Metal-free catalytic enantioselective C-B bond formation: (pinacolato)boron conjugate additions to α,β-unsaturated ketones, esters, Weinreb amides, and aldehydes promoted by chiral N-heterocyclic carbenes.
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Contemporary Strategies for the Synthesis of Tetrahydropyran Derivatives: Application to Total Synthesis of Neopeltolide, a Marine Macrolide Natural ProductOrganocatalytic Reactions Enabled by N-Heterocyclic CarbenesFacile scission of isonitrile carbon-nitrogen triple bond using a diborane(4) reagent.Synthesis and Suzuki-Miyaura Cross-Coupling of Enantioenriched Secondary Potassium β-Trifluoroboratoamides: Catalytic, Asymmetric Conjugate Addition of Bisboronic Acid and Tetrakis(dimethylamino)diboron to α,β-Unsaturated Carbonyl CompoundsAsymmetric homoenolate additions to acyl phosphonates through rational design of a tailored N-heterocyclic carbene catalyst.Diastereoselective and enantioselective conjugate addition reactions utilizing α,β-unsaturated amides and lactams.Transition-metal-free B-B and B-interelement reactions with organic molecules.Acylboranes: synthetic strategies and applications.Catalytic Enantioselective Conjugate Additions of (pin)B-Substituted Allylcopper Compounds Generated in situ from Butadiene or Isoprene.Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to α,β-Unsaturated Carbonyl Compounds.Kinetic resolution of racemic 2-substituted 1,2-dihydroquinolines via asymmetric Cu-catalyzed borylationCatalyst-controlled stereoselective olefin metathesis as a principal strategy in multistep synthesis design: a concise route to (+)-neopeltolide.Hydroxyl-directed stereoselective diboration of alkenes.Symmetry-amplified J splittings for quadrupolar spin pairs: a solid-state NMR probe of homoatomic covalent bonds.Scalable, Metal- and Additive-Free, Photoinduced Borylation of Haloarenes and Quaternary Arylammonium Salts.NHC-Cu-Catalyzed Silyl Conjugate Additions to Acyclic and Cyclic Dienones and Dienoates. Efficient Site-, Diastereo- and Enantioselective Synthesis of Carbonyl-Containing Allylsilanes.Enantioselective synthesis of boron-substituted quaternary carbon stereogenic centers through NHC-catalyzed conjugate additions of (pinacolato)boron units to enones.A cooperative N-heterocyclic carbene/chiral phosphate catalysis system for allenolate annulations.Synthesis of Secondary and Tertiary Alkylboranes via Formal Hydroboration of Terminal and 1,1-Disubstituted Alkenes.Asymmetric diboration of terminal alkenes with a rhodium catalyst and subsequent oxidation: enantioselective synthesis of optically active 1,2-diols.Metal-free borylative ring-opening of vinyl epoxides and aziridines.Substrate-Assisted, Transition-Metal-Free Diboration of Alkynamides with Mixed Diboron: Regio- and Stereoselective Access to trans-1,2-Vinyldiboronates.Alkoxide activation of aminoboranes towards selective amination.Copper(I)-Catalyzed Enantioselective Nucleophilic Borylation of Aliphatic Ketones: Synthesis of Enantioenriched Chiral Tertiary α-Hydroxyboronates.The Phosphinoboration of N-Heterocycles.Homolytic Cleavage of a B-B Bond by the Cooperative Catalysis of Two Lewis Bases: Computational Design and Experimental Verification.Organosulfide-Catalyzed Diboration of Terminal Alkynes under Light.Synthesis and application of a dual chiral [2.2]paracyclophane-based N-heterocyclic carbene in enantioselective β-boration of acyclic enones.Catalytic Asymmetric Synthesis of Phosphine Boronates.Asymmetric borylation of α,β-unsaturated esters catalyzed by novel ring expanded N-heterocyclic carbenes based on chiral 3,4-dihydro-quinazolinium compounds.Super electron donors derived from diboron.Substrate-Assisted, Transition-Metal-Free Diboration of Alkynamides with Mixed Diboron: Regio- and Stereoselective Access to trans -1,2-VinyldiboronatesN-Heterocyclic Carbene Boranes as Electron-Donating and Electron-Accepting Components of π-Conjugated Systems
P2860
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P2860
Metal-free catalytic enantioselective C-B bond formation: (pinacolato)boron conjugate additions to α,β-unsaturated ketones, esters, Weinreb amides, and aldehydes promoted by chiral N-heterocyclic carbenes.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
2012年论文
@zh
2012年论文
@zh-cn
name
Metal-free catalytic enantiose ...... hiral N-heterocyclic carbenes.
@en
type
label
Metal-free catalytic enantiose ...... hiral N-heterocyclic carbenes.
@en
prefLabel
Metal-free catalytic enantiose ...... hiral N-heterocyclic carbenes.
@en
P2093
P2860
P356
P1476
Metal-free catalytic enantiose ...... hiral N-heterocyclic carbenes.
@en
P2093
Jeannette M O'Brien
Suttipol Radomkit
P2860
P304
P356
10.1021/JA302929D
P407
P577
2012-05-04T00:00:00Z