stereogenic centers: synthesis of (-)-mesembrine.Direct Copper-Free Domino Conjugate Addition-Cycloallylation using Organozinc ReagentsEnantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams.Unusual allylpalladium carboxylate complexes: identification of the resting state of catalytic enantioselective decarboxylative allylic alkylation reactions of ketones.Enantioselective cyclizations of silyloxyenynes catalyzed by cationic metal phosphine complexes.Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-Carbon Quaternary Stereocenters.Selective syntheses of Δ(α,β) and Δ(β,γ) butenolides from allylic cyclopropenecarboxylates via tandem ring expansion/[3,3]-sigmatropic rearrangementsEnantioselective construction of all-carbon quaternary centers by branch-selective Pd-catalyzed allyl-allyl cross-coupling.Electronic differentiation competes with transition state sensitivity in palladium-catalyzed allylic substitutions.Construction of vicinal tertiary and all-carbon quaternary stereocenters via Ir-catalyzed regio-, diastereo-, and enantioselective allylic alkylation and applications in sequential Pd catalysisEnantioselective synthesis of alpha,alpha-disubstituted cyclopentenes by an N-heterocyclic carbene-catalyzed desymmetrization of 1,3-diketonesDiastereo- and enantioselective iridium-catalyzed allylation of cyclic ketone enolates: synergetic effect of ligands and barium enolatesThe catalytic enantioselective total synthesis of (+)-liphagal.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Catalytic asymmetric alkylation of substituted isoflavanonesSelective nickel- and manganese-catalyzed decarboxylative cross coupling of some α,β-unsaturated carboxylic acids with cyclic ethers.Direct, iridium-catalyzed enantioselective and regioselective allylic etherification with aliphatic alcohols.Sterically Demanding Unsymmetrical Diaryl-λ(3)-iodanes for Electrophilic Pentafluorophenylation and an Approach to α-Pentafluorophenyl Carbonyl Compounds with an All-Carbon Stereocenter.General entry to aspidosperma alkaloids: enantioselective total synthesis of (-)-aspidophytine.Enantioselective palladium-catalyzed decarboxylative allylation of carbazolones and indolones: formal synthesis of (+)-kopsihainanine A.The bidirectional total synthesis of sampsonione P and hyperibone I.Stereospecific Decarboxylative Nazarov Cyclization Mediated by Carbon Dioxide for the Preparation of Highly Substituted 2-Cyclopentenones.
P2860
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P2860
Regio- and enantioselective Pd-catalyzed allylic alkylation of ketones through allyl enol carbonates.
description
2005 nî lūn-bûn
@nan
2005年の論文
@ja
2005年学术文章
@wuu
2005年学术文章
@zh
2005年学术文章
@zh-cn
2005年学术文章
@zh-hans
2005年学术文章
@zh-my
2005年学术文章
@zh-sg
2005年學術文章
@yue
2005年學術文章
@zh-hant
name
Regio- and enantioselective Pd ...... through allyl enol carbonates.
@en
Regio- and enantioselective Pd ...... through allyl enol carbonates.
@nl
type
label
Regio- and enantioselective Pd ...... through allyl enol carbonates.
@en
Regio- and enantioselective Pd ...... through allyl enol carbonates.
@nl
prefLabel
Regio- and enantioselective Pd ...... through allyl enol carbonates.
@en
Regio- and enantioselective Pd ...... through allyl enol carbonates.
@nl
P356
P1476
Regio- and enantioselective Pd ...... through allyl enol carbonates.
@en
P2093
P304
P356
10.1021/JA043472C
P407
P50
P577
2005-03-01T00:00:00Z