Asymmetric synthesis of tertiary alcohols and alpha-tertiary amines via Cu-catalyzed C-C bond formation to ketones and ketimines.
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Rapid decarboxylative allylation of nitroalkanes.Copper- and copper-N-heterocyclic carbene-catalyzed C-H activating carboxylation of terminal alkynes with CO2 at ambient conditions.Enantioselective Synthesis of Carbo- and Heterocycles through a CuH-Catalyzed Hydroalkylation Approach.Enantio- and Diastereoselective 1,2-Additions to α-Ketoesters with Diborylmethane and Substituted 1,1-Diborylalkanes.Copper-Catalyzed Enantioselective Addition of Styrene-Derived Nucleophiles to Imines Enabled by Ligand-Controlled Chemoselective HydrocuprationCopper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.Asymmetric palladium-catalyzed intramolecular alpha-arylation of aldehydesThe Enantioselective Addition of Alkyne Nucleophiles to Carbonyl Groups.Enantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols To Form Allylic Quaternary Centers.Asymmetric synthesis of tertiary thiols and thioethers.Enantioselective aldol reactions catalyzed by chiral phosphine oxides.Catalytic enantioselective decarboxylative reactions using organocatalysts.Chemoenzymatic dynamic kinetic resolution: a powerful tool for the preparation of enantiomerically pure alcohols and amines.Stereoselective borylative ketone-diene coupling.Various difunctionalizations of acrylamide: an efficient approach to synthesize oxindoles.Enantioselective allylation, crotylation, and reverse prenylation of substituted isatins: iridium-catalyzed C-C bond-forming transfer hydrogenation.Catalytic enantioselective addition of Grignard reagents to aromatic silyl ketimines.Tertiary alcohol preferred: Hydroxylation of trans-3-methyl-L-proline with proline hydroxylases.Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to α,β-Unsaturated Carbonyl Compounds.Enantioselective copper catalysed, direct functionalisation of allenes via allyl copper intermediates.Catalytic asymmetric synthesis of CF3-substituted tertiary propargylic alcohols via direct aldol reaction of α-N3 amideEnantioselective synthesis of boron-substituted quaternary carbons by NHC-Cu-catalyzed boronate conjugate additions to unsaturated carboxylic esters, ketones, or thioesters.Enantioselective Generation of Adjacent Stereocenters in a Copper-Catalyzed Three-Component Coupling of Imines, Allenes, and DiboranesEnantioselective construction of pyrrolidines by palladium-catalyzed asymmetric [3 + 2] cycloaddition of trimethylenemethane with imines.NHC-Cu-Catalyzed Silyl Conjugate Additions to Acyclic and Cyclic Dienones and Dienoates. Efficient Site-, Diastereo- and Enantioselective Synthesis of Carbonyl-Containing Allylsilanes.Enantioselective synthesis of boron-substituted quaternary carbon stereogenic centers through NHC-catalyzed conjugate additions of (pinacolato)boron units to enones.Direct catalytic enantio- and diastereoselective ketone aldol reactions of isocyanoacetates.Rhodium-catalyzed spirocyclic sultam synthesis by [3+2] annulation with cyclic N-sulfonyl ketimines and alkynes.Synthesis of chiral aliphatic amines through asymmetric hydrogenation.Chiral Brønsted acid-catalyzed enantioselective addition of indoles to ketimines.Diamine-catalyzed addition of ZnEt2 to PhC(O)CF3 : two mechanisms and autocatalytic asymmetric enhancement.Copper-Catalyzed Amination of Congested and Functionalized α-Bromocarboxamides with either Amines or Ammonia at Room Temperature.Phase-transfer-catalysed asymmetric synthesis of tetrasubstituted allenes.Asymmetric Grignard Synthesis of Tertiary Alcohols through Rational Ligand Design.Asymmetric organocatalytic synthesis of tertiary azomethyl alcohols: key intermediates towards azoxy compounds and α-hydroxy-β-amino esters.A Regio- and Enantioselective CuH-Catalyzed Ketone Allylation with Terminal Allenes.Tandem Oxidative Derivatization of Nitrene Insertion Products for the Highly Diastereoselective Synthesis of 1,3-aminoalcohols.Copper(I)-Catalyzed Enantioselective Nucleophilic Borylation of Aliphatic Ketones: Synthesis of Enantioenriched Chiral Tertiary α-Hydroxyboronates.Catalytic diastereo- and enantioselective additions of versatile allyl groups to N-H ketimines.Copper-Catalyzed Enantioselective Alkylation of Enolizable Ketimines with Organomagnesium Reagents.
P2860
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P2860
Asymmetric synthesis of tertiary alcohols and alpha-tertiary amines via Cu-catalyzed C-C bond formation to ketones and ketimines.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on 21 June 2008
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
Asymmetric synthesis of tertia ...... tion to ketones and ketimines.
@en
Asymmetric synthesis of tertia ...... tion to ketones and ketimines.
@nl
type
label
Asymmetric synthesis of tertia ...... tion to ketones and ketimines.
@en
Asymmetric synthesis of tertia ...... tion to ketones and ketimines.
@nl
prefLabel
Asymmetric synthesis of tertia ...... tion to ketones and ketimines.
@en
Asymmetric synthesis of tertia ...... tion to ketones and ketimines.
@nl
P356
P1433
P1476
Asymmetric synthesis of tertia ...... tion to ketones and ketimines.
@en
P2093
Masakatsu Shibasaki
Motomu Kanai
P304
P356
10.1021/CR078340R
P577
2008-06-21T00:00:00Z