Formation of a room temperature stable Fe(V)(O) complex: reactivity toward unactivated C-H bonds.
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Activation of Dioxygen by a TAML Activator in Reverse Micelles: Characterization of an Fe(III)Fe(IV) Dimer and Associated Catalytic ChemistryTuning the reactivity of Fe(V)(O) toward C-H bonds at room temperature: effect of waterPhotochemical generation and kinetic studies of a putative porphyrin-ruthenium(V)-oxo species.To rebound or dissociate? This is the mechanistic question in C-H hydroxylation by heme and nonheme metal-oxo complexes.Mono- and binuclear non-heme iron chemistry from a theoretical perspective.Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes.Water oxidation using earth-abundant transition metal catalysts: opportunities and challenges.Dioxygen activation by nonheme iron enzymes with the 2-His-1-carboxylate facial triad that generate high-valent oxoiron oxidants.Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations.Direct evidence of Fe(V) and Fe(IV) intermediates during reduction of Fe(VI) to Fe(III): a nuclear forward scattering of synchrotron radiation approach.Metal-Assisted Oxo Atom Addition to an Fe(III) Thiolate.Spectroscopic and Reactivity Comparisons of a Pair of bTAML Complexes with FeV═O and FeIV═O Units.Electrochemical Formation of FeV (O) and Mechanism of Its Reaction with Water During O-O Bond Formation.NaClO-Generated Iron(IV)oxo and Iron(V)oxo TAMLs in Pure Water.Mechanistic elucidation of C-H oxidation by electron rich non-heme iron(IV)-oxo at room temperature.Activation parameters as mechanistic probes in the TAML iron(V)-oxo oxidations of hydrocarbons.Selective photocatalytic hydroxylation and epoxidation reactions by an iron complex using water as the oxygen source.Autocatalytic dioxygen activation to produce an iron(v)-oxo complex without any reductants.Reactivity and operational stability of N-tailed TAMLs through kinetic studies of the catalyzed oxidation of orange II by H2 O2 : synthesis and X-ray structure of an N-phenyl TAML.Ligand control in the photochemical generation of high-valent porphyrin-iron-oxo derivatives.Reductive activation of O2 by a bioinspired Fe complex for catalytic epoxidation reactions.Water oxidation catalysed by iron complex of N,N'-dimethyl-2,11-diaza[3,3](2,6)pyridinophane. Spectroscopy of iron-oxo intermediates and density functional theory calculations.High-Valent Iron-Oxo and -Nitrido Complexes: Bonding and Reactivity
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P2860
Formation of a room temperature stable Fe(V)(O) complex: reactivity toward unactivated C-H bonds.
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article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on 16 January 2014
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Formation of a room temperature stable Fe
@nl
Formation of a room temperatur ...... toward unactivated C-H bonds.
@en
type
label
Formation of a room temperature stable Fe
@nl
Formation of a room temperatur ...... toward unactivated C-H bonds.
@en
prefLabel
Formation of a room temperature stable Fe
@nl
Formation of a room temperatur ...... toward unactivated C-H bonds.
@en
P2093
P2860
P50
P356
P1476
Formation of a room temperatur ...... toward unactivated C-H bonds.
@en
P2093
Basab B Dhar
Michael P Hendrich
Munmun Ghosh
Sayam Sen Gupta
P2860
P304
P356
10.1021/JA412537M
P407
P577
2014-01-16T00:00:00Z