Synthesis and reactions of N-heterocyclic carbene boranes. - Wikidata - awgldk - TriplyDB

Synthesis and reactions of N-heterocyclic carbene boranes.

Synthesis and reactions of N-heterocyclic carbene boranes.

http://www.wikidata.org/entity/Q37928601

about

Radicals: Reactive Intermediates with Translational Potential Borenium ion catalyzed hydroboration of alkenes with N-heterocyclic carbene-boranes Direct estimate of the internal π-donation to the carbene centre within N-heterocyclic carbenes and related molecules Reductions of aldehydes and ketones with a readily available N-heterocyclic carbene borane and acetic acid Carbene-Stabilized Main Group Radicals and Radical Ions Donor-acceptor chemistry in the main group.Radical reactions of borohydrides.N-heterocyclic carbene (NHC) complexes of group 4 transition metals.Catalysis of Radical Reactions: A Radical Chemistry Perspective.Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to α,β-Unsaturated Carbonyl Compounds.Metal-free catalytic enantioselective C-B bond formation: (pinacolato)boron conjugate additions to α,β-unsaturated ketones, esters, Weinreb amides, and aldehydes promoted by chiral N-heterocyclic carbenes.One-pot synthesis of cyanohydrin derivatives from alkyl bromides via incorporation of two one-carbon components by consecutive radical/ionic reactions.Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anion Synthesis and minisci reactions of organotrifluoroborato building blocks.Flow Giese reaction using cyanoborohydride as a radical mediator.Using Ylide Functionalization to Stabilize Boron Cations.The renaissance of organic radical chemistry - deja vu all over again.N-heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation.An electron-precise, tetrahedral μ3 boride complex.Theoretical design of strong neutral radical-boron adducts: trisubstituted boranes as potential radical scavengers.Genetically programmed chiral organoborane synthesis.An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH].N-Heterocyclic Carbene Stabilized Boryl Radicals.Fine-Tuning of Lewis Acidity: The Case of Borenium Hydride Complexes Derived from Bis(phosphinimino)amide Boron Precursors.Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor.A multiply functionalized base-coordinated Ge(II) compound and its reversible dimerization to the digermene.Isolation of a bis(oxazol-2-ylidene)-phenylborylene adduct and its reactivity as a boron-centered nucleophile.Isolation of a neutral boron-containing radical stabilized by a cyclic (alkyl)(amino)carbene.Boron radical cations from the facile oxidation of electron-rich diborenes.Tetrahydrofuran ring opening and related reactions with an N-heterocyclic carbene-boryl trifluoromethanesulfonate.Radical Hydrodehalogenation of Aryl Bromides and Chlorides with Sodium Hydride and 1,4-Dioxane.Synthesis of benzothiophene and indole derivatives through metal-free propargyl-allene rearrangement and allyl migration.Crystalline boron-linked tetraaminoethylene radical cations.Consecutive reduction, radical-cyclization, and oxidative-dehydrogenation reaction of ortho-substituted diboryl compounds.N-Heterocyclic Carbene Boranes as Reactive Oxygen Species-Responsive Materials: Application to the Two-Photon Imaging of Hypochlorous Acid in Living Cells and Tissues.Aminopyridine-Borane Complexes as Hydrogen Atom Donor Reagents: Reaction Mechanism and Substrate Selectivity.Silylene-Nickel Promoted Cleavage of B-O Bonds: From Catechol Borane to the Hydroborylene Ligand.Borylative Radical Cyclizations of Benzo[3,4]cyclodec-3-ene-1,5-diynes and N-Heterocyclic Carbene-Boranes.Carbon-based two electron σ-donor ligands beyond classical N-heterocyclic carbenes.Synthesis of a Doubly Boron-Doped Perylene through NHC-Borenium Hydroboration/C-H Borylation/Dehydrogenation.

