Recent developments on the trifluoromethylation of (hetero)arenes.
about
Carbon-carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylationsAddition of CF3 across unsaturated moieties: a powerful functionalization toolSynthetic and mechanistic aspects of the regioselective base-mediated reaction of perfluoroalkyl- and perfluoroarylsilanes with heterocyclic N-oxidesPalladium-catalyzed intramolecular C-H difluoroalkylation: synthesis of substituted 3,3-difluoro-2-oxindoles.4-Trifluoromethyl-p-quinols as dielectrophiles: three-component, double nucleophilic addition/aromatization reactions.Copper-catalyzed trifluoromethylation of alkenes with an electrophilic trifluoromethylating reagentRapid and efficient trifluoromethylation of aromatic and heteroaromatic compounds using potassium trifluoroacetate enabled by a flow system.Recent advances in trifluoromethylation reactions with electrophilic trifluoromethylating reagents.Recent developments in the trifluoromethylation of alkynes.Metal-free trifluoromethylation of aromatic and heteroaromatic aldehydes and ketones.Pd-catalyzed α-arylation of trimethylsilyl enolates of α,α-difluoroacetamides.Biocatalytic trifluoromethylation of unprotected phenols.Practical method for the Cu-mediated trifluoromethylation of arylboronic acids with CF3 radicals derived from NaSO2CF3 and tert-butyl hydroperoxide (TBHP).Product Control in Alkene Trifluoromethylation: Hydrotrifluoromethylation, Vinylic Trifluoromethylation, and Iodotrifluoromethylation using Togni Reagent.Waste as catalyst: tandem Wittig/conjugate reduction sequence to α-CF3 γ-keto esters that uses Ph3PO as catalyst for the chemoselective conjugate reduction.Iron-catalyzed trifluoromethylation with concomitant C-C bond formation via 1,2-migration of an aryl group.Copper-mediated deoxygenative trifluoromethylation of benzylic xanthates: generation of a C-CF(3) bond from an O-based electrophile.Efficient copper-catalyzed direct intramolecular aminotrifluoromethylation of unactivated alkenes with diverse nitrogen-based nucleophiles.Copper-catalyzed regioselective fluorination of allylic halides.Copper-catalyzed trifluoromethylation-cyclization of enynes: highly regioselective construction of trifluoromethylated carbocycles and heterocycles.Visible-light hypervalent iodide carboxylate photo(trifluoro)methylations and controlled radical polymerization of fluorinated alkenes.Sandmeyer trifluoromethylation of arenediazonium tetrafluoroborates.In situ generation of PhI(+)CF3 and transition-metal-free oxidative sp2 C-H trifluoromethylation.Anionic Derivatives of Perfluorinated Trimethylgold.A broadly applicable [18F]trifluoromethylation of aryl and heteroaryl iodides for PET imaging.Oxidative trifluoromethylation of unactivated olefins: an efficient and practical synthesis of α-trifluoromethyl-substituted ketones.Copper-mediated aerobic (phenylsulfonyl)difluoromethylation of arylboronic acids with difluoromethyl phenyl sulfone.Oxidative nucleophilic strategy for synthesis of thiocyanates and trifluoromethyl sulfides from thiols.Transition-metal-free synthesis of β-trifluoromethylated enamines with trifluoromethanesulfinate.Selective Oxytrifluoromethylation of Allylamines with CO2.Electron-Catalyzed Fluoroalkylation of Vinyl Azides.Trifluoromethylthiolation and Trifluoromethylselenolation of α-Diazo Esters Catalyzed by Copper.Palladium-Catalyzed Trifluoromethylation of (Hetero)Arenes with CF3 Br.Catalytic Oxidative Trifluoromethoxylation of Allylic C-H Bonds Using a Palladium Catalyst.The first nucleophilic C-H perfluoroalkylation of aromatic compounds via (arene)tricarbonylchromium complexes.Denitrogenative hydrofluorination of aromatic aldehyde hydrazones using (difluoroiodo)toluene.Copper-catalyzed cyclic oxytrifluoromethylation of 2,3-allenoic acids to trifluoromethylated butenolides.Synthesis of difluoromethyl thioethers from difluoromethyl trimethylsilane and organothiocyanates generated in situ.Iron-catalyzed trifluoromethylation of enamide.PhI(OAc)(2) -mediated radical trifluoromethylation of vinyl azides with Me(3)SiCF(3).
