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Cooccupancy of the outer vestibule of voltage-gated sodium channels by micro-conotoxin KIIIA and saxitoxin or tetrodotoxinSynthetic studies towards Zetekitoxin AB: preparation of 4,5-epi-11-hydroxy-saxitoxinol.Syntheses of Cyclic Guanidine-Containing Natural Products.A stereocontrolled synthesis of (+)-saxitoxin.Marked difference in saxitoxin and tetrodotoxin affinity for the human nociceptive voltage-gated sodium channel (Nav1.7) [corrected]Mutant cycle analysis with modified saxitoxins reveals specific interactions critical to attaining high-affinity inhibition of hNaV1.7.A stereoselective synthesis of the bromopyrrole natural product (-)-agelastatin A.Hypervalent iodine reagents in the total synthesis of natural products.Transition-metal-catalyzed aminations and aziridinations of C-H and C=C bonds with iminoiodinanes.Recent development of synthetic preparation methods for guanidines via transition metal catalysis.Synthesis of saxitoxin derivatives bearing guanidine and urea groups at C13 and evaluation of their inhibitory activity on voltage-gated sodium channels.Visualizing dermal permeation of sodium channel modulators by mass spectrometric imaging.Stereoselective Synthesis of Cyclic Guanidines by Directed Diamination of Unactivated Alkenes.Synthesis of Cyclic Guanidines via Silver-Catalyzed Intramolecular Alkene Hydroamination Reactions of N-Allylguanidines.Iron(II)-catalyzed intermolecular amino-oxygenation of olefins through the N-O bond cleavage of functionalized hydroxylamines.Synthesis of bicyclic guanidines via cascade hydroamination/Michael additions of mono-N-acryloylpropargylguanidines.Synthesis of cyclic guanidines via Pd-catalyzed alkene carboamination.Catalytic oxyamidation of indoles.Palladium(0)-catalyzed intramolecular dearomative arylation of pyrroles.Synthesis of azasilacyclopentenes and silanols via Huisgen cycloaddition-initiated C-H bond insertion cascades.Transition metal-catalyzed iodine(iii)-mediated nitrene transfer reactions: efficient tools for challenging syntheses.Synthesis and Identification of Key Biosynthetic Intermediates for the Formation of the Tricyclic Skeleton of Saxitoxin.Synthesis of Cyclic Guanidines Bearing N-Arylsulfonyl and N-Cyano Protecting Groups via Pd-Catalyzed Alkene Carboamination Reactions.
P2860
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P2860
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
@pt
bilimsel makale
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scientific article published on 29 August 2008
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
A stereoselective synthesis of (+)-gonyautoxin 3.
@en
A stereoselective synthesis of
@nl
type
label
A stereoselective synthesis of (+)-gonyautoxin 3.
@en
A stereoselective synthesis of
@nl
prefLabel
A stereoselective synthesis of (+)-gonyautoxin 3.
@en
A stereoselective synthesis of
@nl
P2860
P356
P1476
A stereoselective synthesis of (+)-gonyautoxin 3.
@en
P2093
John V Mulcahy
P2860
P304
12630-12631
P356
10.1021/JA805651G
P407
P577
2008-08-29T00:00:00Z