P2860

Q28468198-F7FD080D-E055-4579-98FC-0EF26382E86F Q36117020-1FC08543-0CF0-46CA-A95F-D0B7C8678164 Q36524958-BAA0691F-3D34-4478-923B-0D6618C4F894 Q36774232-D0FCF071-7909-4634-83E7-547ECBB93399 Q38123495-8751FBCE-DE24-42B5-8423-966F7F3CEAEA Q38208700-0AE8B7B4-E9A4-4B58-87DF-981483F7F9AE Q38263232-57CC9D17-FEE4-431F-A69A-AE8B33F9C2DC Q38327305-E07E795F-7488-4C27-8F92-74F628244A31 Q38605492-36C2E1B3-DE1C-4999-8277-0E99B2E295FA Q41319490-9957DC5F-FB64-4F16-8CE4-0CAD859E4163 Q41826469-8CA23C08-4652-4514-BEB0-6DE51922FA0B Q41879946-3D222B5D-A3B7-4EFA-9B0E-DB85A4AD84EF Q42042236-DB9AC11A-DE82-46CB-AF0B-148CDC3053FE Q42148633-25F16F5B-46F4-48B5-9B58-A07788FE185E Q42154332-5CE62DCA-1C67-451C-BD7E-7143D15BB1BF Q42314607-A3B43139-BF8F-4601-8080-D3AB2FB4A962 Q42782305-D4B03238-65BF-4F69-80BB-208B2CE0EBF4 Q43533924-EA7F3024-36D4-48CE-9A2B-F7094BE89489 Q45179913-68616A78-1975-409A-9872-5657C7CFCEF7 Q45729111-A8885183-9159-4FC4-BCAE-D792687DCA57 Q45982903-CB68CF2A-3461-4F3A-BCEC-942331FEE14E Q46320941-8E6AE469-F925-4A0A-899D-73D224D22781 Q46442940-CC47769C-EB56-45A5-87E0-E66E8A3FC1C5 Q46526330-4B924BEF-39F0-403C-BEC6-4FCCAD9E2198 Q46791581-A27B58F9-06B6-473C-AEC8-5DE6B0F8B610 Q46819133-33E53860-66B0-486B-A672-09002F1085DC Q46872559-0E679689-2BF6-4762-8B7F-7BDE4932FF9D Q46881189-EA58A262-FFFB-4A79-A699-1D27726360A0 Q46908479-1222633C-7D2F-4DA9-A519-A3DC5DA9529F Q46982191-BBA26200-3F93-4C2E-AC51-BBCD48D3D76E Q47100603-6AFF5E99-72CF-4DE3-8EB5-891CBCCDC800 Q47110334-C93305D2-0F0E-4B1A-AE1F-16465532E3AC Q47122545-6CC3579F-3FC9-44A7-8548-E82F8893213C Q47790898-E8236C7D-E51B-4CF2-811C-B28F1EB2BBA1 Q48045759-C0874C32-380E-4A89-B9BA-8ACCCC173A6C Q48140173-CD71B42F-74AB-4023-BC89-44FE47DA9B1E Q48179089-B5AD8AA8-0681-431C-9271-48E2049C5D3B Q48230563-5AEE2DD4-8A8A-4EE3-A984-59F14B42B720 Q48297432-B49B87E6-EC7D-4B11-9B7E-89FC4A1925EE Q48351289-9D2EF4BA-D361-499E-987B-792A7E0C5AD7

P2860

Synthesis and reactions of N-heterocyclic carbene boranes.

http://www.wikidata.org/entity/Q37928601

description

article científic

@ca

article scientifique

@fr

articol științific

@ro

articolo scientifico

@it

artigo científico

@gl

artigo científico

@pt

artigo científico

@pt-br

artikel ilmiah

@id

artikull shkencor

@sq

artículo científico

@es

name

Synthesis and reactions of N-heterocyclic carbene boranes.

@en

Synthesis and reactions of N-heterocyclic carbene boranes.

@nl

type

label

Synthesis and reactions of N-heterocyclic carbene boranes.

@en

Synthesis and reactions of N-heterocyclic carbene boranes.

@nl

prefLabel

Synthesis and reactions of N-heterocyclic carbene boranes.

@en

Synthesis and reactions of N-heterocyclic carbene boranes.

