Catalytic enantioselective alkylation of substituted dioxanone enol ethers: ready access to Calpha-tetrasubstituted hydroxyketones, acids, and esters
about
Preparation of 1,5-Dioxaspiro[5.5]undecan-3-one.Formal total syntheses of classic natural product target molecules via palladium-catalyzed enantioselective alkylation.Enantioselective synthesis of α-secondary and α-tertiary piperazin-2-ones and piperazines by catalytic asymmetric allylic alkylation.Transition metal-catalyzed decarboxylative allylation and benzylation reactionsSynthesis and Exploration of Electronically Modified (R)-5,5-Dimethyl-(p-CF3)3-i-PrPHOX in Palladium-Catalyzed Enantio- and Diastereoselective Allylic Alkylation: A Practical Alternative to (R)-(p-CF3)3-t-BuPHOX.NeoPHOX - a structurally tunable ligand system for asymmetric catalysisCatalytic enantioselective total synthesis of (+)-eucomic acid.Alternative synthesis of the Colorado potato beetle pheromone.Polycyclic Furanobutenolide-Derived Cembranoid and Norcembranoid Natural Products: Biosynthetic Connections and Synthetic Efforts.Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams.Unusual allylpalladium carboxylate complexes: identification of the resting state of catalytic enantioselective decarboxylative allylic alkylation reactions of ketones.Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-Carbon Quaternary Stereocenters.Catalytic enantioselective approach to the eudesmane sesquiterpenoids: total synthesis of (+)-carissone.Enantioselective synthesis of a hydroxymethyl-cis-1,3-cyclopentenediol building block.High-Throughput Screening of the Asymmetric Decarboxylative Alkylation Reaction of Enolate-Stabilized Enol Carbonates.The catalytic enantioselective total synthesis of (+)-liphagal.Ring-contraction strategy for the practical, scalable, catalytic asymmetric synthesis of versatile γ-quaternary acylcyclopentenes.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Rapid synthesis of an electron-deficient t-BuPHOX ligand: cross-coupling of aryl bromides with secondary phosphine oxides.Enantioselective construction of α-quaternary cyclobutanones by catalytic asymmetric allylic alkylation.Enantioselective total synthesis of (+)-cassiol.Model Studies To Access the [6,7,5,5]-Core of Ineleganolide Using Tandem Translactonization-Cope or Cyclopropanation-Cope Rearrangements as Key Steps.Biocatalytic conversion of cyclic ketones bearing alpha-quaternary stereocenters to lactones in an enantioselective radical approach to medium-sized carbocycles.The Development of a Unified Enantioselective, Convergent Synthetic Approach Toward the Furanobutenolide-Derived Polycyclic Norcembranoid Diterpenes: Asymmetric Formation of the Polycyclic Norditerpenoid Carbocyclic Core by Tandem Annulation Cascade
P2860
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P2860
Catalytic enantioselective alkylation of substituted dioxanone enol ethers: ready access to Calpha-tetrasubstituted hydroxyketones, acids, and esters
description
2008 nî lūn-bûn
@nan
2008年の論文
@ja
2008年学术文章
@wuu
2008年学术文章
@zh-cn
2008年学术文章
@zh-hans
2008年学术文章
@zh-my
2008年学术文章
@zh-sg
2008年學術文章
@yue
2008年學術文章
@zh
2008年學術文章
@zh-hant
name
Catalytic enantioselective alk ...... roxyketones, acids, and esters
@en
Catalytic enantioselective alk ...... roxyketones, acids, and esters
@nl
type
label
Catalytic enantioselective alk ...... roxyketones, acids, and esters
@en
Catalytic enantioselective alk ...... roxyketones, acids, and esters
@nl
prefLabel
Catalytic enantioselective alk ...... roxyketones, acids, and esters
@en
Catalytic enantioselective alk ...... roxyketones, acids, and esters
@nl
P2860
P356
P1476
Catalytic enantioselective alk ...... roxyketones, acids, and esters
@en
P2093
Brian M Stoltz
Masaki Seto
P2860
P304
P356
10.1002/ANIE.200801424
P407
P577
2008-01-01T00:00:00Z