Enantioselective allylation, crotylation, and reverse prenylation of substituted isatins: iridium-catalyzed C-C bond-forming transfer hydrogenation.
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The mechanism and an improved asymmetric allylboration of ketones catalyzed by chiral biphenolsDiastereo- and enantioselective anti-alkoxyallylation employing allylic gem-dicarboxylates as allyl donors via iridium-catalyzed transfer hydrogenation.anti-Diastereo- and enantioselective carbonyl (hydroxymethyl)allylation from the alcohol or aldehyde oxidation level: allyl carbonates as allylmetal surrogates.Iridium-catalyzed anti-diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol or aldehyde oxidation level.Total synthesis of (+)-roxaticin via C-C bond forming transfer hydrogenation: a departure from stoichiometric chiral reagents, auxiliaries, and premetalated nucleophiles in polyketide construction.Enantioselective iridium-catalyzed vinylogous Reformatsky-aldol reaction from the alcohol oxidation level: linear regioselectivity by way of carbon-bound enolatesIridium-catalyzed anti-diastereo- and enantioselective carbonyl (α-trifluoromethyl)allylation from the alcohol or aldehyde oxidation level.Chiral calcium VAPOL phosphate mediated asymmetric chlorination and Michael reactions of 3-substituted oxindoles.Highly enantioselective catalytic benzoyloxylation of 3-aryloxindoles using chiral VAPOL calcium phosphateSimple organic molecules as catalysts for enantioselective synthesis of amines and alcoholsEnantioselective iridium-catalyzed carbonyl allylation from the alcohol oxidation level via transfer hydrogenation: minimizing pre-activation for synthetic efficiencyFormation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation.Allenes and computational chemistry: from bonding situations to reaction mechanisms.Catalytic enantioselective OFF ↔ ON activation processes initiated by hydrogen transfer: concepts and challenges.Alkyne-aldehyde reductive C-C coupling through ruthenium-catalyzed transfer hydrogenation: direct regio- and stereoselective carbonyl vinylation to form trisubstituted allylic alcohols in the absence of premetallated reagents.Enantioselective carbonyl allylation, crotylation, and tert-prenylation of furan methanols and furfurals via iridium-catalyzed transfer hydrogenation.Protecting-group-free synthesis of 3-tert-prenylated oxindoles: contiguous all-carbon quaternary centers via tertiary neopentyl substitution.Synthesis of the cytotrienin A core via metal catalyzed C-C coupling.An N-heterocyclic carbene/Lewis acid strategy for the stereoselective synthesis of spirooxindole lactones.Organocatalytic asymmetric Michael addition of unprotected 3-substituted oxindoles to 1,4-naphthoquinoneRegioselective ruthenium catalyzed hydrohydroxyalkylation of dienes with 3-hydroxy-2-oxindoles: prenylation, geranylation, and beyond.Enhanced anti-diastereo- and enantioselectivity in alcohol-mediated carbonyl crotylation using an isolable single component iridium catalyst.Catalytic asymmetric synthesis of substituted 3-hydroxy-2-oxindoles.Catalytic enantioselective allylation of ketimines by using palladium pincer complexes with chiral bis(imidazoline)s.Synthesis of 3,3-Disubstituted Oxindoles by Palladium-Catalyzed Asymmetric Intramolecular α-Arylation of Amides: Reaction Development and Mechanistic Studies.Catalytic Asymmetric Direct Vinylogous Aldol Reaction of Isatins with β,γ-Unsaturated Butenolides.A highly enantioselective Hg(ii)-catalyzed Sakurai-Hosomi reaction of isatins with allyltrimethylsilanes.Magnesium(II)-catalyzed asymmetric hetero-Diels-Alder reaction of Brassard's dienes with isatins.Catalytic asymmetric addition of alkyl enol ethers to 1,2-dicarbonyl compounds: highly enantioselective synthesis of substituted 3-alkyl-3-hydroxyoxindoles.Chiral phosphine-catalyzed asymmetric allylic alkylation of 3-substituted benzofuran-2(3H)-ones or oxindoles with Morita-Baylis-Hillman carbonates.Catalytic enantioselective amide allylation of isatins and its application in the synthesis of 2-oxindole derivatives spiro-fused to the α-methylene-γ-butyrolactone functionality.Cationic Ir/Me-BIPAM-Catalyzed Asymmetric Intramolecular Direct Hydroarylation of α-KetoamidesMe-BIPAM for the Synthesis of Optically Active 3-Aryl-3-hydroxy-2-oxindoles by Ruthenium-catalyzed Addition of Arylboronic Acids to IsatinsSynthesis of Furanose Spirooxindoles via 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Catalyzed Aldol Reactions of a Pyruvic Aldehyde DerivativeOrganocatalytic asymmetric Henry reaction of isatins: Highly enantioselective synthesis of 3-hydroxy-2-oxindoles
P2860
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P2860
Enantioselective allylation, crotylation, and reverse prenylation of substituted isatins: iridium-catalyzed C-C bond-forming transfer hydrogenation.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年学术文章
@wuu
2009年学术文章
@zh-cn
2009年学术文章
@zh-hans
2009年学术文章
@zh-my
2009年学术文章
@zh-sg
2009年學術文章
@yue
2009年學術文章
@zh
2009年學術文章
@zh-hant
name
Enantioselective allylation, c ...... orming transfer hydrogenation.
@en
Enantioselective allylation, c ...... orming transfer hydrogenation.
@nl
type
label
Enantioselective allylation, c ...... orming transfer hydrogenation.
@en
Enantioselective allylation, c ...... orming transfer hydrogenation.
@nl
prefLabel
Enantioselective allylation, c ...... orming transfer hydrogenation.
@en
Enantioselective allylation, c ...... orming transfer hydrogenation.
@nl
P2860
P356
P1476
Enantioselective allylation, c ...... orming transfer hydrogenation.
@en
P2093
Junji Itoh
Soo Bong Han
P2860
P304
P356
10.1002/ANIE.200902328
P407
P577
2009-01-01T00:00:00Z