@nl

P1433

Q37928601-8F38F89D-CBCD-44F6-8DD4-DC056D11EE2A

P1476

Q37928601-5D2A8008-AD44-47EB-823E-4E669F02AB1A

P2093

Q37928601-09FD7E89-B9A8-4B29-96B8-2E0F4362A95A

Q37928601-0F28936B-4264-4331-82E5-050D3A202AC0

Q37928601-41110908-E462-4F66-87DB-80DD3297FC56

Q37928601-B6DF34B5-3D0E-4557-9AB0-8E2245FA8B10

Q37928601-D5ACB657-D3CC-44DA-889B-F816B128D6E0

Q37928601-FE7AF020-723B-4DEC-A659-40088E5E61DD

P2860

Q37928601-056BC5B7-2CE4-4FA5-9500-03456F013BA6

Q37928601-0AFA8917-7385-4620-9784-52A0A9802D08

Q37928601-12EC0097-5350-4498-A7BF-F6158541525D

Q37928601-1525535E-93A8-4989-8382-89FD403DBD6E

Q37928601-1689894D-44E5-44A0-ABDC-9E4D5EBDE1C3

Q37928601-19BED15F-AB1A-4D52-8D0C-4DE16E77C1E5

Q37928601-1C5DB2CD-C75C-407B-B857-4C4578FEB882

Q37928601-1DDD711D-E43E-4A1F-B0C5-62447D4E5762

Q37928601-2B852A4E-515C-4BEE-A696-2D665E52E4CD

Q37928601-2BBB39E0-CC62-4054-81A4-A13D5C5FD398

P304

Q37928601-144C9A44-7033-4A61-85C2-7CA7797E5B77

P31

Q37928601-206B5188-2FFA-4AEA-ACB7-61FC75D97518

P356

Q37928601-BA9B5631-EBE5-492F-A132-B6282ED1C0E5

P407

Q37928601-DD2C38AC-9990-461A-8624-F66F63C86CA5

P433

Q37928601-3C5B3932-5668-4A6A-9D9D-3CA96EE24B0A

P478

Q37928601-C24F0680-B081-417F-A5E3-5ABE3673BA99

P577

Q37928601-6469862D-3E28-4F7D-AB13-F73DAC9EF38B

P698

Q37928601-DF61AE1E-2EFA-45DE-9ACB-0FB374F7F4FA

P356

P1433

Angewandte Chemie International Edition

P1476

Synthesis and reactions of N-heterocyclic carbene boranes.

@en

P2093

Andrey Solovyev

http://www.w3.org/2001/XMLSchema#string

Dennis P Curran

http://www.w3.org/2001/XMLSchema#string

Emmanuel Lacôte

http://www.w3.org/2001/XMLSchema#string

Louis Fensterbank

http://www.w3.org/2001/XMLSchema#string

Malika Makhlouf Brahmi

http://www.w3.org/2001/XMLSchema#string

Max Malacria

http://www.w3.org/2001/XMLSchema#string

P2860

Electronic stabilization of nucleophilic carbenes

CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF₃ and BH₃.

A stable, neutral diborene containing a B=B double bond.

The chemistry of functionalised N-heterocyclic carbenes.

Organocatalysis by N-heterocyclic carbenes.

Superelectrophilic intermediates in nitrogen-directed aromatic borylation.

Stable cyclic carbenes and related species beyond diaminocarbenes.

A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes

A Facile Synthesis of Carbamoylsilanes, -boranes and -phosphane Oxides - Isolation of the First Uncomplexed Carbamoylborane

Efficient C-B bond formation promoted by N-heterocyclic carbenes: synthesis of tertiary and quaternary B-substituted carbons through metal-free catalytic boron conjugate additions to cyclic and acyclic alpha,beta-unsaturated carbonyls.

P304

10294-10317

http://www.w3.org/2001/XMLSchema#string

P31

scholarly article

P356

10.1002/ANIE.201102717

http://www.w3.org/2001/XMLSchema#string

P407

P433

44

http://www.w3.org/2001/XMLSchema#string

P478

50

http://www.w3.org/2001/XMLSchema#string

P577

2011-09-07T00:00:00Z

http://www.w3.org/2001/XMLSchema#dateTime

P698

21898724

http://www.w3.org/2001/XMLSchema#string