Kinetic resolution of allyl fluorides by enantioselective allylic trifluoromethylation based on silicon-assisted C-F bond cleavage.
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Stereoconvergent Negishi Arylations of Racemic Secondary Alkyl Electrophiles: Differentiating between a CF3 and an Alkyl GroupAdvances in catalytic enantioselective fluorination, mono-, di-, and trifluoromethylation, and trifluoromethylthiolation reactions.The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylations.Diastereoselective additive trifluoromethylation/halogenation of isoxazole triflones: synthesis of all-carbon-functionalized trifluoromethyl isoxazoline triflonesSterically Demanding Unsymmetrical Diaryl-λ(3)-iodanes for Electrophilic Pentafluorophenylation and an Approach to α-Pentafluorophenyl Carbonyl Compounds with an All-Carbon Stereocenter.Synthesis of chiral (tetrazolyl)methyl-containing acrylates via silicon-induced organocatalytic kinetic resolution of Morita-Baylis-Hillman fluorides.Asymmetric Traceless Petasis Borono-Mannich Reactions of Enals: Reductive Transposition of Allylic Diazenes.Highly Stereoselective Gold-Catalyzed Coupling of Diazo Reagents and Fluorinated Enol Silyl Ethers to Tetrasubstituted Alkenes.A simple base-mediated synthesis of diverse functionalized ring-fluorinated 4H-pyrans via double direct C-F substitutions.Lewis Acid Catalyzed Asymmetric Three-Component Coupling Reaction: Facile Synthesis of α-Fluoromethylated Tertiary Alcohols.Catalytic Silylations of Alcohols: Turning Simple Protecting-Group Strategies into Powerful Enantioselective Synthetic Methods.Asymmetric Desymmetrization via Metal-Free C-F Bond Activation: Synthesis of 3,5-Diaryl-5-fluoromethyloxazolidin-2-ones with Quaternary Carbon Centers.Palladium-catalyzed synthesis of monofluoroalkenes from 3,3-difluoropropenes using dimethylmalonate and derivatives as nucleophiles.Asymmetric chlorination of 4-substituted pyrazolones catalyzed by natural cinchona alkaloid.
P2860
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P2860
Kinetic resolution of allyl fluorides by enantioselective allylic trifluoromethylation based on silicon-assisted C-F bond cleavage.
description
2013 nî lūn-bûn
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2013年の論文
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2013年学术文章
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2013年学术文章
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2013年学术文章
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2013年学术文章
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2013年学术文章
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2013年学术文章
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2013年學術文章
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2013年學術文章
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name
Kinetic resolution of allyl fl ...... on-assisted C-F bond cleavage.
@en
Kinetic resolution of allyl fl ...... on-assisted C-F bond cleavage.
@nl
type
label
Kinetic resolution of allyl fl ...... on-assisted C-F bond cleavage.
@en
Kinetic resolution of allyl fl ...... on-assisted C-F bond cleavage.
@nl
prefLabel
Kinetic resolution of allyl fl ...... on-assisted C-F bond cleavage.
@en
Kinetic resolution of allyl fl ...... on-assisted C-F bond cleavage.
@nl
P2093
P2860
P356
P1476
Kinetic resolution of allyl fl ...... on-assisted C-F bond cleavage.
@en
P2093
Akihito Yamano
Etsuko Tokunaga
Hiromi Taira
Kazunobu Fukushi
Motoo Shiro
Naoyuki Shibata
Norio Shibata
Takayuki Nishimine
P2860
P304
P356
10.1002/ANIE.201308071
P407
P577
2013-11-07T00:00:00Z