Recent progress in the generation and use of nitrogen-centred radicals.
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Synthetic Strategies for 5- and 6-Membered Ring Azaheterocycles Facilitated by Iminyl RadicalsCopper-catalyzed oxidative amination and allylic amination of alkenes.Cu(I)-catalyzed sequential diamination and dehydrogenation of terminal olefins: a facile approach to imidazolinones.Regioselective C-H bond amination by aminoiodanes.Toward the ABCD Core of the Calyciphylline A-Type Daphniphyllum Alkaloids: Solvent non-Innocence in Neutral Aminyl Radical Cyclizations.Total Synthesis of Gelsenicine via a Catalyzed Cycloisomerization StrategyCatalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation.Facile Cu(I)-catalyzed oxidative coupling of anilines to azo compounds and hydrazines with diaziridinone under mild conditions.Rapid access to the heterocyclic core of the calyciphylline A and daphnicyclidin A-type Daphniphyllum alkaloids via tandem cyclization of a neutral aminyl radical.Samarium diiodide induced ketyl-(het)arene cyclisations towards novel N-heterocycles.Some aspects of radical chemistry in the assembly of complex molecular architectures.Complexes with nitrogen-centered radical ligands: classification, spectroscopic features, reactivity, and catalytic applications.O-Acyl oximes: versatile building blocks for N-heterocycle formation in recent transition metal catalysis.New amination strategies based on nitrogen-centered radical chemistry.N-Acyloxyphthalimides as nitrogen radical precursors in the visible light photocatalyzed room temperature C-H amination of arenes and heteroarenesFunctionalization of C-H Bonds by Photoredox Catalysis.Triiodide-Mediated δ-Amination of Secondary C-H Bonds.Synthesis and characterization of a series of structurally and electronically diverse Fe(II) complexes featuring a family of triphenylamido-amine ligands.Enantioselective catalytic β-amination through proton-coupled electron transfer followed by stereocontrolled radical-radical coupling.A mild, ferrocene-catalyzed C-H imidation of (hetero)arenesIntermolecular addition reactions of N-alkyl-N-chlorosulfonamides to unsaturated compoundsEnantioselective direct α-amination of aldehydes via a photoredox mechanism: a strategy for asymmetric amine fragment coupling.Nitrene Radical Intermediates in Catalytic Synthesis.Visible-Light-Mediated Generation of Nitrogen-Centered Radicals: Metal-Free Hydroimination and Iminohydroxylation Cyclization Reactions.Amide-directed photoredox-catalysed C-C bond formation at unactivated sp3 C-H bonds.Radical carbonitrosation and recycling of the waste gas nitrogen monoxide.Isolation of a carborane-fused triazole radical anion.Formation of N-sulfonyl imines from iminoiodinanes by iodine-promoted, N-centered radical sulfonamidation of aldehydes.Synthesis of Arylamines via Aminium Radicals.Visible-light-mediated, nitrogen-centered radical amination of tertiary alkyl halides under metal-free conditions to form α-tertiary amines.Endeavors to access molecular complexity: strategic use of free radicals in natural product synthesis.Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer.Photoredox Imino Functionalizations of Olefins.A Simple and Broadly Applicable C-N Bond Forming Dearomatization Protocol Enabled by Bifunctional Amino Reagents.Electrochemical Synthesis of Imidazo-Fused N-Heteroaromatic Compounds through a C-N Bond-Forming Radical Cascade.Complementary Strategies for Directed C(sp3 )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer.A Copper-Catalyzed Aerobic [1,3]-Nitrogen Shift through Nitrogen-Radical 4-exo-trig Cyclization.Electrochemical C-H/N-H Functionalization for the Synthesis of Highly Functionalized (Aza)indoles.Copper-Catalyzed Intramolecular Oxidative Amination of Unactivated Internal Alkenes.Dehydro-oxazole, thiazole and imidazole radicals: insights into the electronic structure, stability and reactivity aspects.
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Recent progress in the generation and use of nitrogen-centred radicals.
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
@pt
bilimsel makale
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scientific article published on 17 June 2008
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vedecký článok
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vetenskaplig artikel
@sv
videnskabelig artikel
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vědecký článek
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name
Recent progress in the generation and use of nitrogen-centred radicals.
@en
Recent progress in the generation and use of nitrogen-centred radicals.
@nl
type
label
Recent progress in the generation and use of nitrogen-centred radicals.
@en
Recent progress in the generation and use of nitrogen-centred radicals.
@nl
prefLabel
Recent progress in the generation and use of nitrogen-centred radicals.
@en
Recent progress in the generation and use of nitrogen-centred radicals.
@nl
P356
P1476
Recent progress in the generation and use of nitrogen-centred radicals.
@en
P2093
Samir Z Zard
P304
P356
10.1039/B613443M
P577
2008-06-17T00:00:00Z