Understanding the differential performance of Rh2(esp)2 as a catalyst for C-H amination.
about
Simultaneous structure-activity studies and arming of natural products by C-H amination reveal cellular targets of eupalmerin acetate.Chemo- and site-selective derivatizations of natural products enabling biological studies.Selective intermolecular amination of C-H bonds at tertiary carbon centers.Metal-catalyzed nitrogen-atom transfer methods for the oxidation of aliphatic C-H bonds.Rhodium carbenoid approach for introduction of 4-substituted (Z)-pent-2-enoates into sterically encumbered pyrroles and indoles.Development of a concise synthesis of (-)-oseltamivir (Tamiflu)Rh2(II)-catalyzed nitro-group migration reactions: selective synthesis of 3-nitroindoles from β-nitro styryl azidesRhodium-Catalyzed C-H Amination - An Enabling Method for Chemical Synthesis.Rh(II)2-catalyzed synthesis of α-, β-, or δ-carbolines from aryl azides.Capturing fleeting intermediates in a catalytic C-H amination reaction cycle.Alkynoate synthesis through the vinylogous reactivity of rhodium(II) carbenoids.Iron(II) bromide-catalyzed intramolecular C-H bond amination [1,2]-shift tandem reactions of aryl azides.Intramolecular Ir(I)-catalyzed benzylic C-H bond amination of ortho-substituted aryl azides.Development of a Suzuki cross-coupling reaction between 2-azidoarylboronic pinacolate esters and vinyl triflates to enable the synthesis of [2,3]-fused indole heterocycles.Role of metal-oxo complexes in the cleavage of C-H bonds.Versatile reactivity of Pd-catalysts: mechanistic features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed C-H bond functionalization.Metal-Catalyzed and Metal-Free Intermolecular Amination of Light Alkanes and BenzenesApplication of diazene-directed fragment assembly to the total synthesis and stereochemical assignment of (+)-desmethyl-meso-chimonanthine and related heterodimeric alkaloids.Rhodium-catalyzed synthesis of 2,3-disubstituted indoles from β,β-disubstituted stryryl azides.Catalytic oxyamidation of indoles.Ketimido metallophthalocyanines: an approach to phthalocyanine-supported mononuclear high-valent ruthenium complexes.Unveiling latent α-iminocarbene reactivity for intermolecular cascade reactions through alkyne oxidative amination.Rhodium-Catalyzed Stereospecific C-H Amination for the Construction of Spiroaminal Cores: Reactivity Difference between Nitrenoid and Carbenoid Species against Amide Functionality.Synthesis of azasilacyclopentenes and silanols via Huisgen cycloaddition-initiated C-H bond insertion cascades.Synthesis and Properties of New N-Heteroheptacenes for Solution-Based Organic Field Effect Transistors.Site-selective bromination of sp3 C-H bonds.Dirhodium(II) carboxylate catalyzed formation of 1,2,3-trisubstituted indoles from styryl azides.
P2860
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P2860
Understanding the differential performance of Rh2(esp)2 as a catalyst for C-H amination.
description
2009 nî lūn-bûn
@nan
2009年の論文
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2009年学术文章
@wuu
2009年学术文章
@zh-cn
2009年学术文章
@zh-hans
2009年学术文章
@zh-my
2009年学术文章
@zh-sg
2009年學術文章
@yue
2009年學術文章
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2009年學術文章
@zh-hant
name
Understanding the differential performance of Rh2
@nl
Understanding the differential performance of Rh2(esp)2 as a catalyst for C-H amination.
@en
type
label
Understanding the differential performance of Rh2
@nl
Understanding the differential performance of Rh2(esp)2 as a catalyst for C-H amination.
@en
prefLabel
Understanding the differential performance of Rh2
@nl
Understanding the differential performance of Rh2(esp)2 as a catalyst for C-H amination.
@en
P2860
P356
P1476
Understanding the differential performance of Rh2(esp)2 as a catalyst for C-H amination.
@en
P2093
David N Zalatan
P2860
P304
P356
10.1021/JA902893U
P407
P577
2009-06-01T00:00:00Z