The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylations.
about
Visible-light-induced oxidant and metal-free dehydrogenative cascade trifluoromethylation and oxidation of 1,6-enynes with waterFluorinated Vinylsilanes from the Copper-Catalyzed Defluorosilylation of Fluoroalkene Feedstocks.Two-step conversion of carboxylic esters into distally fluorinated ketones via ring cleavage of cyclopropanol intermediates: application of sulfinate salts as fluoroalkylating reagents.The Nucleophilicity of Persistent α-Monofluoromethide Anions.Catalytic Enantioselective Michael Addition Reactions of Tertiary Enolates Generated by Detrifluoroacetylation.Organocatalytic Insertion of Isatins into Aryl Difluoronitromethyl Ketones.Catalytic Enantioselective Synthesis of Highly Functionalized Difluoromethylated Cyclopropanes.Taming Metal/Fluorine Carbenoids.Gram-scale preparation of negative-type liquid crystals with a CF2CF2-carbocycle unit via an improved short-step synthetic protocol.Silver-mediated oxidative C-H difluoromethylation of phenanthridines and 1,10-phenanthrolines.Synthesis of γ-keto sulfones by copper-catalyzed oxidative sulfonylation of tertiary cyclopropanols.Highly Stereoselective Gold-Catalyzed Coupling of Diazo Reagents and Fluorinated Enol Silyl Ethers to Tetrasubstituted Alkenes.Nickel-catalyzed direct C-H trifluoroethylation of heteroarenes with trifluoroethyl iodide.Catalytic Asymmetric 1,3-Dipolar Cycloaddition of β-Fluoroalkylated α,β-Unsaturated 2-Pyridylsulfones with Nitrones for Chiral Fluoroalkylated Isoxazolidines and γ-Amino Alcohols.Diastereoselective [3 + 2] cycloaddition of 3-ylideneoxindoles with in situ generated CF2HCHN2: syntheses of CF2H-containing spirooxindoles.Synthesis of fluoro-functionalized diaryl-λ3-iodonium salts and their cytotoxicity against human lymphoma U937 cells.Rapid access to diverse, trifluoromethyl-substituted alkenes using complementary strategies.Direct nucleophilic trifluoromethylation of carbonyl compounds by potent greenhouse gas, fluoroform: Improving the reactivity of anionoid trifluoromethyl species in glymesAnion-Initiated Trifluoromethylation by TMSCF: Deconvolution of the Siliconate-Carbanion Dichotomy by Stopped-Flow NMR/IRA Chiron approach towards the stereoselective synthesis of polyfluorinated carbohydrates
P2860
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P2860
The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylations.
description
2016 nî lūn-bûn
@nan
2016年の論文
@ja
2016年学术文章
@wuu
2016年学术文章
@zh-cn
2016年学术文章
@zh-hans
2016年学术文章
@zh-my
2016年学术文章
@zh-sg
2016年學術文章
@yue
2016年學術文章
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2016年學術文章
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name
The unique fluorine effects in ...... sights into fluoroalkylations.
@en
type
label
The unique fluorine effects in ...... sights into fluoroalkylations.
@en
prefLabel
The unique fluorine effects in ...... sights into fluoroalkylations.
@en
P2860
P356
P1476
The unique fluorine effects in ...... sights into fluoroalkylations.
@en
P2093
P2860
P356
10.1039/C6CS00351F
P577
2016-08-08T00:00:00Z