about
Recent Advances in Solid Catalysts Obtained by Metalloporphyrins Immobilization on Layered Anionic Exchangers: A Short Review and Some New Catalytic ResultsMoving protons and electrons in biomimetic systemsA hyperactive cobalt-substituted extradiol-cleaving catechol dioxygenaseSite-Directed Mutagenesis of Gln103 Reveals the Influence of This Residue on the Redox Properties and Stability of MauGDirect Selective Oxidative Functionalization of C-H Bonds with H₂O₂: Mn-Aminopyridine Complexes Challenge the Dominance of Non-Heme Fe CatalystsMechanistic aspects of CYP74 allene oxide synthases and related cytochrome P450 enzymesTowards alternatives to anodic water oxidation: basket-handle thiolate Fe(III) porphyrins for electrocatalytic hydrocarbon oxidation.Evidence for an ionic intermediate in the transformation of fatty acid hydroperoxide by a catalase-related allene oxide synthase from the Cyanobacterium Acaryochloris marinaCarbon-heteroatom bond formation catalysed by organometallic complexesSulfur versus iron oxidation in an iron-thiolate model complexThe crystal structure of a high-spin oxoiron(IV) complex and characterization of its self-decay pathwayEnhanced catalytic activity and unexpected products from the oxidation of cyclohexene by organic nanoparticles of 5,10,15,20-tetrakis-(2,3,4,5,6-pentafluorophenyl)porphyrinatoiron(III) in water by using O2.Kinetic solvent isotope effect in steady-state turnover by CYP19A1 suggests involvement of Compound 1 for both hydroxylation and aromatization steps.A family of diiron monooxygenases catalyzing amino acid beta-hydroxylation in antibiotic biosynthesis.Mössbauer, electron paramagnetic resonance, and density functional theory studies of synthetic S = 1/2 Fe(III)-O-Fe(IV)═O complexes. Superexchange-mediated spin transition at the Fe(IV)═O site.Oxidative aliphatic C-H fluorination with fluoride ion catalyzed by a manganese porphyrin.Functional diversity of 2-oxoglutarate/Fe(II)-dependent dioxygenases in plant metabolism.A series of hybrid P450 BM3 enzymes with different catalytic activity in the light-initiated hydroxylation of lauric acidIsolation and structural and electronic characterization of salts of the decamethylferrocene dication.Molecular probes of the mechanism of cytochrome P450. Oxygen traps a substrate radical intermediateReaction mechanisms of 15-hydroperoxyeicosatetraenoic acid catalyzed by human prostacyclin and thromboxane synthases.Tuning the reactivity of Fe(V)(O) toward C-H bonds at room temperature: effect of waterFerryl protonation in oxoiron(IV) porphyrins and its role in oxygen transferSubstrate-triggered activation of a synthetic [Fe2(μ-O)2] diamond core for C-H bond cleavage.Tuning the Reactivity of Mononuclear Nonheme Manganese(IV)-Oxo Complexes by Triflic Acid.Axial ligand tuning of a nonheme iron(IV)-oxo unit for hydrogen atom abstractionSelective hydroxylation of alkanes by an extracellular fungal peroxygenase.Hydrogen-bonding effects on the reactivity of [X-Fe(III)-O-Fe(IV)═O] (X = OH, F) complexes toward C-H bond cleavage.Reactivity patterns of cytochrome P450 enzymes: multifunctionality of the active species, and the two states-two oxidants conundrum.Identity and mechanisms of alkane-oxidizing metalloenzymes from deep-sea hydrothermal vents.Selective, Tunable O2 Binding in Cobalt(II)-Triazolate/Pyrazolate Metal-Organic Frameworks.Differential coordination demands in Fe versus Mn water-soluble cationic metalloporphyrins translate into remarkably different aqueous redox chemistry and biology.Versatility of biological non-heme Fe(II) centers in oxygen activation reactions.Constructing de novo biosynthetic pathways for chemical synthesis inside living cells.Lessons from nature: unraveling biological CH bond activationHydrogen peroxide dependent cis-dihydroxylation of benzoate by fully oxidized benzoate 1,2-dioxygenaseMolecular imaging of labile iron(II) pools in living cells with a turn-on fluorescent probe.Kinetic solvent isotope effect in human P450 CYP17A1-mediated androgen formation: evidence for a reactive peroxoanion intermediate.Do Spin State and Spin Density Affect Hydrogen Atom Transfer Reactivity?Reactivities of Fe(IV) complexes with oxo, hydroxo, and alkylperoxo ligands: an experimental and computational study.