P2860
Q26770611-AE46AD30-7164-45E8-BFD6-DF7F305DEACBQ27014225-E3A0521D-7E20-4B00-ACC7-CAB656A6ED77Q34053493-CB260420-431E-4EE5-92A0-613736F1EA38Q35259134-689874C9-2B1C-46D2-A8A2-3235EE26F239Q36953783-6B2668D8-EAE9-4758-8FFF-1CFA520010E8Q37406227-CC81D4FE-C137-450F-8507-77B220844C97Q37418628-DF6B6B40-43FD-416D-BD08-AD13D4102B37Q38261804-F5AD84F6-E8F9-4F98-B008-DF205780EE33Q38367448-47753146-58E8-41B6-B29D-A6713305D858Q41816387-93E32559-C4C6-485C-BCE3-06F0A8319D4BQ41990532-22B22D7A-76EE-4A95-9232-0ACA9BC4C6C4Q42034665-AFB64A2B-C1E2-433A-8A68-FF19D643A0FCQ42123910-4070B3B9-9309-4023-9CBA-65577B4F5E70Q42591247-BE9A9C40-C1E3-4A31-8F3F-19374CF23A8CQ43434792-EB900A01-2E15-4E40-AABE-640E6E3DBAF7Q43482084-A9EE8056-9B00-4E37-9647-1D96B40B4FA6Q43547800-B2F84316-FDE5-49A6-B1E9-6E45C2B6AFD2Q43771259-63B0FF16-16EB-4440-949F-5E549C00A3FCQ44295386-B118B4EC-8D32-4A97-813C-637A8CA89C7FQ44631339-56680A0B-E4C4-45B4-BFD9-B76FE7865ACCQ45259573-CC9885CF-F534-4EB6-8380-803C36B23D73Q45384639-6A4154C7-CBF7-496C-A418-7E4726BE7F65Q45719714-1FA87147-2E26-4FCC-8599-E2B220DAC603Q46401857-C9ABB439-E084-4017-B10E-31E90A45716EQ46441354-C8DEF57D-C343-4E9C-8F16-239341E57CE1Q46578195-09A71A19-04BF-40C4-AB50-A5B29FC80E87Q46599184-DC84932B-379A-41C8-B92B-6D3E48BF1D6CQ46827834-CAE7DA88-AE7F-4C18-A3CF-81CD55AFD998Q47992830-ABBEE096-D8E6-45F5-8E55-A72F1AC44EA1Q48161866-3E808382-9A1C-4DBE-ACA0-4BDB043CB113Q48174654-13FF855D-E52F-4A42-AEE5-9A122B4DE40CQ48174732-98DE029B-7B57-4D52-93EB-8AF076895628Q48255113-F4D48C14-D218-4E08-814E-7D5F4EDDAEE1Q48287405-2C66EAA2-66BE-4B5D-B4F0-91E40C1DE067Q48295776-B3AA2648-7051-4E66-835C-75CEC3ADD301Q48296872-5D6BFC26-F5B0-4F6F-AB11-1636161A2C8CQ50473124-8CD1669E-42D1-4EA3-9ADB-125B077A80D7Q50999506-4C33DAB4-8919-4137-B54C-7EE6E4874B1EQ51015743-C4D6AA93-0754-4D5F-9152-CDA7D14E3254Q51132661-387C71FC-7FBE-456B-8C7C-26B43F5EDC4D
P2860
Recent developments on the trifluoromethylation of (hetero)arenes.
description
article científic
@ca
article scientifique
@fr
articol științific
@ro
articolo scientifico
@it
artigo científico
@gl
artigo científico
@pt
artigo científico
@pt-br
artikel ilmiah
@id
artikull shkencor
@sq
artículo científico
@es
name
Recent developments on the trifluoromethylation of (hetero)arenes.
@en
type
label
Recent developments on the trifluoromethylation of (hetero)arenes.
@en
prefLabel
Recent developments on the trifluoromethylation of (hetero)arenes.
@en
P2860
P356
P1476
Recent developments on the trifluoromethylation of (hetero)arenes.
@en
P2093
Helfried Neumann
P2860
P304
P356
10.1002/ASIA.201200211
P577
2012-06-19T00:00:00Z