Ring-contraction strategy for the practical, scalable, catalytic asymmetric synthesis of versatile γ-quaternary acylcyclopentenes.
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The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total SynthesisDeacylative allylation: allylic alkylation via retro-Claisen activation.Intercepted Decarboxylative Allylations of Nitroalkanoates.Expanding insight into asymmetric palladium-catalyzed allylic alkylation of N-heterocyclic molecules and cyclic ketonesBiosynthesis and chemical synthesis of presilphiperfolanol natural products.Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-Carbon Quaternary Stereocenters.Enantioselective total synthesis of the reported structures of (-)-9-epi-presilphiperfolan-1-ol and (-)-presilphiperfolan-1-ol: structural confirmation and reassignment and biosynthetic insights.A unified approach to the daucane and sphenolobane bicyclo[5.3.0]decane core: enantioselective total syntheses of daucene, daucenal, epoxydaucenal B, and 14-para-anisoyloxydauc-4,8-diene.Synthesis of enantioenriched γ-quaternary cycloheptenones using a combined allylic alkylation/Stork-Danheiser approach: preparation of mono-, bi-, and tricyclic systems.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Progress towards the total synthesis of hamigerans C and D: a direct approach to an elaborated 6-7-5 carbocyclic core.Wolff/Cope Approach to the AB Ring of the Sesterterpenoid Variecolin.Catalytic Asymmetric Construction of α-Quaternary Cyclopentanones and Its Application to the Syntheses of (-)-1,14-Herbertenediol and (-)-Aphanorphine.Versatile Cu(I)/Pd(0) dual catalysis for the synthesis of quaternary α-allylated carbonyl compounds: development, mechanistic investigations and scope.
P2860
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P2860
Ring-contraction strategy for the practical, scalable, catalytic asymmetric synthesis of versatile γ-quaternary acylcyclopentenes.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年学术文章
@wuu
2011年学术文章
@zh-cn
2011年学术文章
@zh-hans
2011年学术文章
@zh-my
2011年学术文章
@zh-sg
2011年學術文章
@yue
2011年學術文章
@zh
2011年學術文章
@zh-hant
name
Ring-contraction strategy for ...... -quaternary acylcyclopentenes.
@en
Ring-contraction strategy for ...... -quaternary acylcyclopentenes.
@nl
type
label
Ring-contraction strategy for ...... -quaternary acylcyclopentenes.
@en
Ring-contraction strategy for ...... -quaternary acylcyclopentenes.
@nl
prefLabel
Ring-contraction strategy for ...... -quaternary acylcyclopentenes.
@en
Ring-contraction strategy for ...... -quaternary acylcyclopentenes.
@nl
P2093
P2860
P50
P356
P1476
Ring-contraction strategy for ...... -quaternary acylcyclopentenes.
@en
P2093
Brian M Stoltz
Nathan B Bennett
Thomas Jensen
P2860
P304
P356
10.1002/ANIE.201007814
P407
P577
2011-02-24T00:00:00Z