about
Moving protons and electrons in biomimetic systemsDirect Selective Oxidative Functionalization of C-H Bonds with H₂O₂: Mn-Aminopyridine Complexes Challenge the Dominance of Non-Heme Fe CatalystsSulfide Oxidation by O2: Synthesis, Structure and Reactivity of Novel Sulfide-Incorporated Fe(II) Bis(imino)pyridine ComplexesIntramolecular C-H and C-F Bond Oxygenation Mediated by a Putative Terminal Oxo Species in Tetranuclear Iron ComplexesDesign and synthesis of a dinucleating ligand system with varying terminal donor functions that provides no bridging donor and its application to the synthesis of a series of Fe(III)-μ-O-Fe(III) complexes.A two-state reactivity model explains unusual kinetic isotope effect patterns in C-H bond cleavage by nonheme oxoiron(IV) complexes.Sulfur versus iron oxidation in an iron-thiolate model complexReactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts.Generating Cu(II)-oxyl/Cu(III)-oxo species from Cu(I)-alpha-ketocarboxylate complexes and O2: in silico studies on ligand effects and C-H-activation reactivity.The fundamental role of exchange-enhanced reactivity in C-H activation by S=2 oxo iron(IV) complexesThe crystal structure of a high-spin oxoiron(IV) complex and characterization of its self-decay pathwayManganese catalysts for C-H activation: an experimental/theoretical study identifies the stereoelectronic factor that controls the switch between hydroxylation and desaturation pathways.Mechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups.Nonheme oxo-iron(IV) intermediates form an oxyl radical upon approaching the C-H bond activation transition state.Characterization of a tricationic trigonal bipyramidal iron(IV) cyanide complex, with a very high reduction potential, and its iron(II) and iron(III) congeners.Nuclear resonance vibrational spectroscopy on the Fe(IV)=O S=2 non-heme site in TMG3tren: experimentally calibrated insights into reactivity.Modeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand.High-Valent Nonheme Iron Oxidants in Biology: Lessons from Synthetic Fe(IV)=O Complexes.Tuning the reactivity of Fe(V)(O) toward C-H bonds at room temperature: effect of waterTriggering the generation of an iron(IV)-oxo compound and its reactivity toward sulfides by Ru(II) photocatalysis.Theoretical study of the mechanism of oxoiron(IV) formation from H2O2 and a nonheme iron(II) complex: O-O cleavage involving proton-coupled electron transferA more reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a cis-labile site.Characterization and reactivity of a terminal nickel(III)-oxygen adductTuning the Reactivity of Mononuclear Nonheme Manganese(IV)-Oxo Complexes by Triflic Acid.Synthesis and characterisation of a mesocyclic tripodal triamine ligand.Oxygen-independent decarbonylation of aldehydes by cyanobacterial aldehyde decarbonylase: a new reaction of diiron enzymes.Toward the synthesis of more reactive S = 2 non-heme oxoiron(IV) complexes.Magnetic circular dichroism and computational study of mononuclear and dinuclear iron(IV) complexes.One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center.