Versatile Pd(OTf)2 x 2 H2O-catalyzed ortho-fluorination using NMP as a promoter.
about
Formation of ArF from LPdAr(F): catalytic conversion of aryl triflates to aryl fluoridesCatalysis for fluorination and trifluoromethylationPalladium-Catalyzed Ligand-Directed C−H Functionalization ReactionsSynthetic and mechanistic studies on Pd(0)-catalyzed diamination of conjugated dienes.Bimetallic reductive elimination from dinuclear Pd(III) complexes.On the mechanism of palladium-catalyzed aromatic C-H oxidationFe(III)/NaBH4-mediated free radical hydrofluorination of unactivated alkenesStudying regioisomer formation in the Pd-catalyzed fluorination of aryl triflates by deuterium labeling.Accelerating palladium-catalyzed C-F bond formation: use of a microflow packed-bed reactorPd(II)-catalyzed para-selective C-H arylation of monosubstituted arenes.Evidence for in situ catalyst modification during the Pd-catalyzed conversion of aryl triflates to aryl fluorides.A Fluorinated Ligand Enables Room-Temperature and Regioselective Pd-Catalyzed Fluorination of Aryl Triflates and Bromides.Catalytic enantioselective cyclization and C3-fluorination of polyenes.Copper-catalyzed, directing group-assisted fluorination of arene and heteroarene C-H bonds.An improved catalyst system for the Pd-catalyzed fluorination of (hetero)aryl triflates.The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes.Bystanding F+ oxidants enable selective reductive elimination from high-valent metal centers in catalysis.If C-H bonds could talk: selective C-H bond oxidationTransition metal-catalyzed fluorination of multi carbon-carbon bonds: new strategies for fluorinated heterocycles.Introduction of fluorine and fluorine-containing functional groups.Recent advances in trifluoromethylation of organic compounds using Umemoto's reagents.Recent progress in direct introduction of fluorinated groups on alkenes and alkynes by means of C-H bond functionalization.Heterocycle Formation via Palladium-Catalyzed C-H Functionalization.Silver-mediated trifluoromethoxylation of aryl stannanes and arylboronic acids.Hypervalent Iodine Reagents in High Valent Transition Metal Chemistry.O-acetyl oximes as transformable directing groups for Pd-catalyzed C-H bond functionalization.Aryl-CF(3) bond-forming reductive elimination from palladium(IV)Intercepting Wacker intermediates with arenes: C-H functionalization and dearomatizationMechanism of C-F reductive elimination from palladium(IV) fluorides.Palladium-catalyzed directing group-assisted C8-triflation of naphthalenes.Pd(II)-catalyzed C-H functionalizations directed by distal weakly coordinating functional groupsVanadium-Catalyzed C(sp(3))-H Fluorination Reactions.Ligand-enabled cross-coupling of C(sp3)-H bonds with arylboron reagents via Pd(II)/Pd(0) catalysis.Mechanistic comparison between Pd-catalyzed ligand-directed C-H chlorination and C-H acetoxylation.Electrophilic fluorination of cationic Pt-aryl complexesC-F Bond Formation for the Synthesis of Aryl Fluorides.Ligand-Enabled Stereoselective β-C(sp(3))-H Fluorination: Synthesis of Unnatural Enantiopure anti-β-Fluoro-α-amino Acids.Steric Crowding Makes Challenging C(sp3)-F Reductive Eliminations Feasible.Pd-catalyzed C-H fluorination with nucleophilic fluoride.Ligand-accelerated C-H activation reactions: evidence for a switch of mechanism.
P2860
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P2860
Versatile Pd(OTf)2 x 2 H2O-catalyzed ortho-fluorination using NMP as a promoter.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年論文
@yue
2009年論文
@zh-hant
2009年論文
@zh-hk
2009年論文
@zh-mo
2009年論文
@zh-tw
2009年论文
@wuu
2009年论文
@zh
2009年论文
@zh-cn
name
Versatile Pd(OTf)2 x 2 H2O-catalyzed ortho-fluorination using NMP as a promoter.
@en
type
label
Versatile Pd(OTf)2 x 2 H2O-catalyzed ortho-fluorination using NMP as a promoter.
@en
prefLabel
Versatile Pd(OTf)2 x 2 H2O-catalyzed ortho-fluorination using NMP as a promoter.
@en
P356
P1476
Versatile Pd(OTf)2 x 2 H2O-catalyzed ortho-fluorination using NMP as a promoter.
@en
P2093
Tian-Sheng Mei
Xisheng Wang
P304
P356
10.1021/JA901352K
P407
P50
P577
2009-06-01T00:00:00Z