about
Experimental and computational evidence for gold vinylidenes: generation from terminal alkynes via a bifurcation pathway and facile C-H insertionsMechanism of gold(I)-catalyzed rearrangements of acetylenic amine-N-oxides: computational investigations lead to a new mechanism confirmed by experiment.[3,3]-Sigmatropic rearrangement versus carbene formation in gold-catalyzed transformations of alkynyl aryl sulfoxides: mechanistic studies and expanded reaction scopeA flexible and stereoselective synthesis of azetidin-3-ones through gold-catalyzed intermolecular oxidation of alkynes.A non-diazo approach to α-oxo gold carbenes via gold-catalyzed alkyne oxidation.Catalytic asymmetric dearomatization (CADA) reactions of phenol and aniline derivatives.Synthesis-enabled probing of mitosene structural space leads to improved IC₅₀ over mitomycin C.Gold-catalyzed efficient synthesis of azepan-4-ones via a two-step [5 + 2] annulation.Tempering the reactivities of postulated α-oxo gold carbenes using bidentate ligands: implication of tricoordinated gold intermediates and the development of an expedient bimolecular assembly of 2,4-disubstituted oxazolesOptimizing P,N-bidentate ligands for oxidative gold catalysis: efficient intermolecular trapping of α-oxo gold carbenes by carboxylic acids.Gold-catalyzed regioselective oxidation of propargylic carboxylates: a reliable access to α-carboxy-α,β-unsaturated ketones/aldehydes.A Non-Diazo Strategy to Cyclopropanation via Oxidatively Generated Gold Carbene: the Benefit of A Conformationally Rigid P,N-Bidentate Ligand.Gold-Catalyzed Oxidation of Propargylic Ethers with Internal C-C Triple Bonds: Impressive Regioselectivity Enabled by Inductive Effect.Soft propargylic deprotonation: designed ligand enables Au-catalyzed isomerization of alkynes to 1,3-dienes.Gold-catalyzed highly regioselective oxidation of C-C triple bonds without acid additives: propargyl moieties as masked α,β-unsaturated carbonyls.Rapid access to chroman-3-ones through gold-catalyzed oxidation of propargyl aryl ethers.Gold-catalyzed one-step practical synthesis of oxetan-3-ones from readily available propargylic alcohols.One-pot synthesis of fused pyrroles through a key gold-catalysis-triggered cascade.Expanding the horizon of intermolecular trapping of in situ generated α-oxo gold carbenes: efficient oxidative union of allylic sulfides and terminal alkynes via C-C bond formationA general ligand design for gold catalysis allowing ligand-directed anti-nucleophilic attack of alkynes.A modular, efficient, and stereoselective synthesis of substituted piperidin-4-ols.Combining Zn Ion Catalysis with Homogeneous Gold Catalysis: An Efficient Annulation Approach to N-Protected Indoles.Enantioselective oxidative gold catalysis enabled by a designed chiral P,N-bidentate ligand.6-Exo-spiro (alkoxycarbonylamino)methyl radical cyclization: highly regio- and stereoselective synthesis of (-)-sibirine.Stereocontrolled synthesis of kelsoene by the homo-favorskii rearrangement.Efficient synthesis of cyclopentenones from enynyl acetates via tandem Au(I)-catalyzed 3,3-rearrangement and the Nazarov reaction.A highly efficient preparative method of alpha-ylidene-beta-diketones via Au(III)-catalyzed acyl migration of propargylic esters.Two-step formal [3+2] cycloaddition of enones/enals and allenyl MOM ether: gold-catalyzed highly diastereoselective synthesis of cyclopentanone enol ether containing an all-carbon quaternary center.Gold-catalyzed intramolecular redox reaction of sulfinyl alkynes: efficient generation of alpha-oxo gold carbenoids and application in insertion into R--CO bonds.Platinum-catalyzed formation of cyclic-ketone-fused indoles from N-(2-alkynylphenyl)lactams.Brønsted acid-promoted cyclizations of siloxyalkynes with arenes and alkenes.Radical deoxygenation of hydroxyl groups via phosphites.Au-Catalysed oxidative cyclisation.Efficient One-Pot Multifunctionalization of Alkynes en Route to α-Alkoxyketones, α-Thioketones, and α-Thio Thioketals by using an Umpolung Strategy.Ruthenium-catalyzed oxidative transformations of terminal alkynes to ketenes by using tethered sulfoxides: access to β-lactams and cyclobutanones.Gold-catalyzed assembly of heterobicyclic systems.Remote Cooperative Group Strategy Enables Ligands for Accelerative Asymmetric Gold Catalysis.A C-H Insertion Approach to Functionalized Cyclopentenones.One-Pot Synthesis of Benzene-Fused Medium-Ring Ketones: Gold Catalysis-Enabled Enolate Umpolung Reactivity.A Desulfonylative Approach in Oxidative Gold Catalysis: Regiospecific Access to Donor-Substituted Acyl Gold Carbenes.
P50
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P50
description
researcher (chemistry)
@en
wetenschapper
@nl
name
Liming Zhang
@ast
Liming Zhang
@en
Liming Zhang
@es
Liming Zhang
@nl
type
label
Liming Zhang
@ast
Liming Zhang
@en
Liming Zhang
@es
Liming Zhang
@nl
prefLabel
Liming Zhang
@ast
Liming Zhang
@en
Liming Zhang
@es
Liming Zhang
@nl
P244
P106
P214
7715147425868645040005
P244
no2016121294
P31
P496
0000-0002-5306-1515