Observation of an acryloyl-thiamin diphosphate adduct in the first step of clavulanic acid biosynthesis.

Observation of an acryloyl-thiamin diphosphate adduct in the first step of clavulanic acid biosynthesis.

Item
http://www.wikidata.org/entity/Q35234168
Detection and time course of formation of major thiamin diphosphate-bound covalent intermediates derived from a chromophoric substrate analogue on benzoylformate decarboxylaseConvergent biosynthetic pathways to β-lactam antibioticsOrganocatalytic Reactions Enabled by N-Heterocyclic CarbenesAn enantioselective Claisen rearrangement catalyzed by N-heterocyclic carbenesThe enzymes of β-lactam biosynthesis.α,β-Unsaturated acyl azoliums from N-heterocyclic carbene catalyzed reactions: observation and mechanistic investigation.Chiral N-Heterocyclic Carbene Catalyzed Annulations of Enals and Ynals with Stable Enols: A Highly Enantioselective Coates-Claisen Rearrangement.Identification of charge transfer transitions related to thiamin-bound intermediates on enzymes provides a plethora of signatures useful in mechanistic studies.A conserved lysine in beta-lactam synthetase assists ring cyclization: Implications for clavam and carbapenem biosynthesis.A Lewis acid-promoted Pinner reaction.Novel supramolecular affinity materials based on (-)-isosteviol as molecular templates.Catalysis with N-heterocyclic carbenes under oxidative conditions.A thorough anion–π interaction study in biomolecules: on the importance of cooperativity effects† †Electronic supplementary information (ESI) available: Fig. 1 and 2, Tables 1–24 and all interactions. See DOI: 10.1039/c5sc01386k.
P2860

Observation of an acryloyl-thiamin diphosphate adduct in the first step of clavulanic acid biosynthesis.

Item
http://www.wikidata.org/entity/Q35234168
description
2007 nî lūn-bûn
@nan
2007 թուականի Դեկտեմբերին հրատարակուած գիտական յօդուած
@hyw
2007 թվականի դեկտեմբերին հրատարակված գիտական հոդված
@hy
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
name
Observation of an acryloyl-thi ...... clavulanic acid biosynthesis.
@ast
Observation of an acryloyl-thi ...... clavulanic acid biosynthesis.
@en
type
label
Observation of an acryloyl-thi ...... clavulanic acid biosynthesis.
@ast
Observation of an acryloyl-thi ...... clavulanic acid biosynthesis.
@en
prefLabel
Observation of an acryloyl-thi ...... clavulanic acid biosynthesis.
@ast
Observation of an acryloyl-thi ...... clavulanic acid biosynthesis.
@en
P1433
P1476
P2093
P2860
P304
P31
P356
P407
P433
P478
P50
P577
P5875
P698
P932
P356
P1433
P1476
Observation of an acryloyl-thi ...... f clavulanic acid biosynthesis
@en
P2093
P2860
P304
P31
P356
P407
P433
P478
P50
P577
P5875
P698
P932