Enantioselective iridium-catalyzed imine vinylation: optically enriched allylic amines via alkyne-imine reductive coupling mediated by hydrogen.
about
Large-scale asymmetric synthesis of the bioprotective agent JP4-039 and analogsAllylic Amines as Key Building Blocks in the Synthesis of (E)-Alkene Peptide IsosteresAliphatic imines in titanium-mediated reductive cross-coupling: unique reactivity of Ti(O-i-Pr)4/n-BuLi.Multifunctional organoboron compounds for scalable natural product synthesis.Iridium-catalyzed C-C coupling via transfer hydrogenation: carbonyl addition from the alcohol or aldehyde oxidation level employing 1,3-cyclohexadiene.Ruthenium-catalyzed C-C bond forming transfer hydrogenation: carbonyl allylation from the alcohol or aldehyde oxidation level employing acyclic 1,3-dienes as surrogates to preformed allyl metal reagents.Ruthenium catalyzed C-C bond formation via transfer hydrogenation: branch-selective reductive coupling of allenes to paraformaldehyde and higher aldehydes.Enantioselective iridium-catalyzed carbonyl allylation from the alcohol or aldehyde oxidation level via transfer hydrogenative coupling of allyl acetate: departure from chirally modified allyl metal reagents in carbonyl additionDiastereo- and Enantioselective Reductive Aldol Addition of Vinyl Ketones via Catalytic HydrogenationMechanism and origins of regio- and enantioselectivities in RhI-catalyzed hydrogenative couplings of 1,3-diynes and activated carbonyl partners: intervention of a cumulene intermediateFormation of C-C Bonds via Catalytic Hydrogenation and Transfer Hydrogenation: Vinylation, Allylation, and Enolate Addition of Carbonyl Compounds and IminesFormation and utility of azasilacyclopentadienes derived from silacyclopropenes and nitrilesThe regio- and stereochemical course of reductive cross-coupling reactions between 1,3-disubstituted allenes and vinylsilanes: Synthesis of (Z)-dienes.Catalytic carbonyl addition through transfer hydrogenation: a departure from preformed organometallic reagents.Convergent synthesis of piperidines by the union of conjugated alkynes with imines: a unique regioselective bond construction for heterocycle synthesis.Formation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation.Direct vinylation of alcohols or aldehydes employing alkynes as vinyl donors: a ruthenium catalyzed C-C bond-forming transfer hydrogenation.Diene hydroacylation from the alcohol or aldehyde oxidation level via ruthenium-catalyzed C-C bond-forming transfer hydrogenation: synthesis of beta,gamma-unsaturated ketones.Formation of C-C Bonds via Ruthenium Catalyzed Transfer Hydrogenation: Carbonyl Addition from the Alcohol or Aldehyde Oxidation LevelCatalytic enantioselective OFF ↔ ON activation processes initiated by hydrogen transfer: concepts and challenges.Alkyne-aldehyde reductive C-C coupling through ruthenium-catalyzed transfer hydrogenation: direct regio- and stereoselective carbonyl vinylation to form trisubstituted allylic alcohols in the absence of premetallated reagents.Unlocking Hydrogenation for C-C Bond Formation: A Brief Overview of Enantioselective Methods.Enantioselective carbonyl reverse prenylation from the alcohol or aldehyde oxidation level employing 1,1-dimethylallene as the prenyl donorEnantioselective allylation, crotylation, and reverse prenylation of substituted isatins: iridium-catalyzed C-C bond-forming transfer hydrogenation.Catalytic C-C Bond Formation and the Hendricksonian Ideal: Atom- and Redox-Economy, Stereo- and Site-SelectivityReductive Cyclization of Halo-Ketones to Form 3-Hydroxy-2-Oxindoles via Palladium Catalyzed Hydrogenation: A Hydrogen-Mediated Grignard Addition.Synthesis of quaternary carbon stereogenic centers through enantioselective Cu-catalyzed allylic substitutions with vinylaluminum reagents.ESI-MS, DFT, and synthetic studies on the H(2)-mediated coupling of acetylene: insertion of C=X bonds into rhodacyclopentadienes and Brønsted acid cocatalyzed hydrogenolysis of organorhodium intermediates.Stereoisomerically pure trisubstituted vinylaluminum reagents and their utility in copper-catalyzed enantioselective synthesis of 1,4-dienes containing Z or E alkenes.anti-Aminoallylation of aldehydes via ruthenium-catalyzed transfer hydrogenative coupling of sulfonamido allenes: 1,2-aminoalcohols.Lewis acid mediated vinyl-transfer reaction of alkynes to N-alkylimines by using the N-alkyl residue as a sacrificial hydrogen donor.Transition-metal-free chemo- and regioselective vinylation of azaallyls.Catalytic Hydroalkylation of Allenes.Rhodium-Catalyzed Diastereoselective Cyclization of Allenyl-Sulfonylcarbamates: A Stereodivergent Approach to 1,3-Aminoalcohol Derivatives.Highly enantioselective synthesis of cyclic sulfamidates and sulfamides via rhodium-catalyzed transfer hydrogenation.Rh-Catalyzed Chemo- and Enantioselective Hydrogenation of Allylic Hydrazones.Nickel-catalyzed, directing-group-assisted [2+2+2] cycloaddition of imine and alkynes.Enantioselective synthesis of β-substituted chiral allylic amines via Rh-catalyzed asymmetric hydrogenation.
P2860
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P2860
Enantioselective iridium-catalyzed imine vinylation: optically enriched allylic amines via alkyne-imine reductive coupling mediated by hydrogen.
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年学术文章
@wuu
2007年学术文章
@zh
2007年学术文章
@zh-cn
2007年学术文章
@zh-hans
2007年学术文章
@zh-my
2007年学术文章
@zh-sg
2007年學術文章
@yue
2007年學術文章
@zh-hant
name
Enantioselective iridium-catal ...... coupling mediated by hydrogen.
@en
Enantioselective iridium-catal ...... coupling mediated by hydrogen.
@nl
type
label
Enantioselective iridium-catal ...... coupling mediated by hydrogen.
@en
Enantioselective iridium-catal ...... coupling mediated by hydrogen.
@nl
prefLabel
Enantioselective iridium-catal ...... coupling mediated by hydrogen.
@en
Enantioselective iridium-catal ...... coupling mediated by hydrogen.
@nl
P356
P1476
Enantioselective iridium-catal ...... coupling mediated by hydrogen.
@en
P2093
Andriy Barchuk
Ming-Yu Ngai
P304
12644-12645
P356
10.1021/JA075438E
P407
P577
2007-10-03T00:00:00Z