A stable, neutral diborene containing a B=B double bond.
about
Low-valent organometallics--synthesis, reactivity, and potential applicationsMetal-free binding and coupling of carbon monoxide at a boron-boron triple bond.CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF₃ and BH₃.Borenium ion catalyzed hydroboration of alkenes with N-heterocyclic carbene-boranesSynthesis and reactions of N-heterocyclic carbene boranes.Carbene-Stabilized Main Group Radicals and Radical IonsStability and molecular properties of the boron-nitrogen alternating analogs of azulene and naphthalene: a computational study.Reductive Insertion of Elemental Chalcogens into Boron-Boron Multiple Bonds.Formation and Reactivity of Electron-Precise B-B Single and Multiple Bonds.Borylenes: An Emerging Class of Compounds.A Brief Survey of our Contribution to Stable Carbene Chemistry.Insights into the carbene-initiated aggregation of [Fe(cot)(2)].First dinuclear copper/gallium complexes: supporting Cu0 and Cu(I) centres by low-valent organogallium ligands.Group 13 ligand supported heavy-metal complexes: first structural evidence for gallium-lead and gallium-mercury bonds.Diazabutadiene complexes of selenium as Se2+ transfer reagents.Beta-diketiminate-stabilized magnesium(I) dimers and magnesium(II) hydride complexes: synthesis, characterization, adduct formation, and reactivity studies.Spying on the boron-boron triple bond using spin-spin coupling measured from 11B solid-state NMR spectroscopy.The first bismuth-NHC complexes.Synthesis of a dialumene-benzene adduct and its reactivity as a synthetic equivalent of a dialumene.Recent advances in the field of main-group mono- and diatomic "allotropes" stabilised by neutral ligands.Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes.Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines.An electron-precise, tetrahedral μ3 boride complex.Single, double, triple bonds and chains: the formation of electron-precise B-B bonds.Stabilization of diborane(4) by transition metal fragments and a novel metal to π Dewar-Chatt-Duncanson model of back donation.Reactivity of Stabilized Li/Cl Carbenoids towards Lewis Base Adducts of BH3: B-H Bond Activation versus Carbene Dimerization.Main group chemistry: metal-reinforced bonding.Efficient Water Reduction with sp3 -sp3 Diboron(4) Compounds: Application to Hydrogenations, H-D Exchange Reactions, and Carbonyl Reductions.Triaminotriborane(3): A Homocatenated Boron Chain Connected by B-B Multiple Bonds.A di-substituted boron dication and its hydride-induced transformation to an NHC-stabilized borabenzene.An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH].A stable silicon(0) compound with a Si=Si double bond.Ultrashort Beryllium-Beryllium Distances Rivalling Those of Metal-Metal Quintuple Bonds Between Transition Metals.Neutral Diboron Analogues of Archetypal Aromatic Species by Spontaneous Cycloaddition.The synthesis and structure of a carbene-stabilized iminocarboranyl-boron(I) compound.Isolation of a bis(oxazol-2-ylidene)-phenylborylene adduct and its reactivity as a boron-centered nucleophile.Isolation of a neutral boron-containing radical stabilized by a cyclic (alkyl)(amino)carbene.Boron complexes of redox-active diimine ligand.Boron radical cations from the facile oxidation of electron-rich diborenes.Increasing the Reactivity of Diborenes: Derivatization of NHC-Supported Dithienyldiborenes with Electron-Donor Groups.
P2860
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P2860
A stable, neutral diborene containing a B=B double bond.
description
2007 nî lūn-bûn
@nan
2007 թուականի Սեպտեմբերին հրատարակուած գիտական յօդուած
@hyw
2007 թվականի սեպտեմբերին հրատարակված գիտական հոդված
@hy
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
name
A stable, neutral diborene containing a B=B double bond.
@ast
A stable, neutral diborene containing a B=B double bond.
@en
A stable, neutral diborene containing a B=B double bond.
@nl
type
label
A stable, neutral diborene containing a B=B double bond.
@ast
A stable, neutral diborene containing a B=B double bond.
@en
A stable, neutral diborene containing a B=B double bond.
@nl
prefLabel
A stable, neutral diborene containing a B=B double bond.
@ast
A stable, neutral diborene containing a B=B double bond.
@en
A stable, neutral diborene containing a B=B double bond.
@nl
P2093
P356
P1476
A stable, neutral diborene containing a B=B double bond
@en
P2093
Brandon Quillian
Gregory H Robinson
Henry F Schaefer
Paul V R Schleyer
Pingrong Wei
R Bruce King
Yaoming Xie
P304
12412-12413
P356
10.1021/JA075932I
P407
P577
2007-09-21T00:00:00Z