Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions
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Direct Selective Oxidative Functionalization of C-H Bonds with H₂O₂: Mn-Aminopyridine Complexes Challenge the Dominance of Non-Heme Fe CatalystsReactivity of an Fe(IV)-Oxo Complex with Protons and OxidantsFacile Access to Graphene Oxide from Ferro-Induced Oxidation.Spectroscopic, Electrochemical and Computational Characterisation of Ru Species Involved in Catalytic Water Oxidation: Evidence for a [Ru(V) (O)(Py2 (Me) tacn)] Intermediate.Conversion of 1-alkenes into 1,4-diols through an auxiliary-mediated formal homoallylic C-H oxidationUsing solution- and solid-state S K-edge X-ray absorption spectroscopy with density functional theory to evaluate M-S bonding for MS4(2-) (M = Cr, Mo, W) dianionsTuning the reactivity of Fe(V)(O) toward C-H bonds at room temperature: effect of waterOne-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center.Fenton chemistry at aqueous interfaces.Oxidation of water by a nonhaem diiron(IV) complex via proton-coupled electron transfer.Formation of a room temperature stable Fe(V)(O) complex: reactivity toward unactivated C-H bonds.Supramolecular reactivity in the gas phase: investigating the intrinsic properties of non-covalent complexes.Bis-Fe(IV): nature's sniper for long-range oxidation.A DFT study of the cis-dihydroxylation of nitroaromatic compounds catalyzed by nitrobenzene dioxygenase.Assessment of electronic structure methods for the determination of the ground spin states of Fe(ii), Fe(iii) and Fe(iv) complexes.Dioxygen activation by nonheme iron enzymes with the 2-His-1-carboxylate facial triad that generate high-valent oxoiron oxidants.Oxygen activation by mononuclear nonheme iron dioxygenases involved in the degradation of aromatics.Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations.Chiral Manganese Aminopyridine Complexes: the Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2 O2.Direct evidence of Fe(V) and Fe(IV) intermediates during reduction of Fe(VI) to Fe(III): a nuclear forward scattering of synchrotron radiation approach.Metal-Assisted Oxo Atom Addition to an Fe(III) Thiolate.Rate-Determining Attack on Substrate Precedes Rieske Cluster Oxidation during Cis-Dihydroxylation by Benzoate DioxygenaseMechanism and Catalytic Diversity of Rieske Non-Heme Iron-Dependent Oxygenases.Osmium(III) and osmium(V) complexes bearing a macrocyclic ligand: a simple and efficient catalytic system for cis-dihydroxylation of alkenes with hydrogen peroxide.An iron(III) tetradentate monoamido complex as a nonheme iron-based peroxidase mimetic.Efficient epoxidation of olefins by H2O2 catalyzed by iron "helmet" phthalocyanines.Nonheme iron mediated oxidation of light alkanes with oxone: characterization of reactive oxoiron(IV) ligand cation radical intermediates by spectroscopic studies and DFT calculations.Equilibrating (L)FeIII-OOAc and (L)FeV(O) Species in Hydrocarbon Oxidations by Bio-Inspired Nonheme Iron Catalysts Using H2O2 and AcOH.H2 oxidation versus organic substrate oxidation in non-heme iron mediated reactions with H2O2.Mononuclear Nonheme Iron(III)-Iodosylarene and High-Valent Iron-Oxo Complexes in Olefin Epoxidation Reactions.The mechanism of stereospecific C-H oxidation by Fe(Pytacn) complexes: bioinspired non-heme iron catalysts containing cis-labile exchangeable sites.Olefin cis-Dihydroxylation and Aliphatic C-H Bond Oxygenation by a Dioxygen-Derived Electrophilic Iron-Oxygen Oxidant.C-H bond activation by metal-superoxo species: what drives high reactivity?Properties and reactivities of nonheme iron(IV)-oxo versus iron(V)-oxo: long-range electron transfer versus hydrogen atom abstraction.A DFT and ONIOM study of C-H hydroxylation catalyzed by nitrobenzene 1,2-dioxygenase.Hydroxylation of aromatics with the help of a non-haem FeOOH: a mechanistic study under single-turnover and catalytic conditions.ortho-Hydroxylation of aromatic acids by a non-heme Fe(V)=O species: how important is the ligand design?Does a higher metal oxidation state necessarily imply higher reactivity toward H-atom transfer? A computational study of C-H bond oxidation by high-valent iron-oxo and -nitrido complexes.Catalysis and molecular magnetism of dinuclear iron(III) complexes with N-(2-pyridylmethyl)-iminodiethanol/-ate.Identification of a low-spin acylperoxoiron(III) intermediate in bio-inspired non-heme iron-catalysed oxidations.
P2860
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P2860
Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions
description
im September 2011 veröffentlichter wissenschaftlicher Artikel
@de
wetenschappelijk artikel
@nl
наукова стаття, опублікована у вересні 2011
@uk
name
Observation of Fe
@nl
Observation of Fe(V)=O using v ...... –H and C=C oxidation reactions
@en
type
label
Observation of Fe
@nl
Observation of Fe(V)=O using v ...... –H and C=C oxidation reactions
@en
prefLabel
Observation of Fe
@nl
Observation of Fe(V)=O using v ...... –H and C=C oxidation reactions
@en
P2093
P2860
P50
P356
P1433
P1476
Observation of Fe(V)=O using v ...... –H and C=C oxidation reactions
@en
P2093
Irene Prat
Jennifer S. Mathieson
Mireia Güell
P2860
P2888
P304
P356
10.1038/NCHEM.1132
P577
2011-09-04T00:00:00Z