Metal-free catalytic C-Si bond formation in an aqueous medium. Enantioselective NHC-catalyzed silyl conjugate additions to cyclic and acyclic α,β-unsaturated carbonyls.
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Organocatalytic Reactions Enabled by N-Heterocyclic CarbenesN-Heterocyclic carbene transition metal complexes for catalysis in aqueous media.Recent advances in carbon dioxide capture, fixation, and activation by using N-heterocyclic carbenes.Transition-metal-free B-B and B-interelement reactions with organic molecules.Copper(II)-catalyzed silylation of activated alkynes in water: diastereodivergent access to E- or Z-β-silyl-α,β-unsaturated carbonyl and carboxyl compoundsCopper-catalyzed silylation of p-quinone methides: new entry to dibenzylic silanes.Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to α,β-Unsaturated Carbonyl Compounds.Metal-free catalytic enantioselective C-B bond formation: (pinacolato)boron conjugate additions to α,β-unsaturated ketones, esters, Weinreb amides, and aldehydes promoted by chiral N-heterocyclic carbenes.NHC-Cu-Catalyzed Silyl Conjugate Additions to Acyclic and Cyclic Dienones and Dienoates. Efficient Site-, Diastereo- and Enantioselective Synthesis of Carbonyl-Containing Allylsilanes.Enantioselective synthesis of boron-substituted quaternary carbon stereogenic centers through NHC-catalyzed conjugate additions of (pinacolato)boron units to enones.Copper-catalyzed addition of nucleophilic silicon to aldehydes.N-heterocyclic carbene organocatalysts for dehydrogenative coupling of silanes and hydroxyl compounds.On the structural diversity of [K(18-crown-6)EPh3] complexes (E = C, Si, Ge, Sn, Pb): synthesis, crystal structures and NOESY NMR study.Silylative cyclopropanation of allyl phosphates with silylboronates.Alkoxide activation of aminoboranes towards selective amination.Boryl substitution of functionalized aryl-, heteroaryl- and alkenyl halides with silylborane and an alkoxy base: expanded scope and mechanistic studies† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5sc00384a Click here foBoryl substitution of functionalized aryl-, heteroaryl- and alkenyl halides with silylborane and an alkoxy base: expanded scope and mechanistic studies.Copper(I)-Catalyzed Asymmetric Desymmetrization through Inverse-Electron-Demand aza-Diels-Alder Reaction: Efficient Access to Tetrahydropyridazines Bearing a Unique α-Chiral Silane Moiety.Reversible Oxidative Addition at Carbon.Facile insertion of a cyclic alkyl(amino) carbene carbon into the B-B bond of diboron(4) reagents.Asymmetric conjugate addition of Grignard reagents to 3-silyl unsaturated esters for the facile preparation of enantioenriched β-silylcarbonyl compounds and allylic silanes.Triflimide-catalyzed allyl-allyl cross-coupling: a metal-free allylic alkylation.One-pot three-component highly selective synthesis of homoallylboronates by using metal-free catalysis.Metal-free enantioselective addition of nucleophilic silicon to aromatic aldehydes catalyzed by a [2.2]paracyclophane-based N-heterocyclic carbene catalyst.Organocatalytic silyl transfer from silylborane to nitroalkenes for the synthesis of β-silyl nitroalkanes and β-silyl amines.Super electron donors derived from diboron.
P2860
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P2860
Metal-free catalytic C-Si bond formation in an aqueous medium. Enantioselective NHC-catalyzed silyl conjugate additions to cyclic and acyclic α,β-unsaturated carbonyls.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
2011年论文
@zh
2011年论文
@zh-cn
name
Metal-free catalytic C-Si bond ...... lic α,β-unsaturated carbonyls.
@en
Metal-free catalytic C-Si bond ...... lic α,β-unsaturated carbonyls.
@nl
type
label
Metal-free catalytic C-Si bond ...... lic α,β-unsaturated carbonyls.
@en
Metal-free catalytic C-Si bond ...... lic α,β-unsaturated carbonyls.
@nl
prefLabel
Metal-free catalytic C-Si bond ...... lic α,β-unsaturated carbonyls.
@en
Metal-free catalytic C-Si bond ...... lic α,β-unsaturated carbonyls.
@nl
P2860
P356
P1476
Metal-free catalytic C-Si bond ...... lic α,β-unsaturated carbonyls.
@en
P2093
Jeannette M O'Brien
P2860
P304
P356
10.1021/JA203031A
P407
P577
2011-04-27T00:00:00Z