Nickel-catalyzed coupling reactions of alkyl electrophiles, including unactivated tertiary halides, to generate carbon-boron bonds.
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Recent advances in homogeneous nickel catalysisRadicals: Reactive Intermediates with Translational PotentialPhotoredox Catalysis in Organic ChemistryClick with a boronic acid handle: a neighboring group-assisted click reaction that allows ready secondary functionalization.Suzuki-Miyaura cross-coupling of potassium alkoxyethyltrifluoroborates: access to aryl/heteroarylethyloxy motifs.Nickel-catalyzed carbon-carbon bond-forming reactions of unactivated tertiary alkyl halides: Suzuki arylations.Suzuki-Miyaura cross-coupling of potassium dioxolanylethyltrifluoroborate and aryl/heteroaryl chlorides.Silicon-Carbon Bond Formation via Nickel-Catalyzed Cross-Coupling of Silicon Nucleophiles with Unactivated Secondary and Tertiary Alkyl ElectrophilesCarbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process.sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.Transitioning organic synthesis from organic solvents to water. What's your E Factor?Formal nucleophilic borylation and borylative cyclization of organic halides.Acylboranes: synthetic strategies and applications.Nickel-Catalyzed Borylation of Benzylic Ammonium Salts: Stereospecific Synthesis of Enantioenriched Benzylic Boronates.Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes.Palladium-Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen NucleophileSynthesis and minisci reactions of organotrifluoroborato building blocks.Enantioselective palladium-catalyzed diboration of 1,1-disubstituted allenes.Copper-Catalyzed Amidation of Primary and Secondary Alkyl Boronic Esters.Synthesis of Secondary and Tertiary Alkylboranes via Formal Hydroboration of Terminal and 1,1-Disubstituted Alkenes.Simple access to elusive α-boryl carbanions and their alkylation: an umpolung construction for organic synthesis.Highly efficient catalytic enantioselective Mannich reaction of malonates with N-tert-butoxycarbonyl imines by using Yb(OTf)3/pybox catalysts at room temperature.Mechanistic Study of an Improved Ni Precatalyst for Suzuki-Miyaura Reactions of Aryl Sulfamates: Understanding the Role of Ni(I) Species.Comparison of dppf-Supported Nickel Precatalysts for the Suzuki-Miyaura Reaction: The Observation and Activity of Nickel(I).Copper/B2pin2-catalyzed C-H difluoroacetylation-cycloamidation of anilines leading to the formation of 3,3-difluoro-2-oxindoles.Catalytic Carbo- and Aminoboration of Alkenyl Carbonyl Compounds via 5- and 6-Membered Palladacycles.Selective Radical Fluorination of Tertiary Alkyl Halides at Room Temperature.Decarboxylative borylation.Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C-N Bond Activation.Nickel-Catalyzed Stereoselective Arylboration of Unactivated Alkenes.Copper-Catalyzed Alkynylboration of Alkenes with Diboron Reagents and Bromoalkynes.Nickel-catalyzed acetamidation and lactamization of arylboronic acids.Palladium-catalyzed intramolecular reductive cross-coupling of Csp2-Csp3 bond formation.Stereoselective Synthesis of Trisubstituted Alkenes through Sequential Iron-Catalyzed Reductive anti-Carbozincation of Terminal Alkynes and Base-Metal-Catalyzed Negishi Cross-Coupling.Copper(I)-catalyzed carbon-halogen bond-selective boryl substitution of alkyl halides bearing terminal alkene moieties.Iridium-catalysed borylation of sterically hindered C(sp³)-H bonds: remarkable rate acceleration by a catalytic amount of potassium tert-butoxide.Site-selective bromination of sp3 C-H bonds.Copper‐Catalyzed Borylation of Cyclic Sulfamidates: Access to Enantiomerically Pure (β‐and γ‐Aminoalkyl)boronic Esters.Reductive coupling of benzyl oxalates with highly functionalized alkyl bromides by nickel catalysis.Transition Metal-Free 1,2-Carboboration of Unactivated Alkenes.
P2860
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P2860
Nickel-catalyzed coupling reactions of alkyl electrophiles, including unactivated tertiary halides, to generate carbon-boron bonds.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年学术文章
@wuu
2012年学术文章
@zh-cn
2012年学术文章
@zh-hans
2012年学术文章
@zh-my
2012年学术文章
@zh-sg
2012年學術文章
@yue
2012年學術文章
@zh
2012年學術文章
@zh-hant
name
Nickel-catalyzed coupling reac ...... o generate carbon-boron bonds.
@ast
Nickel-catalyzed coupling reac ...... o generate carbon-boron bonds.
@en
type
label
Nickel-catalyzed coupling reac ...... o generate carbon-boron bonds.
@ast
Nickel-catalyzed coupling reac ...... o generate carbon-boron bonds.
@en
prefLabel
Nickel-catalyzed coupling reac ...... o generate carbon-boron bonds.
@ast
Nickel-catalyzed coupling reac ...... o generate carbon-boron bonds.
@en
P2860
P356
P1476
Nickel-catalyzed coupling reac ...... to generate carbon-boron bonds
@en
P2093
Gregory C Fu
P2860
P304
10693-10697
P356
10.1021/JA304068T
P407
P577
2012-06-06T00:00:00Z