π-Frontier molecular orbitals in S = 2 ferryl species and elucidation of their contributions to reactivity.Nonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity.Intramolecular gas-phase reactions of synthetic nonheme oxoiron(IV) ions: proximity and spin-state reactivity rulesA Mononuclear Carboxylate-Rich Oxoiron(IV) Complex: a Structural and Functional Mimic of TauD Intermediate 'J'TET family proteins: oxidation activity, interacting molecules, and functions in diseases.Synthetic iron-oxo "diamond core" mimics structure of key intermediate in methane monooxygenase catalytic cycleTryptophan-mediated charge-resonance stabilization in the bis-Fe(IV) redox state of MauG.Axial ligand effects on the geometric and electronic structures of nonheme oxoiron(IV) complexesCopper(I)-alpha-ketocarboxylate complexes: characterization and O2 reactions that yield copper-oxygen intermediates capable of hydroxylating arenesProton- and reductant-assisted dioxygen activation by a nonheme iron(II) complex to form an oxoiron(IV) intermediateAn inverted and more oxidizing isomer of [Fe(IV)(O)(tmc)(NCCH3)]2+
P2860
Q26829547-E133E3B7-C0E8-4BFD-BBF9-A2FB05DE4D09Q28066116-089F827B-3754-4DE8-BEE2-F83BD13C6F5AQ28677812-2AF6C788-7C26-494D-A362-647A2C7831D3Q28834032-F1E3CAB4-EF74-487D-94CF-CD457459BFE3Q31038572-AE0583FC-16A1-401C-A92D-A103B47ECD43Q33705333-3C29393F-479B-4AB9-8184-41B2096D2DF3Q33744230-28DC0AF8-CF01-4C62-9A12-72236DEE2B47Q33824275-A761CBC3-4CE2-45C9-89E1-60025C62503DQ33883930-1B4A5507-1089-4D03-BD20-95D5C306A671Q33899773-44288A0F-0E8A-467B-AD70-8B0BB7B91CF2Q33990453-690C7269-07C8-4B06-A1FB-8ACCFBF76DC1Q33992789-A73298B6-428C-4E15-9833-FDCB48D9182EQ34361066-07E7F42E-5DE1-4CB1-90CC-1407EBB03B56Q34534021-9508AC63-0071-4848-B524-624C77BBD4D0Q34728822-8E037220-CB9F-4F28-B67E-4F3F827D58E2Q34895057-2B762F3F-E58A-4DB1-AD14-9BF7E1071A82Q34990257-4AE0E065-B73F-4955-A849-CC4E9362E901Q35067238-46D8C234-5B85-4DED-999B-F0D489B59453Q35093837-2142FF59-4017-4E2F-90B4-92F7FF83B22DQ35102626-8F7ED188-4889-44EF-8F07-92ACBE8014BCQ35104404-D1783102-B2EF-496C-9E2E-6F1137B602ABQ35147804-A3A07A3A-CC35-40D2-819B-926BCC21BC24Q35462178-4F9846AB-5A53-457C-BF5B-09A9F1858620Q35801360-0F715D00-1DFC-4D5B-B2CC-6B92AAD2C1BBQ35815761-59684E21-D68C-456C-997E-C89FFF6B9022Q35909799-6D3D87A3-A9D9-4066-BB7E-3581F18F9EC1Q35974119-7388220A-AACA-4652-AB6B-B977870E8296Q36093562-8A532848-697C-4997-A2EC-E4AA4A99F9DCQ36132697-361C4CD3-AF8D-4BBC-9FDB-CA5A43F34C41Q36221936-31F1719D-65D6-4D1B-878A-BA2548584EA3Q36448772-01F5396B-80DC-4D4D-8482-591B0E653967Q36452377-534AB891-81C4-44E9-9BEB-408E4803AA1BQ36482216-DA537B42-6F88-4E22-878D-B20A871B2ACFQ36668364-CC212372-CA70-45AB-A36F-D3F83731087AQ36693230-3B057A34-D583-464F-9DF5-172494A2172EQ36932428-2F16C3F5-9BBC-4A47-BAC5-1467AB92CC6EQ36952383-1C5A9D6B-5C07-4CC4-A3CF-1FA13EBE8ED5Q37059200-C11799C7-9F4A-4EC2-B83F-F489E8458638Q37120630-70AB1344-8F4D-4DE6-8FCE-A0532BDBBA2FQ37129704-4874BEFD-555F-4CE6-B9E2-1D9DA74A5BDA
P2860
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
2007年论文
@zh
2007年论文
@zh-cn
name
The road to non-heme oxoferryls and beyond.
@en
type
label
The road to non-heme oxoferryls and beyond.
@en
prefLabel
The road to non-heme oxoferryls and beyond.
@en
P356
P1476
The road to non-heme oxoferryls and beyond.
@en
P2093
Lawrence Que
P304
P356
10.1021/AR700024G
P577
2007-06-27T00:00:00Z