Reactivity models of hydrogen activation by frustrated Lewis pairs: synergistic electron transfers or polarization by electric field?
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Expanding the Boundaries of Water-Tolerant Frustrated Lewis Pair Hydrogenation: Enhanced Back Strain in the Lewis Acid Enables the Reductive Amination of Carbonyls.A unified survey of Si-H and H-H bond activation catalysed by electron-deficient boranes.Frustrated Lewis pair chemistry: development and perspectives.Liberation of H2 from (o-C6H4Me)3P-H(+) + (-)H-B(p-C6F4H)3 ion-pair: A transition-state in the minimum energy path versus the transient species in Born-Oppenheimer molecular dynamics.Alkaline earths as main group reagents in molecular catalysis.Reactivity-Tuning in Frustrated Lewis Pairs: Nucleophilicity and Lewis Basicity of Sterically Hindered Phosphines.The broadening reach of frustrated Lewis pair chemistry.Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides.On the mechanism of hydrogen activation by frustrated Lewis pairs.Designing effective 'frustrated Lewis pair' hydrogenation catalysts.Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes.Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]-H···H-[TMP].Replacing C6F5 groups with Cl and H atoms in frustrated Lewis pairs: H2 additions and catalytic hydrogenations.Cleavage of hydrogen by activation at a single non-metal centre - towards new hydrogen storage materials.Direct observation of a borane-silane complex involved in frustrated Lewis-pair-mediated hydrosilylations.Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept.On the hydrogen activation by frustrated Lewis pairs in the solid state: benchmark studies and theoretical insights.Deeper Insight into the Factors Controlling H2 Activation by Geminal Aminoborane-Based Frustrated Lewis Pairs.Understanding the Role of Dispersion in Frustrated Lewis Pairs and Classical Lewis Adducts: A Domain-Based Local Pair Natural Orbital Coupled Cluster Study.Reactivity of the geminal phosphinoborane tBu2PCH2BPh2 towards alkynes, nitriles, and nitrilium triflates.A DFT study of hydrogen and methane activation by B(C6F5)3/P(t-Bu)3 and Al(C6F5)3/P(t-Bu)3 frustrated Lewis pairs.A Frustrated Phosphane-Borane Lewis Pair and Hydrogen: A Kinetics Study.Dihydrogen bond interactions as a result of H2 cleavage at Cu, Ag and Au centres.Bypassing a highly unstable frustrated Lewis pair: dihydrogen cleavage by a thermally robust silylium-phosphine adduct.Aluminium Diphosphamethanides: Hidden Frustrated Lewis Pairs.Double-hybrid density functionalsAre intramolecular frustrated Lewis pairs also intramolecular catalysts? A theoretical study on H2 activation
P2860
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P2860
Reactivity models of hydrogen activation by frustrated Lewis pairs: synergistic electron transfers or polarization by electric field?
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2013 nî lūn-bûn
@nan
2013年の論文
@ja
2013年学术文章
@wuu
2013年学术文章
@zh-cn
2013年学术文章
@zh-hans
2013年学术文章
@zh-my
2013年学术文章
@zh-sg
2013年學術文章
@yue
2013年學術文章
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2013年學術文章
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name
Reactivity models of hydrogen ...... olarization by electric field?
@en
Reactivity models of hydrogen ...... olarization by electric field?
@nl
type
label
Reactivity models of hydrogen ...... olarization by electric field?
@en
Reactivity models of hydrogen ...... olarization by electric field?
@nl
prefLabel
Reactivity models of hydrogen ...... olarization by electric field?
@en
Reactivity models of hydrogen ...... olarization by electric field?
@nl
P50
P356
P1476
Reactivity models of hydrogen ...... olarization by electric field?
@en
P2093
András Stirling
P304
P356
10.1021/JA312387Q
P407
P577
2013-03-07T00:00:00Z