Enantioselective organocatalytic C-H bond functionalization via tandem 1,5-hydride transfer/ring closure: asymmetric synthesis of tetrahydroquinolines.
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Preparation of neuroprotective condensed 1,4-benzoxazepines by regio- and diastereoselective domino Knoevenagel-[1,5]-hydride shift cyclization reactionRedox-neutral α-oxygenation of amines: reaction development and elucidation of the mechanism.Computationally guided stereocontrol of the combined C-H functionalization/Cope rearrangementAsymmetric Redox-Annulation of Cyclic Amines.C-H bond functionalization via hydride transfer: formation of α-arylated piperidines and 1,2,3,4-tetrahydroisoquinolines via stereoselective intramolecular amination of benzylic C-H bonds.Asymmetric Yttrium-Catalyzed C(sp3 )-H Addition of 2-Methyl Azaarenes to Cyclopropenes.Metal-free α-amination of secondary amines: computational and experimental evidence for azaquinone methide and azomethine ylide intermediates.Enantioselective addition of diphenyl phosphonate to ketimines derived from isatins catalyzed by binaphthyl-modified organocatalystsRedox-neutral copper(II) carboxylate catalyzed α-alkynylation of amines.Facile Access to Ring-Fused Aminals via Direct α-Amination of Secondary Amines with ortho-Aminobenzaldehydes. Synthesis of Vasicine, Deoxyvasicine, Deoxyvasicinone, Mackinazolinone and Ruteacarpine.A Nucleophilic Strategy for Enantioselective Intermolecular α-Amination: Access to Enantioenriched α-Arylamino Ketones.Organocatalytic C-H activation reactions.C-H bond functionalization through intramolecular hydride transfer.Organo- and Organometallic-Catalytic Intramolecular [1,5]-Hydride Transfer/Cyclization Process through C(sp(3) )-H Bond Activation.Hydrogen-Atom Transfer Reactions.Aza-Diels-Alder reaction between N-aryl-1-oxo-1H-isoindolium ions and tert-enamides: Steric effects on reaction outcome.Intramolecular Redox-Mannich Reactions: Facile Access to the Tetrahydroprotoberberine Core.The redox-Mannich reaction.Redox-neutral α,β-difunctionalization of cyclic amines.Harnessing the Electrophilicity of Keteniminium Ions: A Simple and Straightforward Entry to Tetrahydropyridines and Piperidines from Ynamides.Redox-neutral α-C-H bond functionalization of secondary amines with concurrent C-P bond formation/N-alkylation.Redox-neutral α-arylation of amines.Enantioselective Michael addition of 2-hydroxy-1,4-naphthoquinones to nitroalkenes catalyzed by binaphthyl-derived organocatalysts.A one-pot multicomponent strategy for stereospecific construction of tricyclic pyrrolo[1,2-a]quinolines.Cascade intramolecular N-arylation/intermolecular carboamination reactions for the construction of tricyclic heterocycles.Intramolecular [3 + 2]-cycloadditions of azomethine ylides derived from secondary amines via redox-neutral C-H functionalization.Tertiary amines as synthetic equivalents of vinyl cations: zinc bromide promoted coupling of propargylamines with α-isocyanoacetamides to give 2,4,5-trisubstituted oxazoles initiated by an internal redox process.Cascade hydroamination/redox reaction for the synthesis of cyclic aminals catalyzed by a combined gold complex and Brønsted acid.Merging organocatalysis with transition metal catalysis and using O2 as the oxidant for enantioselective C-H functionalization of aldehydes.Redox-Neutral Aromatization of Cyclic Amines: Mechanistic Insights and Harnessing of Reactive Intermediates for Amine α- and β-C-H Functionalization.Construction of tetrahydropyranoquinoline derivatives via an asymmetric organocatalytic aza-Michael-IED/HAD cascade reaction.Asymmetric tandem 1,5-hydride shift/ring closure for the synthesis of chiral spirooxindole tetrahydroquinolines.Catalytic enantioselective tert-aminocyclization by asymmetric binary acid catalysis (ABC): stereospecific 1,5-hydrogen transfer.Cyclization of Ynamide-Tethered 1,3,8-Triynes.Hf(OTf)4-Catalyzed highly diastereoselective synthesis of 1,3-disubstituted tetralin derivatives via benzylic C(sp3)-H bond functionalization.Brønsted acid cocatalysis in photocatalytic intramolecular coupling of tertiary amines: efficient synthesis of 2-arylindols.The redox-neutral approach to C-H functionalization.A convergent rhodium-catalysed asymmetric synthesis of tetrahydroquinolines.Organocatalytic aza-Michael-Michael cascade reactions: a flexible approach to 2,3,4-trisubstituted tetrahydroquinolines.Synthesis and kinetic resolution of substituted tetrahydroquinolines by lithiation then electrophilic quench.
P2860
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P2860
Enantioselective organocatalytic C-H bond functionalization via tandem 1,5-hydride transfer/ring closure: asymmetric synthesis of tetrahydroquinolines.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Enantioselective organocatalyt ...... hesis of tetrahydroquinolines.
@en
Enantioselective organocatalyt ...... hesis of tetrahydroquinolines.
@nl
type
label
Enantioselective organocatalyt ...... hesis of tetrahydroquinolines.
@en
Enantioselective organocatalyt ...... hesis of tetrahydroquinolines.
@nl
prefLabel
Enantioselective organocatalyt ...... hesis of tetrahydroquinolines.
@en
Enantioselective organocatalyt ...... hesis of tetrahydroquinolines.
@nl
P2093
P356
P1476
Enantioselective organocatalyt ...... hesis of tetrahydroquinolines.
@en
P2093
Dae Young Kim
Sun Mi Kim
Young Ku Kang
P304
11847-11849
P356
10.1021/JA103786C
P407
P577
2010-09-01T00:00:00Z