Long-lived trifluoromethanide anion: a key intermediate in nucleophilic trifluoromethylations.
about
Catalytic asymmetric synthesis of enantioenriched heterocycles bearing a C-CF3 stereogenic center.A Reinterpretation of the Crystal Structure Analysis of [K(crypt-222)]+ CF3- : No Proof for the Trifluoromethanide Ion.The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylations.An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of 18 F-Labeled α-SCF3 Carbonyl Compounds.Organocatalyzed Trifluoromethylation of Ketones and Sulfonyl Fluorides by Fluoroform under a Superbase System.Fluorine-decoupled carbon spectroscopy for the determination of configuration at fully substituted, trifluoromethyl- and perfluoroalkyl-bearing carbons: comparison with 19F-1H heteronuclear Overhauser effect spectroscopy.On Pentakis(pentafluoroethyl)stannate, [Sn(C2 F5 )5 ]- , and the Gas-Free Generation of Pentafluoroethyllithium, LiC2 F5.In situ generation and reactions of p-(trifluoromethyl)benzyl electrophiles: an efficient access to p-(trifluoromethyl)benzyl compounds.Gold(I) Fluorohalides: Theory and Experiment.The Tris(pentafluoroethyl)silanide Anion.The Nucleophilicity of Persistent α-Monofluoromethide Anions.Borazine-CF3- Adducts for Rapid, Room Temperature, and Broad Scope Trifluoromethylation.Synthesis of Aryl Triflones through the Trifluoromethanesulfonylation of Benzynes.Stable (sila)difluoromethylboranes via C-F activation of fluoroform derivatives.Deconstructing covalent organocatalysis.Bis(difluoromethyl)trimethylsilicate Anion: A Key Intermediate in Nucleophilic Difluoromethylation of Enolizable Ketones with Me3 SiCF2 H.Iodine-mediated regioselective synthesis of vinyl triflones from styrenes with CF3SO2Na.Decarboxylative Reissert type trifluoro- and trichloro-methylation of (iso)quinoline derivatives in batch and continuous flow.Direct nucleophilic trifluoromethylation of carbonyl compounds by potent greenhouse gas, fluoroform: Improving the reactivity of anionoid trifluoromethyl species in glymesAnion-Initiated Trifluoromethylation by TMSCF: Deconvolution of the Siliconate-Carbanion Dichotomy by Stopped-Flow NMR/IR
P2860
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P2860
Long-lived trifluoromethanide anion: a key intermediate in nucleophilic trifluoromethylations.
description
2014 nî lūn-bûn
@nan
2014 թուականի Օգոստոսին հրատարակուած գիտական յօդուած
@hyw
2014 թվականի օգոստոսին հրատարակված գիտական հոդված
@hy
2014年の論文
@ja
2014年論文
@yue
2014年論文
@zh-hant
2014年論文
@zh-hk
2014年論文
@zh-mo
2014年論文
@zh-tw
2014年论文
@wuu
name
Long-lived trifluoromethanide ...... ophilic trifluoromethylations.
@ast
Long-lived trifluoromethanide ...... ophilic trifluoromethylations.
@en
Long-lived trifluoromethanide ...... ophilic trifluoromethylations.
@nl
type
label
Long-lived trifluoromethanide ...... ophilic trifluoromethylations.
@ast
Long-lived trifluoromethanide ...... ophilic trifluoromethylations.
@en
Long-lived trifluoromethanide ...... ophilic trifluoromethylations.
@nl
prefLabel
Long-lived trifluoromethanide ...... ophilic trifluoromethylations.
@ast
Long-lived trifluoromethanide ...... ophilic trifluoromethylations.
@en
Long-lived trifluoromethanide ...... ophilic trifluoromethylations.
@nl
P2093
P2860
P50
P356
P1476
Long-lived trifluoromethanide ...... eophilic trifluoromethylations
@en
P2093
G K Surya Prakash
George A Olah
Karl O Christe
Thomas Mathew
P2860
P304
11575-11578
P356
10.1002/ANIE.201406505
P407
P577
2014-08-21T00:00:00Z