Synthesis of quaternary carbon stereogenic centers through enantioselective Cu-catalyzed allylic substitutions with vinylaluminum reagents.
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Axial preferences in allylations via the Zimmerman-Traxler transition state.Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsPalladium-catalyzed enantioselective Heck alkenylation of acyclic alkenols using a redox-relay strategy.Enantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols To Form Allylic Quaternary Centers.A broadly applicable NHC-Cu-catalyzed approach for efficient, site-, and enantioselective coupling of readily accessible (pinacolato)alkenylboron compounds to allylic phosphates and applications to natural product synthesis.Asymmetric conjugate additions and allylic alkylations using nucleophiles generated by hydro- or carbometallation.Metal complexes with oxygen-functionalized NHC ligands: synthesis and applications.Privileged chiral N-heterocyclic carbene ligands for asymmetric transition-metal catalysis.Evolution of catalytic stereoselective olefin metathesis: from ancillary transformation to purveyor of stereochemical identity.Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution.Enantioselective Nickel-Catalyzed Intramolecular Allylic Alkenylations Enabled by Reversible Alkenylnickel E/Z Isomerization.Copper-catalyzed enantioselective allylic substitution with readily accessible carbonyl- and acetal-containing vinylboron reagents.Enantioselective synthesis of alkyne-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution reactions with (i-Bu)2(alkynyl)aluminum reagents.Enantioselective synthesis of quaternary carbon stereogenic centers through copper-catalyzed conjugate additions of aryl- and alkylaluminum reagents to acyclic trisubstituted enonesFormation of vinyl-, vinylhalide- or acyl-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed enantioselective conjugate additions of Si-containing vinylaluminums to β-substituted cyclic enones.Asymmetric synthesis of α-chiral allylic silanes by enantioconvergent γ-selective copper(I)-catalyzed allylic silylation.Bidentate hydroxyalkyl NHC ligands for the copper-catalyzed asymmetric allylic substitution of allyl phosphates with Grignard reagents.Exceptionally E- and β-selective NHC-Cu-catalyzed proto-silyl additions to terminal alkynes and site- and enantioselective proto-boryl additions to the resulting vinylsilanes: synthesis of enantiomerically enriched vicinal and geminal borosilanes.Cu-Catalyzed electrophilic amination of internal alkynes via hydroalumination.Ligand-Controlled Regiodivergent and Enantioselective Copper-Catalyzed Hydroallylation of Alkynes.Synthesis of Chiral Tertiary Boronic Esters: Phosphonate-Directed Catalytic Asymmetric Hydroboration of Trisubstituted Alkenes.Stereospecific, Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Allylic Pivalates To Deliver Quaternary Stereocenters.Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis.Enantioselective construction of branched 1,3-dienyl substituted quaternary carbon stereocenters by asymmetric allenyl Claisen rearrangement.New catalysts with unsymmetrical N-heterocyclic carbene ligands.Copper-free asymmetric allylic alkylation of trisubstituted cyclic allyl bromides using Grignard reagents.
P2860
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P2860
Synthesis of quaternary carbon stereogenic centers through enantioselective Cu-catalyzed allylic substitutions with vinylaluminum reagents.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Synthesis of quaternary carbon ...... s with vinylaluminum reagents.
@en
Synthesis of quaternary carbon ...... s with vinylaluminum reagents.
@nl
type
label
Synthesis of quaternary carbon ...... s with vinylaluminum reagents.
@en
Synthesis of quaternary carbon ...... s with vinylaluminum reagents.
@nl
prefLabel
Synthesis of quaternary carbon ...... s with vinylaluminum reagents.
@en
Synthesis of quaternary carbon ...... s with vinylaluminum reagents.
@nl
P2093
P2860
P356
P1476
Synthesis of quaternary carbon ...... s with vinylaluminum reagents.
@en
P2093
Kevin P McGrath
P2860
P304
14315-14320
P356
10.1021/JA106829K
P407
P577
2010-10-01T00:00:00Z