Copper-catalyzed trifluoromethylation of unactivated olefins
about
Addition of CF3 across unsaturated moieties: a powerful functionalization toolLate-Stage Fluorination: From Fundamentals to ApplicationAllylic functionalization of unactivated olefins with Grignard reagents.The palladium-catalyzed trifluoromethylation of vinyl sulfonates.Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes.Iron(II)-catalyzed trifluoromethylation of potassium vinyltrifluoroboratesCopper-catalyzed oxytrifluoromethylation of unactivated alkenes.Isolation and Reactivity of Trifluoromethyl Iodonium Salts.Copper-catalyzed trifluoromethylation of alkenes with an electrophilic trifluoromethylating reagentDifluoro-and Trifluoromethylation of Electron-Deficient Alkenes in an Electrochemical Microreactor.Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process.Introduction of fluorine and fluorine-containing functional groups.Late-stage formation of carbon-fluorine bonds.Recent advances in trifluoromethylation of organic compounds using Umemoto's reagents.Recent progress in direct introduction of fluorinated groups on alkenes and alkynes by means of C-H bond functionalization.Recent developments in the trifluoromethylation of alkynes.Catalysis of Radical Reactions: A Radical Chemistry Perspective.Hypervalent Iodine Reagents in High Valent Transition Metal Chemistry.Mechanistic studies on intramolecular C-H trifluoromethoxylation of (hetero)arenes via OCF3-migration.Iodine(III) Reagents in Radical ChemistrySynthesis and applications of α-trifluoromethylated alkylboron compoundsIdentification of monodentate oxazoline as a ligand for copper-promoted ortho-C-H hydroxylation and aminationRegio- and Stereoselective Radical Perfluoroalkyltriflation of Alkynes Using Phenyl(perfluoroalkyl)iodonium Triflates.Efficient Synthesis of β-CF3/SCF3-Substituted Carbonyls via Copper-Catalyzed Electrophilic Ring-Opening Cross-Coupling of Cyclopropanols.Visible-light-induced oxidant and metal-free dehydrogenative cascade trifluoromethylation and oxidation of 1,6-enynes with waterThe dual role of thiourea in the thiotrifluoromethylation of alkenes.Product Control in Alkene Trifluoromethylation: Hydrotrifluoromethylation, Vinylic Trifluoromethylation, and Iodotrifluoromethylation using Togni Reagent.Iron-catalyzed trifluoromethylation with concomitant C-C bond formation via 1,2-migration of an aryl group.Efficient copper-catalyzed direct intramolecular aminotrifluoromethylation of unactivated alkenes with diverse nitrogen-based nucleophiles.Copper-catalyzed regioselective fluorination of allylic halides.Directing-group-assisted copper-catalyzed olefinic trifluoromethylation of electron-deficient alkenes.Copper-catalyzed trifluoromethylation-cyclization of enynes: highly regioselective construction of trifluoromethylated carbocycles and heterocycles.Copper-catalyzed synthesis of trifluoromethyl-substituted isoxazolines.In situ generation of PhI(+)CF3 and transition-metal-free oxidative sp2 C-H trifluoromethylation.Regioselective hydroxylation of C(12)-C(15) fatty acids with fluorinated substituents by cytochrome P450 BM3.Rapid access to β-trifluoromethyl-substituted ketones: harnessing inductive effects in Wacker-type oxidations of internal alkenes.Palladium(II)-catalyzed allylic C-H oxidation of hindered substrates featuring tunable selectivity over extent of oxidation.Copper-catalyzed trifluoromethylation of N,N-dialkylhydrazones.Kinetic resolution of allyl fluorides by enantioselective allylic trifluoromethylation based on silicon-assisted C-F bond cleavage.Transforming Olefins into γ,δ-Unsaturated Nitriles through Copper Catalysis.
P2860
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P2860
Copper-catalyzed trifluoromethylation of unactivated olefins
description
2011 nî lūn-bûn
@nan
2011 թուականի Օգոստոսին հրատարակուած գիտական յօդուած
@hyw
2011 թվականի օգոստոսին հրատարակված գիտական հոդված
@hy
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
name
Copper-catalyzed trifluoromethylation of unactivated olefins
@ast
Copper-catalyzed trifluoromethylation of unactivated olefins
@en
Copper-catalyzed trifluoromethylation of unactivated olefins
@nl
type
label
Copper-catalyzed trifluoromethylation of unactivated olefins
@ast
Copper-catalyzed trifluoromethylation of unactivated olefins
@en
Copper-catalyzed trifluoromethylation of unactivated olefins
@nl
prefLabel
Copper-catalyzed trifluoromethylation of unactivated olefins
@ast
Copper-catalyzed trifluoromethylation of unactivated olefins
@en
Copper-catalyzed trifluoromethylation of unactivated olefins
@nl
P2860
P356
P1476
Copper-catalyzed trifluoromethylation of unactivated olefins
@en
P2093
Andrew T Parsons
Stephen L Buchwald
P2860
P304
P356
10.1002/ANIE.201104053
P407
P577
2011-08-25T00:00:00Z