Enantioselective electrophilic trifluoromethylation of beta-keto esters with Umemoto reagents induced by chiral nonracemic guanidines.

Enantioselective electrophilic trifluoromethylation of beta-keto esters with Umemoto reagents induced by chiral nonracemic guanidines.

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http://www.wikidata.org/entity/Q43292693
The productive merger of iodonium salts and organocatalysis: a non-photolytic approach to the enantioselective alpha-trifluoromethylation of aldehydes.Shelf-stable electrophilic trifluoromethylating reagents: A brief historical perspective.Enantioselective organocatalytic synthesis of fluorinated molecules.Introduction of fluorine and fluorine-containing functional groups.Recent advances in trifluoromethylation reactions with electrophilic trifluoromethylating reagents.Photo-organocatalytic Enantioselective Perfluoroalkylation of β-Ketoesters.Efficient access to extended Yagupolskii-Umemoto-type reagents: triflic acid catalyzed intramolecular cyclization of ortho-ethynylaryltrifluoromethylsulfanes.Oxidative trifluoromethylation of unactivated olefins: an efficient and practical synthesis of α-trifluoromethyl-substituted ketones.Kinetic resolution of allyl fluorides by enantioselective allylic trifluoromethylation based on silicon-assisted C-F bond cleavage.A highly stable and versatile heterobifunctional fluoroalkylation reagent for preparation of fluorinated organic compounds.A sterically demanding organo-superbase avoids decomposition of a naked trifluoromethyl carbanion directly generated from fluoroform.Enantioselective electrophilic trifluoromethylthiolation of β-ketoesters: a case of reactivity and selectivity bias for organocatalysis.Trifluoromethylchlorosulfonylation of Alkenes: Evidence for an Inner-Sphere Mechanism by a Copper Phenanthroline Photoredox Catalyst
P2860

Enantioselective electrophilic trifluoromethylation of beta-keto esters with Umemoto reagents induced by chiral nonracemic guanidines.

Item
http://www.wikidata.org/entity/Q43292693
description
2009 nî lūn-bûn
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2009年の論文
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2009年学术文章
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2009年学术文章
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2009年学术文章
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2009年学术文章
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2009年學術文章
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name
Enantioselective electrophilic ...... chiral nonracemic guanidines.
@en
Enantioselective electrophilic ...... chiral nonracemic guanidines.
@nl
type
label
Enantioselective electrophilic ...... chiral nonracemic guanidines.
@en
Enantioselective electrophilic ...... chiral nonracemic guanidines.
@nl
prefLabel
Enantioselective electrophilic ...... chiral nonracemic guanidines.
@en
Enantioselective electrophilic ...... chiral nonracemic guanidines.
@nl
P1433
P1476
P2093
P304
P31
P356
P433
P478
P50
P577
P5875
P698
P921
P356
P1433
P1476
Enantioselective electrophilic ...... y chiral nonracemic guanidines
@en
P2093
P304
P31
P356
P433
P478
P50
P577
P5875
P698
P921