Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer. - Wikidata - awgldk - TriplyDB

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer.

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer.

http://www.wikidata.org/entity/Q47108193

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Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide.Separating Proton and Electron Transfer Effects in Three-Component Concerted Proton-Coupled Electron Transfer Reactions.Photoredox-Mediated Routes to Radicals: The Value of Catalytic Radical Generation in Synthetic Methods Development.Cooperative Light-Activated Iodine and Photoredox Catalysis for the Amination of Csp3 -H Bonds.Copper-catalyzed oxidative C(sp3)-H/C(sp2)-H cross-coupling en route to carbocyclic rings.Enantioselective catalytic β-amination through proton-coupled electron transfer followed by stereocontrolled radical-radical coupling.Direct Aldehyde Csp2 -H Functionalization through Visible-Light-Mediated Photoredox Catalysis.Transforming Olefins into γ,δ-Unsaturated Nitriles through Copper Catalysis.Photoredox Imino Functionalizations of Olefins.Distal radical migration strategy: an emerging synthetic means.C-H Insertions by Iron Porphyrin Carbene: Basic Mechanism and Origin of Substrate Selectivity.Complementary Strategies for Directed C(sp3 )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer.Asymmetric alkylation of remote C(sp3)-H bonds by combining proton-coupled electron transfer with chiral Lewis acid catalysis.General, Mild, and Selective Method for Desaturation of Aliphatic Amines.Intramolecular Hydrogen Atom Transfer in Aminyl Radical at Room Temperature with Large Kinetic Isotope Effect.A Visible-Light-Driven Iminyl Radical-Mediated C-C Single Bond Cleavage/Radical Addition Cascade of Oxime Esters.Supramolecular Recognition Allows Remote, Site-Selective C-H Oxidation of Methylenic Sites in Linear Amines.Amidinyl Radical Formation through Anodic N-H Bond Cleavage and Its Application in Aromatic C-H Bond Functionalization.Cooperative Polar/Steric Strategy in Achieving Site-Selective Photocatalyzed C(sp3 )-H Functionalization.Directed γ-C(sp3)-H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis.General, Auxiliary-Enabled Photoinduced Pd-Catalyzed Remote Desaturation of Aliphatic Alcohols.Palladium-Catalyzed Atom-Transfer Radical Cyclization at Remote Unactivated C(sp3 )-H Sites: Hydrogen-Atom Transfer of Hybrid Vinyl Palladium Radical Intermediates.Controllable Remote C-H Bond Functionalization by Visible-Light Photocatalysis.Photoinduced Remote Functionalisations by Iminyl Radical Promoted C-C and C-H Bond Cleavage Cascades.α-Aminoxy-Acid-Auxiliary-Enabled Intermolecular Radical γ-C(sp3 )-H Functionalization of Ketones.Sulfamate Esters Guide Selective Radical-Mediated Chlorination of Aliphatic C-H Bonds.Radical-mediated intramolecular β-C(sp3)-H amidation of alkylimidates: facile synthesis of 1,2-amino alcohols.Alkynylation of Csp2 (O)-H Bonds Enabled by Photoredox-Mediated Hydrogen-Atom Transfer.A General Strategy for Aliphatic C-H Functionalization Enabled by Organic Photoredox Catalysis.Hydrogen-Atom Transfer (HAT) Initiated by Intramolecular Ligand-Metal Electron Transfer.γ-Functionalizations of Amines through Visible-Light-Mediated, Redox-Neutral C-C Bond Cleavage.Site-selective bromination of sp3 C-H bonds.β C–H di-halogenation via iterative hydrogen atom transfer† †Electronic supplementary information (ESI) available. CCDC 1581032. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc01214h.Enantioselective radical process for synthesis of chiral indolines by metalloradical alkylation of diverse C(sp3)-H bonds.Photocatalytic reverse polarity Povarov reaction Diverse secondary C(sp)-H bond functionalization site-selective trifluoroacetoxylation of aliphatic amines Alkinylierung von Csp2 (O)-H-Bindungen durch Photoredox-vermittelten Wasserstoffatomtransfer Kooperative Licht-aktivierte Iod- und Photoredox-Katalyse zur Aminierung von Csp3 -H-Bindungen Asymmetric remote C-H borylation of internal alkenes via alkene isomerization Metal-free alcohol-directed regioselective heteroarylation of remote unactivated C(sp)-H bonds

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P2860

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer.

http://www.wikidata.org/entity/Q47108193

description

2016 nî lūn-bûn

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2016年の論文

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2016年学术文章

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2016年学术文章

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2016年学术文章

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2016年学术文章

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2016年学术文章

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2016年学术文章

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2016年學術文章

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2016年學術文章

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name

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer.

@en

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer.

@nl

type

label

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer.

@en

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer.

@nl

prefLabel

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer.

@en

Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer.

@nl

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Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer.

@en

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Carol J Gu

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Gilbert J Choi

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Qilei Zhu

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Robert R Knowles

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P2860

Thermochemistry of proton-coupled electron transfer reagents and its implications

Palladium-catalysed transannular C-H functionalization of alicyclic amines

Combined effects on selectivity in Fe-catalyzed methylene oxidation.

Oxidative aliphatic C-H fluorination with fluoride ion catalyzed by a manganese porphyrin.

Understanding hydrogen atom transfer: from bond strengths to Marcus theory.

Proton-coupled electron transfer in biology: results from synergistic studies in natural and model systems.

Proton-coupled electron transfer: a reaction chemist's view.

Recent progress in the generation and use of nitrogen-centred radicals.

If C-H bonds could talk: selective C-H bond oxidation

Proton-coupled electron transfer.

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10.1038/NATURE19811

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