One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center.
about
High-Valent Nonheme Iron Oxidants in Biology: Lessons from Synthetic Fe(IV)=O Complexes.Spectroscopic and theoretical investigation of a complex with an [O═Fe(IV)-O-Fe(IV)═O] core related to methane monooxygenase intermediate Q.Formation of a room temperature stable Fe(V)(O) complex: reactivity toward unactivated C-H bonds.Applications of density functional theory to iron-containing molecules of bioinorganic interest.Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes.Dioxygen activation by nonheme iron enzymes with the 2-His-1-carboxylate facial triad that generate high-valent oxoiron oxidants.Metal-Assisted Oxo Atom Addition to an Fe(III) Thiolate.Equilibrating (L)FeIII-OOAc and (L)FeV(O) Species in Hydrocarbon Oxidations by Bio-Inspired Nonheme Iron Catalysts Using H2O2 and AcOH.DFT studies of the substituent effects of dimethylamino on non-heme active oxidizing species: iron(V)-oxo species or iron(IV)-oxo acetate aminopyridine cation radical species?NaClO-Generated Iron(IV)oxo and Iron(V)oxo TAMLs in Pure Water.The mechanism of stereospecific C-H oxidation by Fe(Pytacn) complexes: bioinspired non-heme iron catalysts containing cis-labile exchangeable sites.ortho-Hydroxylation of aromatic acids by a non-heme Fe(V)=O species: how important is the ligand design?Formation of high-valent iron-oxo species in superoxide reductase: characterization by resonance Raman spectroscopy.Does a higher metal oxidation state necessarily imply higher reactivity toward H-atom transfer? A computational study of C-H bond oxidation by high-valent iron-oxo and -nitrido complexes.Identification of a low-spin acylperoxoiron(III) intermediate in bio-inspired non-heme iron-catalysed oxidations.Water oxidation catalysed by iron complex of N,N'-dimethyl-2,11-diaza[3,3](2,6)pyridinophane. Spectroscopy of iron-oxo intermediates and density functional theory calculations.High-Valent Iron-Oxo and -Nitrido Complexes: Bonding and Reactivity
P2860
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P2860
One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
2012年论文
@zh
2012年论文
@zh-cn
name
One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center.
@ast
One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center.
@en
type
label
One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center.
@ast
One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center.
@en
prefLabel
One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center.
@ast
One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center.
@en
P2093
P2860
P356
P1476
One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center
@en
P2093
Adam T Fiedler
Eckard Münck
Emile L Bominaar
Katherine M Van Heuvelen
Lawrence Que
Raymond F De Hont
Xiaopeng Shan
P2860
P304
11933-11938
P356
10.1073/PNAS.1206457109
P407
P50
P577
2012-07-11T00:00:00Z