α,β-Unsaturated acyl azoliums from N-heterocyclic carbene catalyzed reactions: observation and mechanistic investigation.
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Organocatalytic Reactions Enabled by N-Heterocyclic CarbenesUmpolung by N-Heterocyclic Carbenes: Generation and Reactivity of the Elusive 2,2-Diamino Enols (Breslow Intermediates)Mechanistic investigation of the enantioselective intramolecular stetter reaction: proton transfer is the first irreversible stepChiral N-Heterocyclic Carbene Catalyzed Annulations of Enals and Ynals with Stable Enols: A Highly Enantioselective Coates-Claisen Rearrangement.Cooperative Lewis acid/N-heterocyclic carbene catalysisAsymmetric Organocatalysis: The Emerging Utility of α,β-Unsaturated Acylammonium Salts.Stereo- and Chemodivergent NHC-Promoted Functionalisation of Arylalkylketenes with ChloralChemical Synthesis of GM2 Glycans, Bioconjugation with Bacteriophage Qβ, and the Induction of Anticancer Antibodies.Exploiting Acyl and Enol Azolium Intermediates via NHeterocyclic Carbene Catalyzed Reactions of Alpha-Reducible Aldehydes.A Computational Study of the Origin of Stereoinduction in NHC-Catalyzed Annulation Reactions of α,β-Unsaturated Acyl Azoliums.Employing homoenolates generated by NHC catalysis in carbon-carbon bond-forming reactions: state of the art.Catalytic selective synthesis.Recent advances in N-heterocyclic carbene catalyzed achiral synthesis.The effect of the N-mesityl group in NHC-catalyzed reactions.A cooperative N-heterocyclic carbene/chiral phosphate catalysis system for allenolate annulations.Asymmetric NHC-catalyzed synthesis of α-fluoroamides from readily accessible α-fluoroenals.Catalysis with N-heterocyclic carbenes under oxidative conditions.Kinetic resolution of tertiary alcohols: highly enantioselective access to 3-hydroxy-3-substituted oxindoles.N-tert-butyl triazolylidenes: catalysts for the enantioselective (3+2) annulation of α,β-unsaturated acyl azoliums.Assembly of spirooxindole derivatives containing four consecutive stereocenters by using cascade reactions catalyzed by an N-heterocyclic carbene.Enantioselective annulation of enals with 2-naphthols by triazolium salts derived from l-phenylalanine.N-Heterocyclic carbene-catalyzed sulfa-Michael addition of enals.Synthesis and Immunological Evaluation of a Multicomponent Cancer Vaccine Candidate Containing a Long MUC1 Glycopeptide.Access to Enantiopure Triarylmethanes and 1,1-Diarylalkanes by NHC-Catalyzed Acylative Desymmetrization.Oxidative N-Heterocyclic Carbene Catalyzed Dearomatization of Indoles to Spirocyclic Indolenines with a Quaternary Carbon Stereocenter.Enantioselective synthesis of spiro γ-butyrolactones by N-heterocyclic carbene (NHC)-catalyzed formal [3 + 2] annulation of enals with 3-hydroxy oxindoles.Expeditious assembly of fused dihydropyranones via N-heterocyclic carbene-catalyzed tandem Michael addition/lactonization.Cycloadduct formation of α,β-unsaturated esters with azides catalyzed by NHC systems.Enantioselective intermolecular all-carbon [4+2] annulation via N-heterocyclic carbene organocatalysis.Oxidative N-Heterocyclic Carbene-Catalyzed γ-Carbon Addition of Enals to Imines: Mechanistic Studies and Access to Antimicrobial Compounds.N-Heterocyclic carbene-catalyzed formal cross-coupling reaction of α-haloenals with thiols: organocatalytic construction of sp2 carbon-sulfur bonds.A NHC-catalyzed 1,3-dipolar cycloaddition reaction of allyl ketones with azides: direct access to 1,4,5-trisubstituted 1,2,3-triazoles.NHC organocatalytic formal LUMO activation of α,β-unsaturated esters for reaction with enamides.Direct β-activation of saturated aldehydes to formal Michael acceptors through oxidative NHC catalysis.Evolution of asymmetric organocatalysis: multi- and retrocatalysisMechanistic insights into the triazolylidene-catalysed Stetter and benzoin reactions: role of the N-aryl substituentDurch N-heterocyclische Carbene katalysierte oxidative Dearomatisierung von Indolen zu spirocyclischen Indoleninen mit quartärem Stereozentrum
P2860
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P2860
α,β-Unsaturated acyl azoliums from N-heterocyclic carbene catalyzed reactions: observation and mechanistic investigation.
description
2011 nî lūn-bûn
@nan
2011 թուականի Յունուարին հրատարակուած գիտական յօդուած
@hyw
2011 թվականի հունվարին հրատարակված գիտական հոդված
@hy
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
name
α,β-Unsaturated acyl azoliums ...... and mechanistic investigation.
@ast
α,β-Unsaturated acyl azoliums ...... and mechanistic investigation.
@en
type
label
α,β-Unsaturated acyl azoliums ...... and mechanistic investigation.
@ast
α,β-Unsaturated acyl azoliums ...... and mechanistic investigation.
@en
prefLabel
α,β-Unsaturated acyl azoliums ...... and mechanistic investigation.
@ast
α,β-Unsaturated acyl azoliums ...... and mechanistic investigation.
@en
P2860
P356
P1476
α,β-Unsaturated acyl azoliums ...... and mechanistic investigation
@en
P2093
Jeffrey W Bode
Pinguan Zheng
P2860
P304
P356
10.1002/ANIE.201005352
P407
P577
2011-01-05T00:00:00Z