A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres.
about
Enantioselective synthesis of α-secondary and α-tertiary piperazin-2-ones and piperazines by catalytic asymmetric allylic alkylation.Transition metal-catalyzed decarboxylative allylation and benzylation reactionsSynthesis and Exploration of Electronically Modified (R)-5,5-Dimethyl-(p-CF3)3-i-PrPHOX in Palladium-Catalyzed Enantio- and Diastereoselective Allylic Alkylation: A Practical Alternative to (R)-(p-CF3)3-t-BuPHOX.Intercepted Decarboxylative Allylations of Nitroalkanoates.Catalytic asymmetric Claisen rearrangement of enolphosphonates: construction of vicinal tertiary and all-carbon quaternary centersCatalytic Conia-ene and related reactions.Direct Asymmetric Alkylation of Ketones: Still Unconquered.Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams.Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-Carbon Quaternary Stereocenters.Enantio-, diastereo-, and regioselective iridium-catalyzed asymmetric allylic alkylation of acyclic β-ketoesters.Congested C-C bonds by Pd-catalyzed enantioselective allyl-allyl cross-coupling, a mechanism-guided solution.Construction of vicinal tertiary and all-carbon quaternary stereocenters via Ir-catalyzed regio-, diastereo-, and enantioselective allylic alkylation and applications in sequential Pd catalysisHigh-Throughput Screening of the Asymmetric Decarboxylative Alkylation Reaction of Enolate-Stabilized Enol Carbonates.The catalytic enantioselective total synthesis of (+)-liphagal.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Rapid synthesis of an electron-deficient t-BuPHOX ligand: cross-coupling of aryl bromides with secondary phosphine oxides.The reaction mechanism of the enantioselective Tsuji allylation: inner-sphere and outer-sphere pathways, internal rearrangements, and asymmetric C-C bond formation.Enantioselective construction of α-quaternary cyclobutanones by catalytic asymmetric allylic alkylation.Iridium-Catalyzed Stereoselective Allylic Alkylation Reactions with Crotyl Chloride.Diastereo- and enantioselective phase-transfer alkylation of 3-substituted oxindoles with racemic secondary alkyl halides.Wolff/Cope Approach to the AB Ring of the Sesterterpenoid Variecolin.Enantioselective synthesis of sterically hindered α-allyl-α-aryl oxindoles via palladium-catalysed decarboxylative asymmetric allylic alkylation.Multicomponent decarboxylative allylations.Palladium-catalyzed enantioselective decarboxylative cycloaddition of vinylethylene carbonates with isocyanates.Palladium-catalyzed decarboxylative cycloaddition of vinylethylene carbonates with formaldehyde: enantioselective construction of tertiary vinylglycols.Organocatalytic enantioselective allylic alkylation of MBH carbonates with β-keto esters.
P2860
Q34850044-A4842518-22D2-4B7B-8932-9DE0683C21B5Q35049991-D32940E0-0494-4D5A-B46D-B0C5A1BCA34BQ35915688-2D886F0B-2B32-42DB-9AEE-1038709C4655Q36197976-DACE194E-CDF2-447C-8689-AE1CED9C6206Q36452957-C58D9F14-DF5A-4611-A1A4-D358D624BB1FQ38510935-B05F8477-0347-487C-9AE1-2A836084D383Q39302059-9CC37D44-2B15-4876-A0B8-7649373A7D16Q40673992-8C3E1A04-78DA-4367-9C43-20288EBD2FC2Q41136502-73C71784-B2C2-427E-BC06-0D1C58891AD4Q41852154-9BD62F8E-053C-45CA-B15A-305AB38710CEQ41954848-3EC37C39-E678-44C2-8583-EA442B445116Q41986037-C6E862A0-A989-426F-B2A6-6C9639492500Q42136472-B9E874E8-CF76-40FF-9DA6-105003B31A68Q42179500-B36FB7D9-BBA1-4BC9-AC4D-A7DA18C33568Q42182848-96A956D6-DE5B-4758-BAB2-8A6D6053F984Q42209265-68803A6F-D56A-43B2-AEB8-EF5F2F5B9431Q42534222-EAA86B66-7FC7-42B0-8E83-CC0943CDE063Q42921306-581DC3C7-49B8-41D9-9C19-D1434B120524Q45961249-0C967D56-38EA-45BD-9884-6163F09FA158Q47389456-B6FB001D-1BC6-406D-B147-4057A7E335D5Q48315572-EE67DF5C-4C8F-4A50-8D20-5233BB809CDCQ50047733-8BDF13C0-B0E4-4572-A1CA-0197E291301CQ51048448-1C7B567C-D100-4B84-B754-F556FB85723DQ53391722-6B19E23C-EB70-495A-9624-D620C3807A26Q53551484-ABEBC0F4-5B58-4061-BC94-841DA34D5B90Q54327923-0C06326B-0877-41D7-B7FD-3EAEF927ECA5
P2860
A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
A palladium-catalysed enolate ...... ry and tertiary stereocentres.
@en
type
label
A palladium-catalysed enolate ...... ry and tertiary stereocentres.
@en
prefLabel
A palladium-catalysed enolate ...... ry and tertiary stereocentres.
@en
P2093
P2860
P356
P1433
P1476
A palladium-catalysed enolate ...... ry and tertiary stereocentres.
@en
P2093
Brian M Stoltz
David E White
Jan Streuff
Scott C Virgil
P2860
P2888
P304
P356
10.1038/NCHEM.518
P577
2010-03-01T00:00:00Z
P5875
P6179
1051369388