Direct observation of a borane-silane complex involved in frustrated Lewis-pair-mediated hydrosilylations.
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N-Methyl-Benzothiazolium Salts as Carbon Lewis Acids for Si-H σ-Bond Activation and Catalytic (De)hydrosilylationA unified survey of Si-H and H-H bond activation catalysed by electron-deficient boranes.Transition Metal-Free Cleavage of CO.Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations.Catalytic Dearomatization of N-Heteroarenes with Silicon and Boron Compounds.Boron-Catalyzed N-Alkylation of Amines using Carboxylic Acids.Cyclohexa-1,4-dienes in transition-metal-free ionic transfer processes.Borane catalysed ring opening and closing cascades of furans leading to silicon functionalized synthetic intermediatesExpanding Water/Base Tolerant Frustrated Lewis Pair Chemistry to Alkylamines Enables Broad Scope Reductive AminationsMetal-free electrocatalytic hydrogen oxidation using frustrated Lewis pairs and carbon-based Lewis acids.Rapid Surface Functionalization of Hydrogen-Terminated Silicon by Alkyl Silanols.Frustrated Lewis Pair Mediated Csp3 -H Activation.Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation.A General, Practical Triethylborane-Catalyzed Reduction of Carbonyl Functions to Alcohols.Mild partial deoxygenation of esters catalyzed by an oxazolinylborate-coordinated rhodium silylene.Mechanism of the cooperative Si-H bond activation at Ru-S bonds.Late-stage chemoselective functional-group manipulation of bioactive natural products with super-electrophilic silylium ions.J(Si,H) Coupling Constants in Nonclassical Transition-Metal Silane Complexes.B(C6 F5 )3 -Catalyzed Ring Opening and Isomerization of Unactivated Cyclopropanes.B(C6 F5 )3 -Catalyzed Chemoselective Defunctionalization of Ether-Containing Primary Alkyl Tosylates with Hydrosilanes.B(C6 F5 )3 -Catalyzed Cascade Reduction of Pyridines.Group 6 Transition-Metal/Boron Frustrated Lewis Pair Templates Activate N2 and Allow its Facile Borylation and Silylation.Reductive Dehydrogenation of a Stannane via Multiple Sn-H Activation by Frustrated Lewis Pairs.Catalytic Reductive Pinacol-Type Rearrangement of Unactivated 1,2-Diols through a Concerted, Stereoinvertive Mechanism.Chemoselective Reduction of Tertiary Amides to Amines Catalyzed by Triphenylborane.Selective C-O Bond Cleavage of Sugars with Hydrosilanes Catalyzed by Piers' Borane Generated In Situ.The Lewis superacid Al[N(C6F5)2]3 and its higher homolog Ga[N(C6F5)2]3 - structural features, theoretical investigation and reactions of a metal amide with higher fluoride ion affinity than SbF5.Heterolytic Si-H Bond Cleavage at a Molybdenum-Oxido-Based Lewis Pair.C-H addition reactivity of 2-phenylpyridine and 2,2'-bipyridine with pentaphenylborole.Transfer Hydrosilylation.Formal SiH4 chemistry using stable and easy-to-handle surrogates.A Stable but Highly Reactive Phosphine-Coordinated Borenium: Metal-free Dihydrogen Activation and Alkyne 1,2-Carboboration.Chemoselective Silylative Reduction of Conjugated Nitriles under Metal-Free Catalytic Conditions: β-Silyl Amines and Enamines.Hydridosilylamido complexes of Ta and Mo isolobal with Berry's zirconocenes: syntheses, β-Si-H agostic interactions, catalytic hydrosilylation, and insight into mechanism.Borinic Acid Catalysed Reduction of Tertiary Amides with Hydrosilanes: A Mild and Chemoselective Synthesis of Amines.Spontaneous Reduction of a Hydroborane To Generate a B-B Single Bond by the Use of a Lewis Pair.Boron-Catalyzed Regioselective Deoxygenation of Terminal 1,2-Diols to 2-Alkanols Enabled by the Strategic Formation of a Cyclic Siloxane Intermediate.Synthesis of a Pentacene-Type Silaborin via Double Dehydrogenative Cyclization of 1,4-Diboryl-2,5-disilylbenzene.Borocation catalysis.Magnesium-catalyzed hydrosilylation of α,β-unsaturated esters.
P2860
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P2860
Direct observation of a borane-silane complex involved in frustrated Lewis-pair-mediated hydrosilylations.
description
2014 nî lūn-bûn
@nan
2014年の論文
@ja
2014年学术文章
@wuu
2014年学术文章
@zh
2014年学术文章
@zh-cn
2014年学术文章
@zh-hans
2014年学术文章
@zh-my
2014年学术文章
@zh-sg
2014年學術文章
@yue
2014年學術文章
@zh-hant
name
Direct observation of a borane ...... air-mediated hydrosilylations.
@en
Direct observation of a borane ...... air-mediated hydrosilylations.
@nl
type
label
Direct observation of a borane ...... air-mediated hydrosilylations.
@en
Direct observation of a borane ...... air-mediated hydrosilylations.
@nl
prefLabel
Direct observation of a borane ...... air-mediated hydrosilylations.
@en
Direct observation of a borane ...... air-mediated hydrosilylations.
@nl
P2860
P50
P356
P1433
P1476
Direct observation of a borane ...... air-mediated hydrosilylations.
@en
P2093
Heikki M Tuononen
Warren E Piers
P2860
P2888
P304
P356
10.1038/NCHEM.2063
P577
2014-09-28T00:00:00Z