Natural products as inspiration for the development of asymmetric catalysis.
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Folded biomimetic oligomers for enantioselective catalysis.The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total SynthesisEnantioselective protonation.The saponins: polar isoprenoids with important and diverse biological activities.Dioxindole in asymmetric catalytic synthesis: direct access to 3-substituted 3-hydroxy-2-oxindoles via 1,4-additions to nitroalkenes.Capturing the essence of organic synthesis: from bioactive natural products to designed molecules in today's medicine.A Reactivity-Driven Approach to the Discovery and Development of Gold-Catalyzed Organic Reactions.The use of natural products in colorectal cancer drug discovery.Enantioselective recognition at mesoporous chiral metal surfaces.Organocatalytic routes toward substituted 1,2,3-triazoles.Design of Selenium-Based Chiral Chemical Probes for Simultaneous Enantio- and Chemosensing of Chiral Carboxylic Acids with Remote Stereogenic Centers by NMR Spectroscopy.Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-Carbon Quaternary Stereocenters.Construction of highly enantioenriched spirocyclopentaneoxindoles containing four consecutive stereocenters via thiourea-catalyzed asymmetric Michael-Henry cascade reactions.Catalytic enantioselective approach to the eudesmane sesquiterpenoids: total synthesis of (+)-carissone.Combining asymmetric catalysis with natural product functionalization through enantioselective alpha-fluorination.Ring-contraction strategy for the practical, scalable, catalytic asymmetric synthesis of versatile γ-quaternary acylcyclopentenes.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Enantioselective total synthesis of (+)-cassiol.Enantioselective construction of spirooxindole derivatives through [3+2] annulation catalyzed by a bisthiourea as a multiple-hydrogen-bond donor.An efficient and enantioselective Michael addition of aromatic oximes to α,β-unsaturated aldehydes promoted by a chiral diamine catalyst derived from α,α-diphenyl prolinol.Direct Access to N-Unprotected α- and/or β-Tetrasubstituted Amino Acid Esters via Direct Catalytic Mannich-Type Reactions Using N-Unprotected Trifluoromethyl Ketimines.Catalytic Asymmetric Oxidative γ-Coupling of α,β-Unsaturated Aldehydes with Air as the Terminal Oxidant.Sequential Au(i)/chiral tertiary amine catalysis: a tandem C-H functionalization of anisoles or a thiophene/asymmetric Michael addition sequence to quaternary oxindoles.Michael Addition Catalyzed by Chiral Secondary Amine Phosphoramide Using Fluorinated Silyl Enol Ethers: Formation of Quaternary Carbon Stereocenters.Facile and efficient enantioselective hydroxyamination reaction: synthesis of 3-hydroxyamino-2-oxindoles using nitrosoarenes.Chirality measures for vectors, matrices, operators and functions.Formation of the Main Cores Present in Natural Products by Tandem Additions.
P2860
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P2860
Natural products as inspiration for the development of asymmetric catalysis.
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on September 2008
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Natural products as inspiration for the development of asymmetric catalysis.
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Natural products as inspiration for the development of asymmetric catalysis.
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type
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Natural products as inspiration for the development of asymmetric catalysis.
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Natural products as inspiration for the development of asymmetric catalysis.
@nl
prefLabel
Natural products as inspiration for the development of asymmetric catalysis.
@en
Natural products as inspiration for the development of asymmetric catalysis.
@nl
P2860
P356
P1433
P1476
Natural products as inspiration for the development of asymmetric catalysis.
@en
P2093
Brian M Stoltz
P2860
P2888
P304
P356
10.1038/NATURE07370
P407
P577
2008-09-01T00:00:00Z