The inner-sphere process in the enantioselective Tsuji allylation reaction with (S)-t-Bu-phosphinooxazoline ligands.
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Catalytic enantioselective 1,6-conjugate additions of propargyl and allyl groupsPalladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.Enantioselective protonation.Palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters.PREPARATION OF (S)-2-Allyl-2-methylcyclohexanone (Cyclohexanone, 2-methyl-2-(2-propen-1-yl)-, (2S)-).Transition metal-catalyzed decarboxylative allylation and benzylation reactionsAn Efficient Protocol for the Palladium-catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst.Expanding insight into asymmetric palladium-catalyzed allylic alkylation of N-heterocyclic molecules and cyclic ketonesRegiospecific decarboxylative allylation of nitriles.Catalytic stereospecific allyl-allyl cross-coupling of internal allyl electrophiles with AllylB(pin).Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.Diastereocontrol in asymmetric allyl-allyl cross-coupling: stereocontrolled reaction of prochiral allylboronates with prochiral allyl chlorides.Unusual allylpalladium carboxylate complexes: identification of the resting state of catalytic enantioselective decarboxylative allylic alkylation reactions of ketones.Catalytic enantioselective allyl-allyl cross-coupling with a borylated allylboronate.Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-Carbon Quaternary Stereocenters.A general enantioselective route to the chamigrene natural product family.Construction of Tertiary Chiral Centers by Pd-catalyzed Asymmetric Allylic Alkylation of Prochiral Enolate EquivalentsBranched/linear selectivity in palladium-catalyzed allyl-allyl cross-couplings: The role of ligands.Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism.A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres.Catalytic enantioselective allylation of dienals through the intermediacy of unsaturated pi-allyl complexes.Congested C-C bonds by Pd-catalyzed enantioselective allyl-allyl cross-coupling, a mechanism-guided solution.High-Throughput Screening of the Asymmetric Decarboxylative Alkylation Reaction of Enolate-Stabilized Enol Carbonates.The catalytic enantioselective total synthesis of (+)-liphagal.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Homogeneous pd-catalyzed enantioselective decarboxylative protonation.Pd-catalyzed enantioselective allyl-allyl cross-coupling.The reaction mechanism of the enantioselective Tsuji allylation: inner-sphere and outer-sphere pathways, internal rearrangements, and asymmetric C-C bond formation.Ligand-controlled regiodivergent palladium-catalyzed decarboxylative allylation reaction to access α,α-difluoroketones.Catalytic enantioselective conjugate allylation of unsaturated methylidene ketones.Stereoselective β-C-glycosylation by a palladium-catalyzed decarboxylative allylation: formal synthesis of aspergillide A.Enantioselective palladium-catalyzed decarboxylative allylation of carbazolones and indolones: formal synthesis of (+)-kopsihainanine A.Direct Access to Highly Functionalized Heterocycles through the Condensation of Cyclic Imines and α-Oxoesters.Metal-catalyzed Decarboxylative Fluoroalkylation Reactions.Palladium-Catalyzed Asymmetric Allylic Allylation of Racemic Morita-Baylis-Hillman Adducts.Palladium-catalyzed dearomatizing 2,5-alkoxyarylation of furan rings: diastereospecific access to spirooxindoles.Catalytic enantioselective difluoroalkylation of aldehydes.Stereoselective Synthesis of Quaternary Pyrrolidine-2,3-diones and β-Amino Acids.Exploiting the unusual effects of fluorine in methodology.Origin of Selectivity of Tsuji-Trost Allylic Alkylation of Lactones: Highly Ordered Transition States with Lithium-Containing Enolates
P2860
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P2860
The inner-sphere process in the enantioselective Tsuji allylation reaction with (S)-t-Bu-phosphinooxazoline ligands.
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年学术文章
@wuu
2007年学术文章
@zh-cn
2007年学术文章
@zh-hans
2007年学术文章
@zh-my
2007年学术文章
@zh-sg
2007年學術文章
@yue
2007年學術文章
@zh
2007年學術文章
@zh-hant
name
The inner-sphere process in th ...... Bu-phosphinooxazoline ligands.
@en
The inner-sphere process in the enantioselective Tsuji allylation reaction with
@nl
type
label
The inner-sphere process in th ...... Bu-phosphinooxazoline ligands.
@en
The inner-sphere process in the enantioselective Tsuji allylation reaction with
@nl
prefLabel
The inner-sphere process in th ...... Bu-phosphinooxazoline ligands.
@en
The inner-sphere process in the enantioselective Tsuji allylation reaction with
@nl
P2093
P50
P356
P1476
The inner-sphere process in th ...... Bu-phosphinooxazoline ligands.
@en
P2093
Brian M Stoltz
Douglas C Behenna
Smaranda C Marinescu
William A Goddard
P304
11876-11877
P356
10.1021/JA070516J
P407
P577
2007-09-08T00:00:00Z