CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF₃ and BH₃.

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Synthesis and reactions of N-heterocyclic carbene boranes.Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor.

P2860

Q37928601-C76F29EA-386F-4A6A-B2B4-BD9EF5EEAC5C Q46791581-05262797-9326-43C7-836F-034D71F4B4AB

P2860

CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF₃ and BH₃.

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http://www.wikidata.org/entity/Q34207186

description

2010 nî lūn-bûn

@nan

2010 թուականի Օգոստոսին հրատարակուած գիտական յօդուած

@hyw

2010 թվականի օգոստոսին հրատարակված գիտական հոդված

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2010年の論文

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2010年論文

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2010年論文

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2010年論文

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2010年論文

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2010年論文

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2010年论文

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name

CAAC Boranes. Synthesis and ch ...... ne complexes from BF₃ and BH₃.

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CAAC Boranes. Synthesis and ch ...... ne complexes from BF₃ and BH₃.

@en

CAAC Boranes. Synthesis and characterization of cyclic

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type

Item

label

CAAC Boranes. Synthesis and ch ...... ne complexes from BF₃ and BH₃.

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CAAC Boranes. Synthesis and ch ...... ne complexes from BF₃ and BH₃.

@en

CAAC Boranes. Synthesis and characterization of cyclic

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prefLabel

CAAC Boranes. Synthesis and ch ...... ne complexes from BF₃ and BH₃.

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CAAC Boranes. Synthesis and ch ...... ne complexes from BF₃ and BH₃.

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CAAC Boranes. Synthesis and characterization of cyclic

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P1476

CAAC Boranes. Synthesis and ch ...... ne complexes from BF₃ and BH₃.

@en

P2093

Dennis P Curran

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Emmanuel Lacôte

http://www.w3.org/2001/XMLSchema#string

Julien Monot

http://www.w3.org/2001/XMLSchema#string

Louis Fensterbank

http://www.w3.org/2001/XMLSchema#string

Max Malacria

http://www.w3.org/2001/XMLSchema#string

Steven J Geib

http://www.w3.org/2001/XMLSchema#string

P2860

Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference.

A stable, neutral diborene containing a B=B double bond.

A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes

Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino)carbenes, and catalytic activity of the ensuing gold(I) complex in the three-component preparation of 1,2-dihydroquinoline derivatives.

Intramolecular "hydroiminiumation" of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs).

EPR studies of the generation, structure, and reactivity of n-heterocyclic carbene borane radicals.

Amino-aryl-carbenes: alternative ligands for transition metals?

Synthesis and reactivity of triethylborane adduct of N-heterocyclic carbene: versatile synthons for synthesis of N-heterocyclic carbene complexes.

N-heterocyclic carbene boryl radicals: a new class of boron-centered radical.

Complexes of borane and N-heterocyclic carbenes: a new class of radical hydrogen atom donor.

P304

709-712

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scholarly article

P356

10.3762/BJOC.6.82

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http://www.w3.org/2001/XMLSchema#string

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2010-08-02T00:00:00Z

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47556432

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20978616

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P932

2956467

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CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF₃ and BH₃.

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P2860

P2860

CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF₃ and BH₃.

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P1433

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