about
Innate C-H trifluoromethylation of heterocyclesCarbon-carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylationsAddition of CF3 across unsaturated moieties: a powerful functionalization toolDirected Evolution of a Fluorinase for Improved Fluorination Efficiency with a Non-native SubstrateLate-Stage Fluorination: From Fundamentals to ApplicationRadicals: Reactive Intermediates with Translational PotentialSynthetic biology approaches to fluorinated polyketidesRadiofluorination of a pre-formed gallium(III) aza-macrocyclic complex: towards next-generation positron emission tomography (PET) imaging agents.Application of palladium-mediated (18)F-fluorination to PET radiotracer development: overcoming hurdles to translation.Trisubstituted 2-trifluoromethyl pyrrolidines via catalytic asymmetric Michael addition/reductive cyclization.Expanding the fluorine chemistry of living systems using engineered polyketide synthase pathways.Cu-catalyzed fluorination of diaryliodonium salts with KF.¹⁹F NMR fingerprints: identification of neutral organic compounds in a molecular containerA fluoride-derived electrophilic late-stage fluorination reagent for PET imaging.Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis.Fluorosugar chain termination agents as probes of the sequence specificity of a carbohydrate polymeraseFe(III)/NaBH4-mediated free radical hydrofluorination of unactivated alkenesOxidative aliphatic C-H fluorination with fluoride ion catalyzed by a manganese porphyrin.Long-lived trifluoromethanide anion: a key intermediate in nucleophilic trifluoromethylations.Targeted fluorination with the fluoride ion by manganese-catalyzed decarboxylation.Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis.Stable gold(III) catalysts by oxidative addition of a carbon-carbon bond.Profound methyl effects in drug discovery and a call for new C-H methylation reactions.The palladium-catalyzed trifluoromethylation of vinyl sulfonates.Access to novel fluorovinylidene ligands via exploitation of outer-sphere electrophilic fluorination: new insights into C-F bond formation and activation.Evidence for in situ catalyst modification during the Pd-catalyzed conversion of aryl triflates to aryl fluorides.Rhodium-catalysed C(sp(2))-C(sp(2)) bond formation via C-H/C-F activation.Palladium-catalyzed enantioselective 1,1-fluoroarylation of aminoalkenes.Copper-catalyzed oxytrifluoromethylation of unactivated alkenes.Radical aryl migration enables diversity-oriented synthesis of structurally diverse medium/macro- or bridged-rings.Catalytic control of enzymatic fluorine specificityCatalytic enantioselective cyclization and C3-fluorination of polyenes.Isolation and Reactivity of Trifluoromethyl Iodonium Salts.Copper-catalyzed, directing group-assisted fluorination of arene and heteroarene C-H bonds.Copper-catalyzed trifluoromethylation of alkenes with an electrophilic trifluoromethylating reagentRecent advances in transition metal-catalyzed Csp(2)-monofluoro-, difluoro-, perfluoromethylation and trifluoromethylthiolation.Rapid and efficient trifluoromethylation of aromatic and heteroaromatic compounds using potassium trifluoroacetate enabled by a flow system.Deoxyfluorination of alcohols with 3,3-difluoro-1,2-diarylcyclopropenesSilver-catalyzed vinylogous fluorination of vinyl diazoacetatesOxidative aliphatic C-H fluorination with manganese catalysts and fluoride ion
P2860
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P2860
description
2011 nî lūn-bûn
@nan
2011 թուականի Մայիսին հրատարակուած գիտական յօդուած
@hyw
2011 թվականի մայիսին հրատարակված գիտական հոդված
@hy
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
name
Catalysis for fluorination and trifluoromethylation
@ast
Catalysis for fluorination and trifluoromethylation
@en
Catalysis for fluorination and trifluoromethylation.
@nl
type
label
Catalysis for fluorination and trifluoromethylation
@ast
Catalysis for fluorination and trifluoromethylation
@en
Catalysis for fluorination and trifluoromethylation.
@nl
prefLabel
Catalysis for fluorination and trifluoromethylation
@ast
Catalysis for fluorination and trifluoromethylation
@en
Catalysis for fluorination and trifluoromethylation.
@nl
P2093
P2860
P3181
P356
P1433
P1476
Catalysis for fluorination and trifluoromethylation
@en
P2093
Adam S. Kamlet
Takeru Furuya
Tobias Ritter
P2860
P2888
P3181
P356
10.1038/NATURE10108
P407
P577
2011-05-26T00:00:00Z
P5875
P6179
1033820449