Formation of vinyl-, vinylhalide- or acyl-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed enantioselective conjugate additions of Si-containing vinylaluminums to β-substituted cyclic enones.
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Catalytic enantioselective synthesis of quaternary carbon stereocentresAsymmetric conjugate additions and allylic alkylations using nucleophiles generated by hydro- or carbometallation.Metal complexes with oxygen-functionalized NHC ligands: synthesis and applications.Evolution of catalytic stereoselective olefin metathesis: from ancillary transformation to purveyor of stereochemical identity.A multicomponent Ni-, Zr-, and Cu-catalyzed strategy for enantioselective synthesis of alkenyl-substituted quaternary carbons.Enantioselective synthesis of alkyne-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution reactions with (i-Bu)2(alkynyl)aluminum reagents.Enantioselective synthesis of quaternary carbon stereogenic centers through copper-catalyzed conjugate additions of aryl- and alkylaluminum reagents to acyclic trisubstituted enonesAcyclic quaternary centers from asymmetric conjugate addition of alkylzirconium reagents to linear trisubstituted enones.Asymmetric Catalysis with Ethylene. Synthesis of Functionalized Chiral Enolates.Enol ethers as substrates for efficient Z- and enantioselective ring-opening/cross-metathesis reactions promoted by stereogenic-at-Mo complexes: utility in chemical synthesis and mechanistic attributes.Trienamines derived from interrupted cyclic 2,5-dienones: remote δ,ε-C=C bond activation for asymmetric inverse-electron-demand aza-Diels-Alder reaction.Formation of quaternary stereogenic centers by copper-catalyzed asymmetric conjugate addition reactions of alkenylaluminums to trisubstituted enones.Efficient formation of benzylic quaternary centers via palladium catalysis.Effect of multinuclear copper/aluminum complexes in highly asymmetric conjugate addition of trimethylaluminum to acyclic enones.Cu-Catalyzed electrophilic amination of internal alkynes via hydroalumination.Asymmetric Sequential Cu-Catalyzed 1,6/1,4-Conjugate Additions of Hard Nucleophiles to Cyclic Dienones: Determination of Absolute Configurations and Origins of Enantioselectivity.Enantioselective construction of branched 1,3-dienyl substituted quaternary carbon stereocenters by asymmetric allenyl Claisen rearrangement.Highly stereoselective conjugate addition and α-alkynylation reaction with electron-deficient alkynes catalyzed by chiral scandium(III) complexes.Stereocontrolled synthesis of carbocyclic compounds with a quaternary carbon atom based on SN2′ alkylation of γ,δ-epoxy-α,β-unsaturated ketonesSynthesis of -hydrindan-2,4-diones bearing an all-carbon quaternary center by a Danheiser annulation
P2860
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P2860
Formation of vinyl-, vinylhalide- or acyl-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed enantioselective conjugate additions of Si-containing vinylaluminums to β-substituted cyclic enones.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Formation of vinyl-, vinylhali ...... o β-substituted cyclic enones.
@en
Formation of vinyl-, vinylhali ...... o β-substituted cyclic enones.
@nl
type
label
Formation of vinyl-, vinylhali ...... o β-substituted cyclic enones.
@en
Formation of vinyl-, vinylhali ...... o β-substituted cyclic enones.
@nl
prefLabel
Formation of vinyl-, vinylhali ...... o β-substituted cyclic enones.
@en
Formation of vinyl-, vinylhali ...... o β-substituted cyclic enones.
@nl
P2860
P356
P1476
Formation of vinyl-, vinylhali ...... o β-substituted cyclic enones.
@en
P2093
Jennifer A Dabrowski
Tricia L May
P2860
P304
P356
10.1021/JA110054Q
P407
P577
2010-12-20T00:00:00Z