Isolation of a neutral boron-containing radical stabilized by a cyclic (alkyl)(amino)carbene.
about
Recent developments in and perspectives on three-coordinate boron materials: a bright future.α-Radical Phosphines: Synthesis, Structure, and Reactivity.Borylenes: An Emerging Class of Compounds.Cyclic Group 15 Radical Cations.Generation of 1,2-azaboretidines via reduction of ADC borane adducts.Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes.A boron-centered radical: a potassium-crown ether stabilized boryl radical anion.Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals.N-Heterocyclic Carbene Stabilized Boryl Radicals.Crystalline boron-linked tetraaminoethylene radical cations.Consecutive reduction, radical-cyclization, and oxidative-dehydrogenation reaction of ortho-substituted diboryl compounds.Synthesis and Reduction of Sterically Encumbered Mesoionic Carbene-Stabilized Aryldihaloboranes.Isolation of a Reactive Cyclopropane Intermediate via a Unique Catalyst-Free Spontaneous Cyclopropanation Step at 0 °C.Borylative Radical Cyclizations of Benzo[3,4]cyclodec-3-ene-1,5-diynes and N-Heterocyclic Carbene-Boranes.An Isolable Diboron-Centered Diradical with a Triplet Ground State.A Cyclic Alkyl(amino)carbene as Two-Atom π-Chromophore Leading to the First Phosphorescent Linear CuI Complexes.Reduction of a diamidocarbene-supported borenium cation: isolation of a neutral boryl-substituted radical and a carbene-stabilized aminoborylene.Isolation of diborenes and their 90°-twisted diradical congeners.Anorganische Chemie 2014
P2860
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P2860
Isolation of a neutral boron-containing radical stabilized by a cyclic (alkyl)(amino)carbene.
description
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name
Isolation of a neutral boron-c ...... cyclic (alkyl)(amino)carbene.
@en
Isolation of a neutral boron-containing radical stabilized by a cyclic
@nl
type
label
Isolation of a neutral boron-c ...... cyclic (alkyl)(amino)carbene.
@en
Isolation of a neutral boron-containing radical stabilized by a cyclic
@nl
prefLabel
Isolation of a neutral boron-c ...... cyclic (alkyl)(amino)carbene.
@en
Isolation of a neutral boron-containing radical stabilized by a cyclic
@nl
P2093
P2860
P50
P356
P1476
Isolation of a neutral boron-c ...... a cyclic (alkyl)(amino)carbene
@en
P2093
Alexander Damme
Ashwini K Phukan
Philipp Bissinger
Shun Sugawara
P2860
P304
P356
10.1002/ANIE.201403514
P407
P577
2014-06-10T00:00:00Z