Enantioselective synthesis of alkyne-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution reactions with (i-Bu)2(alkynyl)aluminum reagents.
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Recent advances in copper-catalyzed asymmetric coupling reactionsEnantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsCatalytic enantioselective synthesis of quaternary carbon stereocentresA broadly applicable NHC-Cu-catalyzed approach for efficient, site-, and enantioselective coupling of readily accessible (pinacolato)alkenylboron compounds to allylic phosphates and applications to natural product synthesis.Metal complexes with oxygen-functionalized NHC ligands: synthesis and applications.Enantiospecific Alkynylation of Alkylboronic Esters.Evolution of catalytic stereoselective olefin metathesis: from ancillary transformation to purveyor of stereochemical identity.Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution.Copper-catalyzed enantioselective allylic substitution with readily accessible carbonyl- and acetal-containing vinylboron reagents.Selective syntheses of Δ(α,β) and Δ(β,γ) butenolides from allylic cyclopropenecarboxylates via tandem ring expansion/[3,3]-sigmatropic rearrangementsCombining NHC-Cu and Brønsted base catalysis: enantioselective allylic substitution/conjugate additions with alkynylaluminum reagents and stereospecific isomerization of the products to trisubstituted allenes.Metal-free catalytic C-Si bond formation in an aqueous medium. Enantioselective NHC-catalyzed silyl conjugate additions to cyclic and acyclic α,β-unsaturated carbonyls.Iridium-catalyzed enantioselective allylic alkynylation.Bidentate hydroxyalkyl NHC ligands for the copper-catalyzed asymmetric allylic substitution of allyl phosphates with Grignard reagents.Exceptionally E- and β-selective NHC-Cu-catalyzed proto-silyl additions to terminal alkynes and site- and enantioselective proto-boryl additions to the resulting vinylsilanes: synthesis of enantiomerically enriched vicinal and geminal borosilanes.Synthesis of iridium and rhodium complexes with new chiral phosphine-NHC ligands based on 1,1'-binaphthyl framework and their application in asymmetric hydrogenation.Efficient formation of benzylic quaternary centers via palladium catalysis.Stereospecific, Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Allylic Pivalates To Deliver Quaternary Stereocenters.Enantioselective Formation of CF3-Bearing All-Carbon Quaternary Stereocenters via C-H Functionalization of Methanol: Iridium Catalyzed Allene Hydrohydroxymethylation.Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis.Copper(i)-catalysed asymmetric allylic reductions with hydrosilanes.Enantioselective construction of branched 1,3-dienyl substituted quaternary carbon stereocenters by asymmetric allenyl Claisen rearrangement.Synthesis of Branched Alkylboronates by Copper-Catalyzed Allylic Substitution Reactions of Allylic Chlorides with 1,1-Diborylalkanes.Copper-free asymmetric allylic alkylation of trisubstituted cyclic allyl bromides using Grignard reagents.Diversity-oriented enantioselective synthesis of highly functionalized cyclic and bicyclic alcohols.Asymmetric Catalysis with Silicon-Based Cuprates: Enantio- and Regioselective Allylic Substitution of Linear Precursors
P2860
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P2860
Enantioselective synthesis of alkyne-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution reactions with (i-Bu)2(alkynyl)aluminum reagents.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
2011年论文
@zh
2011年论文
@zh-cn
name
Enantioselective synthesis of ...... u)2(alkynyl)aluminum reagents.
@en
type
label
Enantioselective synthesis of ...... u)2(alkynyl)aluminum reagents.
@en
prefLabel
Enantioselective synthesis of ...... u)2(alkynyl)aluminum reagents.
@en
P2860
P356
P1476
Enantioselective synthesis of ...... u)2(alkynyl)aluminum reagents.
@en
P2093
Jennifer A Dabrowski
P2860
P304
P356
10.1021/JA2010829
P407
P577
2011-03-08T00:00:00Z