Umpolung by N-Heterocyclic Carbenes: Generation and Reactivity of the Elusive 2,2-Diamino Enols (Breslow Intermediates)
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Micro-total envelope system with silicon nanowire separator for safe carcinogenic chemistry.Commercial Herbicides Can Trigger the Oxidative Inactivation of Acetohydroxyacid SynthaseOrganocatalytic Reactions Enabled by N-Heterocyclic CarbenesRadical [1,3] Rearrangements of Breslow Intermediates.Functional diversity of organic molecule enzyme cofactors.NHC-catalyzed cleavage of vicinal diketones and triketones followed by insertion of enones and ynones.Crystal structure of di-μ-iodido-bis-{[1,3-bis-(2,6-diiso-propyl-phen-yl)imidazol-2-yl-idene]lithium}.Rate and equilibrium constants for the addition of N-heterocyclic carbenes into benzaldehydes: a remarkable 2-substituent effect.Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect.NHC-catalyzed hydroacylation of styrenes.Diaminocyclopropenylidene organocatalysts: beyond N-heterocyclic carbenes.Characterization of the key intermediates of carbene-catalyzed umpolung by NMR spectroscopy and X-ray diffraction: breslow intermediates, homoenolates, and azolium enolates.Diesel and alkane fuels from biomass by organocatalysis and metal-acid tandem catalysis.Polyhalides as Efficient and Mild Oxidants for Oxidative Carbene Organocatalysis by Radical Processes.Switchable selectivity in an NHC-catalysed dearomatizing annulation reaction.Carbon-based two electron σ-donor ligands beyond classical N-heterocyclic carbenes.N-Heterocyclic-Carbene-Catalyzed Umpolung of Imines.Synthesis of functionalized imidazolidine-2-thiones via NHC/base-promoted aza-benzoin/aza-acetalization domino reactions.Highly chemoselective intermolecular cross-benzoin reactions using an ad hoc designed novel N-heterocyclic carbene catalyst.Oxidative N-Heterocyclic Carbene-Catalyzed γ-Carbon Addition of Enals to Imines: Mechanistic Studies and Access to Antimicrobial Compounds.Mechanistic insight into the Staudinger reaction catalyzed by N-heterocyclic carbenes.Deconstructing covalent organocatalysis.Selective Activation of Fluoroalkenes with N-Heterocyclic Carbenes: Synthesis of N-Heterocyclic Fluoroalkenes and Polyfluoroalkenyl Imidazolium Salts.The ambivalent chemistry of a free anionic N-heterocyclic carbene decorated with a malonate backbone: the plus of a negative charge.Mechanistic insights into the triazolylidene-catalysed Stetter and benzoin reactions: role of the N-aryl substituent
P2860
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P2860
Umpolung by N-Heterocyclic Carbenes: Generation and Reactivity of the Elusive 2,2-Diamino Enols (Breslow Intermediates)
description
2012 nî lūn-bûn
@nan
2012 թուականի Հոկտեմբերին հրատարակուած գիտական յօդուած
@hyw
2012 թվականի հոտեմբերին հրատարակված գիտական հոդված
@hy
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
name
Umpolung by N-Heterocyclic Car ...... Enols (Breslow Intermediates)
@ast
Umpolung by N-Heterocyclic Car ...... Enols (Breslow Intermediates)
@en
type
label
Umpolung by N-Heterocyclic Car ...... Enols (Breslow Intermediates)
@ast
Umpolung by N-Heterocyclic Car ...... Enols (Breslow Intermediates)
@en
prefLabel
Umpolung by N-Heterocyclic Car ...... Enols (Breslow Intermediates)
@ast
Umpolung by N-Heterocyclic Car ...... Enols (Breslow Intermediates)
@en
P2093
P2860
P356
P1476
Umpolung by N-Heterocyclic Car ...... Enols (Breslow Intermediates)
@en
P2093
Albrecht Berkessel
J. Henrique Teles
Jörg-M. Neudörfl
Nils E. Schlörer
Silvia Elfert
V. Reddy Yatham
P2860
P304
12370-12374
P356
10.1002/ANIE.201205878
P407
P577
2012-10-18T00:00:00Z