Transition metal-catalyzed fluorination of multi carbon-carbon bonds: new strategies for fluorinated heterocycles.
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Decarboxylative fluorination strategies for accessing medicinally- relevant productsSilver-catalyzed vinylogous fluorination of vinyl diazoacetatesAminofluorination of 2-alkynylanilines: a Au-catalyzed entry to fluorinated indoles.Asymmetric palladium-catalyzed directed intermolecular fluoroarylation of styrenes.Metal-free trifluoromethylation of aromatic and heteroaromatic aldehydes and ketones.Copper-catalyzed decarboxylative trifluoromethylation of allylic bromodifluoroacetatesCatalytic Intramolecular Aminofluorination, Oxyfluorination, and Carbofluorination with a Stable and Versatile Hypervalent Fluoroiodine Reagent.C-F bond formation with fluoride anions--highly selective iodofluorination of simple allenes.Copper-catalyzed regioselective fluorination of allylic halides.Regioselective palladium-catalyzed intramolecular oxidative aminofluorination of unactivated alkenes.Intramolecular Fluorocyclizations of Unsaturated Carboxylic Acids with a Stable Hypervalent Fluoroiodane Reagent.Highly regio- and stereoselective trans-iodofluorination of ynamides enabling the synthesis of (E)-α-fluoro-β-iodoenamides.Visible-light-induced thiotrifluoromethylation of terminal alkenes with sodium triflinate and benzenesulfonothioates.Catalyst free synthesis of α-fluoro-β-hydroxy ketones/α-fluoro-ynols via electrophilic fluorination of tertiary propargyl alcohols using Selectfluor™ (F-TEDA-BF4).anti-Selective aminofluorination of alkenes with amidines mediated by hypervalent iodine(iii) reagents.Silver-promoted (radio)fluorination of unsaturated carbamates via a radical process.Mild and metal-free oxy- and amino-fluorination for the synthesis of fluorinated heterocycles.Synthesis of fluorinated heteroaromatics through formal substitution of a nitro group by fluorine under transition-metal-free conditions.Reactivity of platinum alkyne complexes towards N-fluorobenzenesulfonimide: formation of platinum compounds bearing a β-fluorovinyl ligand.Oxidative radical 1,2-alkylarylation of alkenes with α-C(sp(3))-H bonds of acetonitriles involving 1,2-aryl migration.Revised role of selectfluor in homogeneous Au-catalyzed oxidative C-O bond formations.Catalytic and asymmetric fluorolactonisations of carboxylic acids through anion phase transfer.Access to benzo-fused nine-membered heterocyclic alkenes with a trifluoromethyl carbinol moiety via a double decarboxylative formal ring-expansion process under palladium catalysis.
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P2860
Transition metal-catalyzed fluorination of multi carbon-carbon bonds: new strategies for fluorinated heterocycles.
description
article científic
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article scientifique
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articol științific
@ro
articolo scientifico
@it
artigo científico
@gl
artigo científico
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artigo científico
@pt-br
artikel ilmiah
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artikull shkencor
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artículo científico
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name
Transition metal-catalyzed flu ...... for fluorinated heterocycles.
@en
type
label
Transition metal-catalyzed flu ...... for fluorinated heterocycles.
@en
prefLabel
Transition metal-catalyzed flu ...... for fluorinated heterocycles.
@en
P2860
P356
P1476
Transition metal-catalyzed flu ...... s for fluorinated heterocycles
@en
P2093
Guosheng Liu
P2860
P304
P356
10.1039/C2OB25702E
P50
P577
2012-06-26T00:00:00Z