Proton- and reductant-assisted dioxygen activation by a nonheme iron(II) complex to form an oxoiron(IV) intermediate
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The crystal structure of a high-spin oxoiron(IV) complex and characterization of its self-decay pathwayModeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand.Photochemical oxidation of a manganese(III) complex with oxygen and toluene derivatives to form a manganese(V)-oxo complexHigh-Valent Nonheme Iron Oxidants in Biology: Lessons from Synthetic Fe(IV)=O Complexes.A more reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a cis-labile site.Synthesis, structural studies, and oxidation catalysis of the manganese(II), iron(II), and copper(II) complexes of a 2-pyridylmethyl pendant armed side-bridged cyclam.[Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation.Sulfur oxygenation in biomimetic non-heme iron-thiolate complexes.Nonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity.A Mononuclear Carboxylate-Rich Oxoiron(IV) Complex: a Structural and Functional Mimic of TauD Intermediate 'J'Sc3+-triggered oxoiron(IV) formation from O2 and its non-heme iron(II) precursor via a Sc3+-peroxo-Fe3+ intermediate.Inhibition of the purified 20S proteasome by non-heme iron complexes.A synthetic high-spin oxoiron(IV) complex: generation, spectroscopic characterization, and reactivity.An Ultra-Stable Oxoiron(IV) Complex and Its Blue Conjugate Base.Applications of density functional theory to iron-containing molecules of bioinorganic interest.Assessment of electronic structure methods for the determination of the ground spin states of Fe(ii), Fe(iii) and Fe(iv) complexes.Synthesis and structural studies of two pyridine-armed reinforced cyclen chelators and their transition metal complexes.Aromatic C-F Hydroxylation by Nonheme Iron(IV)-Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations.O2 activation by bis(imino)pyridine iron(II)-thiolate complexes.Redox inactive metal ion triggered N-dealkylation by an iron catalyst with dioxygen activation: a lesson from lipoxygenases.Redox potential and C-H bond cleaving properties of a nonheme Fe(IV)=O complex in aqueous solution.Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective.Electrochemical study of a nonheme Fe(ii) complex in the presence of dioxygen. Insights into the reductive activation of O2 at Fe(ii) centers.M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR).Characterization of a high-spin non-heme Fe(III)-OOH intermediate and its quantitative conversion to an Fe(IV)═O complex.Metal-Assisted Oxo Atom Addition to an Fe(III) Thiolate.Addition of dioxygen to an N4S(thiolate) iron(II) cysteine dioxygenase model gives a structurally characterized sulfinato-iron(II) complexA direct method for the N-tetraalkylation of azamacrocycles.Near-stoichiometric conversion of H(2)O(2) to Fe(IV)=O at a nonheme iron(II) center. Insights into the O-O bond cleavage step.Activation of dioxygen by a mononuclear non-heme iron complex: characterization of a Fe(III)(OOH) intermediate.A change in the oxidation state of iron: scandium is not innocent.Acid-triggered O-O bond heterolysis of a nonheme FeIII(OOH) species for the stereospecific hydroxylation of strong C-H bonds.Hydroxylation versus Halogenation of Aliphatic C-H Bonds by a Dioxygen-Derived Iron-Oxygen Oxidant: Functional Mimicking of Iron Halogenases.Olefin cis-Dihydroxylation and Aliphatic C-H Bond Oxygenation by a Dioxygen-Derived Electrophilic Iron-Oxygen Oxidant.Hydroxylation of aromatics with the help of a non-haem FeOOH: a mechanistic study under single-turnover and catalytic conditions.Autocatalytic dioxygen activation to produce an iron(v)-oxo complex without any reductants.Reductive activation of O2 by a bioinspired Fe complex for catalytic epoxidation reactions.Lewis Acid Coupled Electron Transfer of Metal-Oxygen Intermediates.The "innocent" role of Sc(3+) on a non-heme Fe catalyst in an O2 environment.Switching on oxygen activation by cobalt complexes of pentadentate ligands.
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Proton- and reductant-assisted dioxygen activation by a nonheme iron(II) complex to form an oxoiron(IV) intermediate
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article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on January 2008
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Proton- and reductant-assisted dioxygen activation by a nonheme iron
@nl
Proton- and reductant-assisted ...... rm an oxoiron(IV) intermediate
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type
label
Proton- and reductant-assisted dioxygen activation by a nonheme iron
@nl
Proton- and reductant-assisted ...... rm an oxoiron(IV) intermediate
@en
prefLabel
Proton- and reductant-assisted dioxygen activation by a nonheme iron
@nl
Proton- and reductant-assisted ...... rm an oxoiron(IV) intermediate
@en
P2093
P2860
P356
P1476
Proton- and reductant-assisted ...... rm an oxoiron(IV) intermediate
@en
P2093
Aurore Thibon
Eckard Münck
Jason England
Jean-Jacques Girerd
Jonathan R Frisch
Lawrence Que
Marlène Martinho
Victor G Young
P2860
P304
P356
10.1002/ANIE.200801832
P407
P577
2008-01-01T00:00:00Z