P2860
Q26764779-48613B91-60E8-4512-BB38-3CD080309D78Q26829547-ECEA2655-489B-4284-89CC-09F8E8D1A64DQ27666296-833C8363-117D-4B21-A6ED-5B981341930FQ27681679-3E0D2345-B700-4756-A5A3-31CDFC8573C6Q28066116-BD01D77B-0022-4360-8D43-4D076B88D6DFQ28749793-8088A11D-CCC5-4F30-A0CF-0911B2F35353Q30560968-CA55FCC4-A7DF-42E9-B4C1-B3578F2E73F4Q33468772-F0710469-3415-4C74-9185-8E178756F462Q33642210-38B4633D-388E-48AE-8BFD-5E2E2601A9E7Q33744230-2A8CFBA0-F20B-4A6E-AD2F-6C4176AF3A83Q33990453-227FB857-2560-4F52-823D-9372A9AC616CQ34017772-3F68DC69-C0A2-42BF-B6FA-F9211CB09217Q34067102-1BAF63BD-0BE2-4C5A-86CA-86EC8577048FQ34100542-80B2905D-95FF-49CA-A41F-537DF3EE14ABQ34210757-E3C54647-46C0-49E9-A925-F37C2F9BCDFEQ34300091-0DD38AF2-02F8-42FB-8C25-80221B981DEBQ34312125-B133FD5D-CFBF-4BB7-A88F-5A98794F70B3Q34393549-A06E7A5E-4B5D-4A4D-B5F1-E2A7ECD47C85Q34537128-2A5BF038-9C2C-418D-943D-26C4290873EDQ34586651-3D2A3C41-A647-4AD1-8FD9-5E1434F131BFQ34622823-35E82CD8-E45D-4DE5-A2B3-8E1B8A9F0F9EQ35093837-F3A2960B-BC87-4ED0-BEBB-5D1A9DEF2EE3Q35189151-89615F89-7005-470F-A080-6A9F880CFFF2Q35332343-311874E9-B42F-45A1-A8AC-A84B2FAB260EQ35801360-10C96D93-3471-4A29-BC59-7CCCBD4ADAEEQ36288485-14D9944D-778D-46E9-B628-B83FF8A8500FQ36650628-E427B1E4-DE44-4F59-9899-5F191D4C2916Q36784234-09B356F0-FE29-43DF-8BB1-8E6171EC5AE5Q36834132-49EF6078-5487-4F5C-BD9F-70D0CD959E69Q36963039-675FDC47-2478-418A-A19E-DD30435DAA39Q36990886-26C99A52-7864-4F5C-89BF-1529287C7981Q37063743-4BFB56FD-6711-4829-AC6B-DF9F38140F03Q37085698-A4A31A11-2845-427E-99A2-39228E41218EQ37158874-9EBE1CA4-57A6-493C-8117-B97B6DEED505Q37177334-C507BE31-95AC-4463-98E6-CEE7BE26B4B4Q37287300-D20D944C-B35B-4A49-A924-ABB768DEBD8CQ37336347-A3E49D15-654A-4C1A-9B67-5385A85073CCQ37401626-6567F7F9-3EFE-463B-93E7-250515066E7EQ37451262-99626A69-ED17-47B2-B51D-7EA742215931Q37464122-E5C33C5E-D2D4-484B-B212-6A64A6298C7D
P2860
description
2006 nî lūn-bûn
@nan
2006年の論文
@ja
2006年学术文章
@wuu
2006年学术文章
@zh-cn
2006年学术文章
@zh-hans
2006年学术文章
@zh-my
2006年学术文章
@zh-sg
2006年學術文章
@yue
2006年學術文章
@zh
2006年學術文章
@zh-hant
name
High-valent iron in chemical and biological oxidations.
@ast
High-valent iron in chemical and biological oxidations.
@en
type
label
High-valent iron in chemical and biological oxidations.
@ast
High-valent iron in chemical and biological oxidations.
@en
prefLabel
High-valent iron in chemical and biological oxidations.
@ast
High-valent iron in chemical and biological oxidations.
@en
P1476
High-valent iron in chemical and biological oxidations.
@en
P2093
John T Groves
P304
P356
10.1016/J.JINORGBIO.2006.01.012
P577
2006-03-03T00:00:00Z